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In organic-rich gas shales, clay minerals and organic matter (OM) have significant influences on the origin, preservation, and production of shale gas. Because of the substantial role of nanoscale pores in the generation, storage, and seepage of shale gas, we examined the effects of clay minerals and OM on nanoscale pore distribution characteristics in Lower Paleozoic shale gas reservoirs. Using the Niutitang and Longmaxi shales as examples, we determined the effects of clay minerals and OM on pores through sedimentation experiments. Field emission–scanning electron microscopy combined with low-pressure N2 adsorption of the samples before and after sedimentation showed significant differences in pore location and pore size distribution between the Niutitang and Longmaxi shales. Nanoscale pores mostly existed in OM in the Longmaxi shale and in clay minerals or OM–clay composites in the Niutitang shale. The distribution differences were attributed largely to variability in thermal evolution and tectonic development and might account for the difference in gas-bearing capacity between the Niutitang and Longmaxi reservoirs. In the nanoscale range, mesopores accounted for 61–76% of total nanoscale pore volume. Considerably developed nanoscale pores in OM were distributed in a broad size range in the Longmaxi shale, which led to good pore connectivity and gas production. Numerous narrow pores (i.e., pores?<?20 nm) in OM–clay composites were found in the Niutitang shale, and might account for this shale’s poor pore connectivity and low gas production efficiency. Enhancing the connectivity of the mesopores (especially pores?<?20 nm and those developed in OM–clay composites) might be the key to improving development of the Niutitang shale. The findings provide new insight into the formation and evolutionary mechanism of nanoscale pores developed in OM and clay minerals. 相似文献
84.
Some Au deposits in southern Anhui Province have recently been found to be closely associated with Late Mesozoic intrusions. Typical examples include the Huashan Au (Sb) deposit and Au deposits at Zhaojialing, Wuxi, and Liaojia. In order to understand the mechanisms that led the formation of these Au deposits, we make detailed reviews on the geological characteristics of these Au deposits. Specifically, we present new LA-ICP-MS zircon U–Pb dating, along with elemental and Hf isotopic data from the Huashan Au (Sb) deposit. Our data suggests that the Huashan ore-related intrusions were emplaced during the Late Jurassic and Early Cretaceous periods (144–148 Ma). They are characterized by arc-magma features and high oxygen fugacity and are rich in inherited zircons. Zircon U–Pb ages and Lu–Hf isotopes from intrusions suggest that Proterozoic juvenile lithosphere is the main source of these intrusions. The regional geological history implies that lithosphere beneath southern Anhui was produced during a Proterozoic subduction and was fertilized with Au (Cu) in the process. Integrated with the results of previous studies, we inferred that Late Mesozoic intrusions formed by the remelting of the lithosphere could provide the metal endowment for the Au-rich deposits in southern Anhui. 相似文献
85.
Xingang Wang Yueping Yin Jiading Wang Baoqin Lian Haijun Qiu Tianfeng Gu 《Landslides》2018,15(7):1377-1389
The rock masses of hydro-fluctuation belt experience seepage pressure following impoundment in the Three Gorges Reservoir; its creep behaviors are significant for reservoir bank slopes. To study the creep behaviors under seepage pressure (0, 1.45, and 1.75 MPa), we performed creep tests using representative landslide sandstone in the Three Gorges Reservoir and investigated the sandstone creep behaviors under the coupling effects of seepage pressure and stress. Previous researches on rocks have usually regarded the creep constitutive parameter as a constant; however, in this study, a nonlinear, nonstationary, plastic-viscous (NNPV) creep model which can describe the curve of sandstone creep tests is proposed. The rock-creep parameters under three levels of seepage pressure were identified, and theoretical curves using the NNPV model agreed well with the experimental data, indicating that the new model cannot only describe the primary creep and secondary creep stages under varying seepage pressures but also, in particular, perfectly describes the tertiary creep stage. Finally, the sensitivity of the NNPV model parameters is analyzed, and the result shows that the nonstationary coefficient α and the nonlinear coefficient m are main parameters affecting the tertiary creep stage. 相似文献
86.
