Excessive greenhouse gas emissions from wastewater treatment plants by using the chemical oxygen demand standard     

Zongqing LV  Xiaoyu SHAN  Xilin XIAO  Ruanhong CAI  Yao ZHANG  Nianzhi JIAO 《中国科学:地球科学(英文版)》2022,65(1):87-95

Chemical oxygen demand(COD)is widely used as an organic pollution indicator in wastewater treatment plants.Large amounts of organic matter are removed during treatment processes to meet environmental standards,and consequently,substantial greenhouse gases(GHGs)such as methane(CH₄)are released.However,the COD indicator covers a great amount of refractory organic matter that is not a pollutant and could be a potential carbon sink.Here,we collected and analysed COD data from 86 worldwide municipal wastewater treatment plants(WWTPs)and applied a model published by the Intergovernmental Panel on Climate Change to estimate the emission of CH₄ due to recalcitrant organic compound processing in China’s municipal wastewater treatment systems.Our results showed that the average contribution of refractory COD to total COD removal was55%in 86 WWTPs.The amount of CH₄ released from the treatment of recalcitrant organic matter in 2018 could have been as high as 38.22 million tons of carbon dioxide equivalent,which amounts to the annual carbon sequestered by China’s wetlands.This suggests that the use of COD as an indicator for organic pollution is undue and needs to be revised to reduce the emission of GHG.In fact,leaving nontoxic recalcitrant organic matter in the wastewater may create a significant carbon sink and will save energy during the treatment process,aiming at carbon neutrality in the wastewater treatment industry.  相似文献   

Interactions between hydrocarbon-bearing fluids and calcite in fused silica capillary capsules and geological implications for deeply-buried hydrocarbon reservoirs     

Zihao JIN  Guanghui YUAN  Yingchang CAO  Keyu LIU  Yanzhong WANG  Jianye SUN  Xiluo HAO  Ling ZHOU  Yihan WEI  Shuqi WU 《中国科学:地球科学(英文版)》2022,65(2):299-316

During the burial processes of deep/ultra-deep hydrocarbon reservoirs,the interactions between hydrocarbon-bearing fluids and reservoirs significantly affect the quality evolution of hydrocarbons and reservoirs;thus,this topic requires further investigation.In this study,the continuous evolution and the coupling mechanisms in various anhydrous and hydrous nC₁₆H₃₄-(water)-(calcite)systems in fused silica capillary capsules(FSCCs)were investigated using laser Raman spectroscopy,fluorescence color analysis,and fluorescence spectroscopy,and the mineral alterations were analyzed using scanning electron microscopy(SEM).The experimental results show that extensive organic-inorganic interactions occur in the systems if water is present,and different inorganic components have different effects on hydrocarbon degradation.Distilled water promotes freeradical thermal cracking and steps oxidation,forming more low-molecular-weight hydrocarbons,CO₂,and organic acids(e.g.,acetic acids)but suppresses the free-radical cross-linking,generating less high-molecular-weight hydrocarbons.However,in the presence of CaCl₂ water,the yields of hydrocarbon gases are lower than in the distilled water system because high concentrations of Ca ions inhibit the generation of free radicals.Calcites,which exhibit different surface reactivities in different fluid conditions,affect hydrocarbon degradation in different ways.In the anhydrous nC16H34-calcite system,calcites promote the generation of both hydrocarbon gases and high-molecular-weight hydrocarbons.In contrast,in the hydrous nC16H34-distilled(CaCl₂)watercalcite system,calcites promote the generation of hydrocarbon gases and suppress the generation of high-molecular-weight hydrocarbons.Calcite also reacts with organic acids via surface reactions to form secondary pores.Therefore,except for the formation temperature and pressure,organic-inorganic interactions are controlled by multiple factors,such as the water saturation,water type,water salinity,and the mineral content,resulting in different evolutions of the hydrocarbon degradation and reservoir properties.  相似文献   

