生物炭对磷石膏中磷的固化作用     

敖翔  徐冠立  李珎  柏涵 《岩石矿物学杂志》2024,43(1):100-108

磷石膏中的磷在雨水淋滤作用下浸出,将污染堆场附近水体。本研究采用生物炭固化磷石膏中的磷,以减少其对周遭水体的污染。主要通过模拟固化实验和对照浸出实验,分析生物炭用量、反应时间和温度、初始pH值对固化效果的影响,通过XRD、SEM-EDS分析固化后的生成物。实验结果显示,在生物炭用量为25 mg时,单位固化量达到最大值13.20 mg/g;在反应温度T=293 K、初始pH=7条件下,反应平衡时间72 h时浸出液的磷平衡浓度C_e= 1.40 mg/L;温度提升有助于提高生物炭的固化效果,当T=308 K时,浸出液的磷平衡浓度C_e=0.167 mg/L;碱性条件有利于固化反应持续进行,在pH=11条件下,浸出液的磷平衡浓度C_e=0.153 mg/L。实验结果表明生物炭对磷石膏中的磷具有明显的固化效果。磷石膏中的二水硫酸钙溶解后,Ca²⁺与表面带负电的生物炭结合,在生物炭显微结构的凹陷处,化学吸附溶液中的磷酸根生成了絮状、团簇状的羟基磷灰石(HAP)沉淀,从而使浸出磷得到有效控制。  相似文献   

珠江口盆地西江主洼油气差异分布机制     

刘培  张向涛  林鹤鸣  杜家元  冯进  陈维涛  梁杰  贾培蒙 《吉林大学学报(地球科学版)》2021,51(1):52-64

西江主洼是珠江口盆地一个低勘探程度洼陷，油气差异聚集特征明显，但其机理不清。本文在断陷盆地油气成藏理论指导下，利用研究区地质、地球物理和地球化学等资料，开展了烃源岩、断盖组合、储集体系和运聚模式等方面的研究。结果表明，裂陷期沉降、沉积中心有序迁移，造成主力烃源岩自东向西由文四段迁移至文三段、文一+二段，控制东、西部油气差异分布。恩平组区域性泥岩发育且晚期断裂缺乏，导致油气纵向上更易聚集于下构造层；区域泥岩减薄尖灭或晚期断裂切开盖层的区域，上构造层有一定油气分布。"源-汇"类型从宏观上控制储层优劣，影响下构造层油气富集程度；"仓储"运移是控制上构造层油气规模聚集的主要模式。下构造层古近系应作为重点部署方向，东部围绕文四段、西部围绕文三段、文一+二段烃源岩构成的含油气系统展开；上构造层勘探需关注珠海组，在隆起周边寻找具备"仓储"运移模式的有利区带。  相似文献   

基于FPN Res-Unet的高分辨率遥感影像建筑物变化检测     

王明常  朱春宇  陈学业  王凤艳  李婷婷  张海明  韩有文 《吉林大学学报(地球科学版)》2021,51(1):296-306

针对城市土地资源变化检测工作繁杂、工作量大、自动化程度低等问题，本文提出一种基于深度学习模型的高分辨率遥感影像建筑物变化检测方法，将语义分割的思想引入到遥感变化检测。基于残差结构特征较卷积层提取性能更优和特征金字塔网络多尺度预测的特点，将残差结构和特征金字塔网络融合到Unet模型中，建立FPN Res-Unet模型。该模型以Unet为基础，引入ResNet18的残差结构作为编码路径特征提取层，在每次卷积后使用边界填充，使得输入图像和输出图像尺寸一致；在解码路径每级上采样过程中，拓展支路径将特征金字塔网络融合到模型的网络主干中，将残差结构、Unet及特征金字塔网络的优点相互融合，增强了Unet的特征提取，弥补了语义分割网络对小目标检测的欠缺；在获取深层语义信息的同时关注细节信息，提高建筑物变化检测精度。实验表明，该方法在所用数据集，准确率、召回率、F₁ 3种指标均达到90%以上。  相似文献   

杨山晚古生代沉积盆地成因类型及其与桐柏-大别造山带关系的探讨   总被引：16，自引：1，他引：15  

李曰俊  金福全 《地质科学》1997,32(1):19-26

杨山晚古生代沉积盆地位于桐柏-大别山北麓,它具有明显的前陆盆地沉积特点,由早期(D₂?—C₁)的复理石建造到晚期(C₁—P?)的磨拉石建造;古生物地理分析表明其与华北、扬子陆块都有密不可分的联系,其间不可能有古洋盆的存在,因而它应当是桐柏一大别造山带碰撞造山过程中形成的前陆盆地。杨山晚古生代前陆盆地的形成说明,扬子陆块和华北陆块的陆-陆碰撞起始于晚泥盆世之前(S₃—D₂),而桐柏-大别造山带中生代的构造事件则可能代表一次大规模陆内逆冲-推覆作用。  相似文献   