B. Matasci G. M. Stock M. Jaboyedoff D. Carrea B. D. Collins A. Guérin G. Matasci L. Ravanel 《Landslides》2018,15(5):859-878
Rockfalls strongly influence the evolution of steep rocky landscapes and represent a significant hazard in mountainous areas. Defining the most probable future rockfall source areas is of primary importance for both geomorphological investigations and hazard assessment. Thus, a need exists to understand which areas of a steep cliff are more likely to be affected by a rockfall. An important analytical gap exists between regional rockfall susceptibility studies and block-specific geomechanical calculations. Here we present methods for quantifying rockfall susceptibility at the cliff scale, which is suitable for sub-regional hazard assessment (hundreds to thousands of square meters). Our methods use three-dimensional point clouds acquired by terrestrial laser scanning to quantify the fracture patterns and compute failure mechanisms for planar, wedge, and toppling failures on vertical and overhanging rock walls. As a part of this work, we developed a rockfall susceptibility index for each type of failure mechanism according to the interaction between the discontinuities and the local cliff orientation. The susceptibility for slope parallel exfoliation-type failures, which are generally hard to identify, is partly captured by planar and toppling susceptibility indexes. We tested the methods for detecting the most susceptible rockfall source areas on two famously steep landscapes, Yosemite Valley (California, USA) and the Drus in the Mont-Blanc massif (France). Our rockfall susceptibility models show good correspondence with active rockfall sources. The methods offer new tools for investigating rockfall hazard and improving our understanding of rockfall processes. 相似文献
87.
Zizhan Hu Xuguang Tang Chen Zheng Menglin Guan Jingwei Shen 《Environmental Earth Sciences》2018,77(14):540
Due to its negative impact on the living environment of human beings, ambient air pollution has become a global challenge to human health. In this study, surface observations of six criteria air pollutants, including PM2.5, PM10, SO2, NO2, CO and O3, were collected to investigate the spatial and temporal variation in the Beijing–Tianjin–Hebei (BTH) region during 2013–2016 and to explore the relationships between atmospheric pollutants and meteorological variables using quantile regression model (QRM) and multiple linear regression model (MLRM). The results show that BTH region has experienced significant air pollution, and the southern part generally has more severe conditions. The annual average indicates clear decreasing trends of the particulate matters, SO2 and CO concentrations over the last 4 years and slight increasing trends of NO2 and O3 in several cities. The seasonal and monthly characteristics indicate that the concentrations of five species reach their maxima in the winter and their minima in the summer, whereas O3 has the opposite behaviour. Finally, the pseudo R2 values show that the QRMs have the best performance in the winter, followed by spring, fall, and summer. Specifically, all the meteorological factors have significant impacts on air pollution but change with pollutants and seasons. The MLRM results are generally consistent with the QRM results in all seasons, and the inconsistencies are more common in the fall and winter. The results of this research provide foundational knowledge for predicting the response of air quality to climate change in the BTH region. 相似文献
88.
