With implications for the origin of ore deposits, redox state of the atmosphere, and effects of volcanic outgassing, understanding the sulfur cycle is vital to our investigation of Earth processes. However, the paucity of sulfur concentration measurements in silicate rocks and the lack of well‐calibrated reference materials with concentrations relevant to the rocks of interest have hindered such investigations. To aid in this endeavour, this study details a new method to determine sulfur concentration via high mass resolution solution inductively coupled plasma‐mass spectrometry (ICP‐MS). The method is based on an aqua regia leach, involving relatively rapid sample preparation and analysis, and uses small test portion masses (< 50 mg). We utilised two independently prepared standard solutions to calibrate the analyses, resulting in 4% accuracy, and applied the method to eight geochemical reference materials. Measurements were reproducible to within ~ 10%. Sulfur concentrations and isotopes of six reference materials were measured additionally by elemental analyser‐combustion‐isotope ratio mass spectrometry to independently evaluate the accuracy of the ICP‐MS method. Reference materials that yielded reproducible measurements identical to published values from other laboratories (JGb‐1, JGb‐2 and MAG‐1) are considered useful materials for the measurement of sulfur. Reference materials that varied between studies but were reproducible for a given test portion perhaps suffer from sample heterogeneity and are not recommended as sulfur reference materials. 相似文献
This paper focuses on the comparison of damage induced by smooth blasting and presplit blasting based on the excavation of high rock slope. The whole damage process of the smooth blasting and presplit blasting excavation method is studied by using a cumulative blasting damage numerical simulation technology based on the secondary development of the dynamic finite element code LS-DYNA. The results demonstrate that, in the case of contour blasting with the method of smooth blasting, the total damage of rock slope is a result of cumulated damage induced by the production hole, buffering hole, and smooth hole. Among the total damage, the blasting of the production hole is the main resource, followed by the smooth and buffering holes. For the presplit blasting, the final damage of rock slope is mainly induced by presplit blasting itself. The spatial distribution characteristics of the final damage zone of two methods are compared. Two classes of damage zone could be found in smooth blasting excavation; one of them is the columnar high-degree damage zone around the slope surface and the other is the low-degree damage zone located in the middle of the slope. But in the case of presplit blasting, there is only the columnar high-degree damage zone around the slope surface. Finally, a damage control suggestion for two blasting excavation methods is proposed and verified based on the excavation of the temporary shiplock slopes of the Three Gorges Project in China. 相似文献
Exploring hydraulic connections between brine mining wells is of great significance to the development of geological resources; however, there are still challenges to accurately identifying these connections. In this study, a combination of hydrochemical and biological analyses was used to investigate the hydraulic connections between three saltworks (Yangkou, Hanting, and Changyi) in southern Laizhou Bay, China. The results showed that the groundwater recharge sources at Yangkou saltworks, and therefore the associated salts and hydrochemical composition of the brine, were different from those of the other two saltworks. The diversity and composition of the microbial community among the three saltworks were identified based on a high-throughput DNA sequencing method. The brines of Hanting and Changyi saltworks had greater similarity in terms of microbial diversity and composition, which was consistent with the hydrochemical results. Based on microbial analysis combined with hydrochemistry, the depths of the mining wells at Hanting saltworks were identified, along with the hydraulic connection with Changyi saltworks. As a tool to judge the hydraulic connections of geological reservoirs, microbial analysis combined with hydrochemistry may be applicable to a wider range of subsurface resources, such as oil and gas, which will provide new ideas for the rational development of underground resources.