Two methods of orthogonally stepwise discrimination and their applications     

Xueren Wang  Jin Zhang 《Mathematical Geology》1992,24(2):203-218

In this paper, we describe two methods of discrimination based on MSE ratio and regression, respectively, and an algorithm of orthogonally stepwise discrimination. The method is not limited by the assumption that the sample covariance matrix is not ill-conditioned or singular, and by any assumption about the distribution of each population as well. So, it has wide range of application to various problems, particularly, to the problem of discrimination with both quantitative and qualitative variables. After variables are selected in the procedure of stepwise discrimination, they need not be rejected. Several examples have been calculated by using the method, and the results are quite satisfying.  相似文献   

毫秒时间尺度太阳微波辐射新特征     

金声震  李小聪  王淑兰  姬慧荣  阎元宜  赵冰 《中国天文和天体物理学报》1991,(4)

自1990年6月北京天文台太阳射电偏振仪投入实测以来,观测到一百多个“Spike”和短时标精细结构微波幅射,其中包括一些新的微波幅射特征。本文给出了主要的四点特征:(1)窄带辐射;(2)快速偏振逆转;(3)快速频率漂移;(4)不同时标的准周期振荡。  相似文献   

Astrophysical constraints on the gravitational constant     

Jin Wang 《Astrophysics and Space Science》1991,184(1):31-36

We study the astrophysical bounds on the change of the gravitational constant with time. We found that |/G|<10^–12yr^–1 is the condition that has to be satisfied in order not to cause a conflict with the observations. We find the condition to be in accord with the lower limits, the superstring theory predicts.  相似文献   

使用价值分析优化方法在功能—技术矩阵求解中的应用     

罗庆生  韩宝玲 《武汉大学学报(信息科学版)》1990,(2)

功能—技术矩阵,经众多工作者的努力研究,已渐趋成熟与实用。但如何利用功能—技术矩阵构造在广义现代设计领域中适用的科学模式,解决多学科设计方案的组成与评价问题,还存在薄弱环节。本文利用“使用价值分析优化”的概念,从设计方案技术先进性和经济合理性的协调统一的角度出发,较好地实现了功能—技术矩阵可行优化组合链的组成与评价,弥补了以往的缺陷。  相似文献   

Are the South and North Liaohe Groups of North China Craton different exotic terranes? Nd isotope constraints   总被引：29，自引：1，他引：29  

Sanzhong Li  Guochun Zhao  Min Sun  Zongzhu Han  Guangtao Zhao  Defeng Hao 《Gondwana Research》2006,9(1-2):198

The Liaohe Group is an important Paleoproterozoic stratigraphic unit in the northeastern part of the North China Craton and is traditionally subdivided into the North and South Liaohe Groups. Associated with both the North and South Liaohe Groups are voluminous Paleoproterozoic granitoid rocks, named the Liaoji granitoids. Different tectonic models, including terrane amalgamation, continent–arc collision and rift closure, have been proposed to interpret the tectonic setting and evolution of the North and South Liaohe Groups and associated Liaoji granitoids. At the centre of the controversy between these models is whether or not the North and South Liaohe Groups developed on the same Archean basement. Nd isotopic geochemistry of the Liaoji granitoids provides important constraints on this controversial issue. The Liaoji granitoids associated with the North and South Liaohe Groups display similar ε_Nd values, restricted to a narrow range from 0 to 2, implying that these granitoid rocks were derived from the same or a similar magma source. Moreover, the Liaoji granitoids associated with the North and South Liaohe Groups have similar Nd model ages (T_DM), ranging from 2.4 to 2.6 Ga, suggesting that the protoliths of the Liaoji granitoids associated with both groups may have formed simultaneously, and that the basement rocks underneath the Liaoji granitoids and associated North and South Liaohe Groups belong to the same continental block rather than two different blocks. Combining lithological, structural and geochronological considerations, we interpret the North and South Liaohe Groups as having developed on a single late Archean basement that underwent Paleoproterozoic rifting associated with the intrusion of the Liaoji granitoids and the formation of the Liaohe Group, and closed upon itself in the Paleoproterozoic.  相似文献   

The Wuchiapingian–Changhsingian boundary (Upper Permian) at Meishan of Changxing County, South China     

Wang Yue  Shen Shuzhong  Cao Changqun  Wang Wei  Charles Henderson  Jin Yugan   《Journal of Asian Earth Sciences》2006,26(6):575-583

Section D at Meishan, Changxing County in the Zhejiang Province, China, has been extensively studied in various aspects of the stratigraphy during the past 20 years. It was ratified by the International Union of Geological Sciences (IUGS) as the Global Standard Stratotype Section and Point (GSSP) for the Permian–Triassic boundary in 2000, and is also a potential stratotype for the Wuchiapingian–Changhsingian boundary. However, the contact relationship between the Longtan (Wuchiapingian) and Changxing (Chainghsingian) formations has been a controversial subject for years. Recent studies on Section C, about 300 m west of Section D, at Meishan confirm a complete depositional succession around the boundary and suggest that the proposed boundary level, the FAD of Clarkina wangi within the lineage from C. longicuspidata to C. wangi, is consistent with the first appearance of the index Changhsingian fusulinid Palaeofusulina sinensis and tapashanitid ammonoids.  相似文献