中亚造山带东南部晚古生代-早中生代地壳增生和古亚洲洋演化:来自内蒙古东南部林西-东乌旗地区岩浆岩的证据SCIEI北大核心CSCD     

刘建峰  李锦轶  赵硕  张进  郑荣国  张文龙  吕前露  郑培玺 《岩石学报》2022,(8):2181-2215

本文在系统收集内蒙古林西-东乌旗地区晚古生代-早中生代岩浆岩的年代学、岩石地球化学以及锆石Hf同位素资料基础上,通过分析岩浆岩岩石组合随时空的变化规律,并结合区域地质资料,探讨了中亚造山带东南部洋盆演化和地壳增生等重要地质问题。研究结果表明,二连浩特-贺根山蛇绿岩带南、北两侧晚古生代-早中生代岩浆岩在年代学上显示不同的活动期次,具有不同岩石组合和地球化学特征,指示它们分属于不同的构造岩浆岩带。蛇绿岩带以北晚泥盆世-中二叠世岩浆活动在时间上呈连续分布的特征,并在晚石炭-早二叠世时期达到活动峰值。火成岩构造组合分析表明,晚泥盆世-石炭纪和早-中二叠世岩浆活动分别与二连浩特-贺根山洋盆向乌里雅斯太大陆边缘之下的俯冲和洋盆闭合后俯冲板片断离引起的软流圈上涌造成的区域伸展背景有关。蛇绿岩带以南岩浆活动时间上呈现石炭纪、早-中二叠世、晚二叠世-三叠纪幕式分布特征,各期岩浆活动前锋有随时间向南迁移的趋势。这三期岩浆活动分别与古亚洲洋板片向宝力道岛弧之下的俯冲、板片后撤以及洋盆消失之后古板块的碰撞造山作用有关。锆石Hf同位素分析表明,中亚造山带东南部晚古生代至早中生代时期存在显著的地壳增生;其中二连浩特-贺根山蛇绿岩带以北表现为地壳的垂向增生,以南表现为地壳的侧向增生。  相似文献   

内蒙古林西县北三段银铅多金属矿床碳、氧、硫、铅同位素特征及成矿物质来源     

吕向光 《地质与勘探》2015,51(5):898-906

本文对内蒙古林西县北三段银铅多金属矿床矿体的碳、氧、硫、铅同位素进行了测定,并对其成矿物质来源及演化进行了探讨。矿区样品的δ34S‰变化范围为-0.24‰~2.37‰,平均值为1.29‰,初步认为矿石中的硫主要来源于深部岩浆,并有少量生物还原硫的加入。样品的δ13CPDB变化范围为-4.57‰~-7.33‰,平均值为-5.96‰,δ18O为-3.4‰~-4.8‰,平均值为-4.06‰;δ13CPDB-δ18OSMOW关系表明,矿体中的碳可能主要由基性-超基性岩浆提供,并有部分来源于地层,且受大气水影响明显。铅同位素表明北三段矿床的成矿物质可能由造山带物质和地幔物质两部分提供。  相似文献   

Provincial evaluation of vulnerability to geological disaster in China and its influencing factors: a three-stage DEA-based analysis   总被引：1，自引：0，他引：1  

Mingze Li  Jun Lv  Xin Chen  Nan Jiang 《Natural Hazards》2015,79(3):1649-1662

  相似文献   

Experimental study of the effects of non-uniformly distributed fine soil on mechanical properties of Shenyang–Dandong Railway coarse-grained soil     

QianMi Yu  JianKun Liu  JingYu Liu  DingJun Lv  TengFei Wang 《寒旱区科学》2015,7(5):503-512

The stress produced by repeated train loads decreases with increasing railway subgrade bed depth, and slightly weathered coarse particles of subgrade bed fillings can be broken at different levels under continuous load. Thus, the mass of fine soil, with a diameter of not more than 0.075 mm, is different at different depths. Fine soil is also sensitive to frost heave and thaw settlement. In order to study the effects of non-uniformly distributed fine soil on the mechanical properties of coarse-grained soil of the Shenyang-Dandong Railway, triaxial tests were conducted with three types of specimens, undergoing six freeze-thaw cycle numbers(0, 1, 3, 7, 9, 12) and three confining pressures(100, 200, 300 k Pa). The freezing temperature is-5 °C and the thawing temperature is +15 °C. The stress-strain behavior, static strength, resilient modulus, cohesive force and the angle of internal friction were measured for different tested specimens. As a result, the law of static strength and resilient modulus of different specimens following the increase of freeze-thaw cycles under three confining pressures is obtained. The changing law of cohesive force and friction angle of three specimens following the increase of freeze-thaw cycles is also calculated, and the different results of different specimens are also compared.  相似文献   