Huangling Gu Zhangxing Nie Jianghong Deng Liuan Duan Qing Hu 《International Geology Review》2018,60(11-14):1404-1434
ABSTRACTThe Guichi ore-cluster district in the Lower Yangtze River Metallogenic Belt hosts extensive Cu–Au–Mo polymetallic deposits including the Tongshan Cu–Mo, Paodaoling Au, Matou Cu–Mo, Anzishan Cu–Mo, Guilinzheng Mo and Zhaceqiao Au deposits, mostly associated with the late Mesozoic magmatic rocks, which has been drawn to attention of study and exploration. However, the metallogenic relationship between magmatic rocks and the Cu–Au-polymetallic deposits is not well constrained. In this study, we report new zircon U–Pb ages, Hf isotopic, and geochemical data for the ore-bearing intrusions of Guichi region. LA-ICP-MS U–Pb ages for the Anzishan quartz diorite porphyrite is 143.9 ± 1.0 Ma. Integrated with previous geochronological data, these late Mesozoic magmatic rocks can be subdivided into two stages of magmatic activities. The first stage (150–132 Ma) is characterized by high-K calc-alkaline intrusions closely associated with Cu–Au polymetallic ore deposits. Whereas, the second stage (130–125 Ma) produced granites and syenites and is mainly characterized by shoshonite series that are related to Mo–Cu mineralization. The first stage of magmatic rocks is considered to be formed by partial melting of subducted Palaeo-Pacific Plate, assimilated with Yangtze lower crust and remelting Meso-Neoproterozoic crust/sediments. The second stage of magmatism is originated from partial melting of Mesoproterozoic-Neoproterozoic crust, mixed with juvenile crustal materials. The depression cross to the uplift zone of the Jiangnan Ancient Continent forms a gradual transition relation, and the hydrothermal mineralization composite with two stages have certain characteristics along the regional fault (Gaotan Fault). Guichi region results from two episodes of magmatism probably related to tectonic transition from subduction of Palaeo-Pacific Plate to back-arc extensional setting between 150 and 125 Ma, which lead to the Mesozoic large-scale polymetallic mineralization events in southeast China. 相似文献
89.
车排子凸起位于准噶尔盆地扎伊尔山前,是夹持在南部四棵树凹陷和东部沙湾凹陷之间的三角构造带。然而对这个三角构造带是原地掩伏构造,山前推覆构造,还是走滑构造控制形成的认识存在争议。目前对于车排子凸起与沙湾凹陷过渡带的构造变形特征以及变形机制的认识尚不清楚。而过渡带是研究该区构造变形与演化的良好区域,精细研究该区域构造几何学与运动学对于揭示其构造变形机制以及认识盆山之间的关系具有积极作用,并对于该区油气勘探具有重要意义。本文以研究区的连片三维地震资料为基础,运用不整合面识别、轴面分析及平衡剖面等方法,对车排子凸起与沙湾凹陷过渡带进行精细的构造解析、建模与构造复原。研究表明,过渡带发育下二叠统(P1j-P1f),中二叠统(P2x-P2w),上二叠统(P3w),三叠系(T),侏罗系(J),白垩系(K)与古近系-第四系(E-Q)7个构造变形层序。发育佳木河组底部及石炭系内部滑脱层。深部(前二叠系)构造楔发育于整个过渡带,其个数和几何学形态的变化直接影响了上覆背斜形态。构造楔在早二叠世开始楔入,挤压作用持续至三叠纪末期。晚三叠世发育生长地层,显示了P-T构造层褶皱变形的时间,随后三叠纪末期,过渡带受到来自西北缘造山带方向的逆冲推覆构造的叠加作用,表现在后缘发育一系列叠瓦构造,推覆距离约为8 km,南部逆冲断层上盘二叠系-三叠系被剥蚀完全,北部残余少量下二叠统佳木河组。 相似文献
90.
为了客观地确定数据点投图后分布的主要区域,本文提出了一种基于数据密度确定数据主要分布区域的方法。利用该方法可以更加直观地了解数据分布,并可以作为数据清洗的预处理手段。本文基于GEOROC大数据,以全碱对硅(TAS)图解为例,进行了分析和验证。通过提取GEOROC 数据库中与TAS 图解相关的岩石样本中SiO2、Na2O、K2O 和烧失量含量数据,通过数据常规清洗和归算,最终获得24 个种类合计13.3 万条有效数据。通过数据投点、分区统计和提取80% 数据的分布区域,验证了24种岩石样品与TAS图解的吻合程度。通过综合研究分析发现,有6类岩石的数据分布与TAS图解定义区域基本一致,18类岩石的数据分布与TAS图解定义区域有系统性偏差。大数据研究证明了TAS图解的不足之处,利用全碱和SiO2作为指标,难以实现提升总体分类的准确性。 相似文献