山东地区典型金属罐喷涂企业VOCs排放特征研究     

曹双  高素莲  闫学军  刘光辉  王琛 《南京气象学院学报》2020,12(6):749-757

了解涂装行业挥发性有机物（VOCs）的排放特征是制定山东地区臭氧（O₃）和PM_2.5防控策略的重要环节.本研究在山东地区测定了两家典型食品金属包装企业喷涂过程中VOCs的排放组成,企业产品以饮料罐和罐头为主.结果表明：两家企业排放的总VOCs质量浓度水平相当,质量浓度变化范围在50~1 500 μg/m³;但两家企业喷涂过程中VOCs的排放组成具有一定的差异,以生产铝罐和马口铁罐为主的企业中的含氧挥发性有机物（OVOCs）含量最多,占比89.71%（质量分数,下同）;而生产铝罐的企业芳香烃（56.15%）是首要的排放种类,其次是OVOCs （32.32%）.通过分析两家企业内外喷涂工艺的VOCs源成分谱,发现同一企业不同工艺之间有一定差异,多种罐生产企业的内、外喷涂中乙醇占比最高,分别为94.28%、84.46%;单铝罐生产企业的内喷涂2-丁酮（24.33%）是重要组分,外喷涂中甲苯（36.40%）含量较高.  相似文献   

一次飑线风暴的环境条件和雷达回波特征分析     

赵玲  李树岭  魏光辉 《气象与环境科学》2013,36(4):29-35

利用常规气象观测和新一代天气雷达监测资料,对大兴安岭地区加格达奇市2006年8月一次飑线天气的环境条件和雷达回波特征等分析发现：此次过程的影响系统高空槽为前倾结构,飑线发生在地面冷锋前,大气具有较强的不稳定层结,有利于上升运动,水汽充足,低层较强的垂直风切变使对流云团和弓形等线状回波生成并较长时间地维持和发展。对流云团位置与上升运动区域较为一致,产生飑线的强对流云团出现在中低层垂直速度梯度较大并靠近上升运动中心一侧,并位于低层比湿和水汽通量散度梯度较大区域即干锋附近以及K指数能量锋上。飑线弓形回波出现在一个中尺度椭圆状对流云团中心内部发展最强处。当云团向东北偏东方向移过加格达奇雷达站时,雷达反射率因子先后呈现出弓形、＂人＂字形等线状回波特征,当线状回波南端＂人＂字形顶部较强回波和后侧入流急流前方＂V＂型槽口的尖峰移经加格达奇时,带来了雷雨大风天气。  相似文献   

土壤有机质高光谱估算研究进展     

郑光辉  王明江  焦彩霞  孙东敏 《南京气象学院学报》2013,5(6):481-486

土壤有机质是土壤的重要组成部分,对许多土壤属性有重要影响.利用光谱技术进行土壤有机质的快速测定是实现精细农业的基础.近几十年中,高光谱技术的发展为土壤研究提供了新的手段.受土壤有机质质量分数、组成以及土壤水分、土壤质地的影响,室内光谱的估算结果总体较好;受大气、地表植被等影响,航空或卫星的成像光谱估算精度较低.星载成像技术的进步将在一定程度上提高土壤有机质的估算精度,为快速、大范围土壤有机质质量分数的遥感制图提供技术支持.  相似文献   

锡林浩特国家气候观象台观测系统发展的思考     

吕向伟 《内蒙古气象》2013,(3):42-43

锡林浩特国家气候观象台是全区乃至全国观测项目最多、重要性最强的气象台站之一,但在近几年的发展过程中遇到了一些问题。文章重点分析了锡林浩特国家气候观象台观测系统的组成和存在的问题,探讨了推进锡林浩特国家气候观象台观测系统发展的思路。  相似文献