New insights into the heterogeneity of the Tagish Lake meteorite: Soluble organic compositions of variously altered specimens     

Danielle N. Simkus  Jos C. Aponte  Jamie E. Elsila  Robert W. Hilts  Hannah L. McLain  Christopher D. K. Herd 《Meteoritics & planetary science》2019,54(6):1283-1302

The Tagish Lake carbonaceous chondrite exhibits a unique compositional heterogeneity that may be attributed to varying degrees of aqueous alteration within the parent body asteroid. Previous analyses of soluble organic compounds from four Tagish Lake meteorite specimens (TL5b, TL11h, TL11i, TL11v) identified distinct distributions and isotopic compositions that appeared to be linked to their degree of parent body processing (Herd et al. 2011; Glavin et al. 2012; Hilts et al. 2014). In the present study, we build upon these initial observations and evaluate the molecular distribution of amino acids, aldehydes and ketones, monocarboxylic acids, and aliphatic and aromatic hydrocarbons, including compound‐specific δ¹³C compositions, for three additional Tagish Lake specimens: TL1, TL4, and TL10a. TL1 contains relatively high abundances of soluble organics and appears to be a moderately altered specimen, similar to the previously analyzed TL5b and TL11h lithologies. In contrast, specimens TL4 and TL10a both contain relatively low abundances of all of the soluble organic compound classes measured, similar to TL11i and TL11v. The organic‐depleted composition of TL4 appears to have resulted from a relatively low degree of parent body aqueous alteration. In the case of TL10a, some unusual properties (e.g., the lack of detection of intrinsic monocarboxylic acids and aliphatic and aromatic hydrocarbons) suggest that it has experienced extensive alteration and/or a distinct organic‐depleted alteration history. Collectively, these varying compositions provide valuable new insights into the relationships between asteroidal aqueous alteration and the synthesis and preservation of soluble organic compounds.  相似文献   

Potassium isotopic compositions of enstatite meteorites     

Chen Zhao  Katharina Lodders  Hannah Bloom  Heng Chen  Zhen Tian  Piers Koefoed  Mria K. Pet&#x;  Kun Wang 《Meteoritics & planetary science》2020,55(6):1404-1417

Enstatite chondrites and aubrites are meteorites that show the closest similarities to the Earth in many isotope systems that undergo mass‐independent and mass‐dependent isotopic fractionations. Due to the analytical challenges to obtain high‐precision K isotopic compositions in the past, potential differences in K isotopic compositions between enstatite meteorites and the Earth remained uncertain. We report the first high‐precision K isotopic compositions of eight enstatite chondrites and four aubrites and find that there is a significant variation of K isotopic compositions among enstatite meteorites (from ?2.34‰ to ?0.18‰). However, K isotopic compositions of nearly all enstatite meteorites scatter around the bulk silicate earth (BSE) value. The average K isotopic composition of the eight enstatite chondrites (?0.47 ± 0.57‰) is indistinguishable from the BSE value (?0.48 ± 0.03‰), thus further corroborating the isotopic similarity between Earth's building blocks and enstatite meteorite precursors. We found no correlation of K isotopic compositions with the chemical groups, petrological types, shock degrees, and terrestrial weathering conditions; however, the variation of K isotopes among enstatite meteorite can be attributed to the parent‐body processing. Our sample of the main‐group aubrite MIL 13004 is exceptional and has an extremely light K isotopic composition (δ⁴¹K = ?2.34 ± 0.12‰). We attribute this unique K isotopic feature to the presence of abundant djerfisherite inclusions in our sample because this K‐bearing sulfide mineral is predicted to be enriched in ³⁹K during equilibrium exchange with silicates.  相似文献   

Modeling Magnetic Tower Jets in the Laboratory     

A. Ciardi  S. V. Lebedev  J. P. Chittenden  D. J. Ampleford  S. N. Bland  B. S. Bott  J. Rapley 《Astrophysics and Space Science》2005,298(1-2):277-286

The twisting of magnetic fields threading an accretion system can lead to the generation on axis of toroidal field loops. As the magnetic pressure increases, the toroidal field inflates, producing a flow. Collimation is due to a background corona, which radially confines this axially growing “magnetic tower”. We investigate the possibility of studying in the laboratory the dynamics, confinement and stability of magnetic tower jets. We present two-dimensional resistive magnetohydrodynamic simulations of radial arrays, which consist of two concentric electrodes connected radially by thin metallic wires. In the laboratory, a radial wire array is driven by a 1 MA current which produces a hot, low density background plasma. During the current discharge a low plasma beta (β < 1), magnetic cavity develops in the background plasma (β is the ratio of thermal to magnetic pressure). This laboratory magnetic tower is driven by the magnetic pressure of the toroidal field and it is surrounded by a shock envelope. On axis, a high density column is produced by the pinch effect. The background plasma has >rsim1, and in the radial direction the magnetic tower is confined mostly by the thermal pressure. In contrast, in the axial direction the pressure rapidly decays and an elongated, well collimated magnetic-jet develops. This is later disrupted by the development of m = 0 instabilities arising in the axial column.  相似文献   

Magnetic tower outflows from a radial wire array Z-pinch     

S. V. Lebedev  A. Ciardi  D. J. Ampleford  S. N. Bland  S. C. Bott  J. P. Chittenden  G. N. Hall  J. Rapley  C. A. Jennings  A. Frank  E. G. Blackman  T. Lery 《Monthly notices of the Royal Astronomical Society》2005,361(1):97-108

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The effect of pH and ionic strength on proton adsorption by the thermophilic bacterium Anoxybacillus flavithermus     

Peta-Gaye Burnett  Hannah Heinrich  Phil J. Bremer  Christopher J. Daughney 《Geochimica et cosmochimica acta》2006,70(8):1914-1927

Numerous studies have utilized surface complexation theory to model proton adsorption behaviour onto mesophilic bacteria. However, few experiments, to date, have investigated the effects of pH and ionic strength on proton interactions with thermophilic bacteria. In this study, we characterize proton adsorption by the thermophile Anoxybacillus flavithermus by performing acid-base titrations and electrophoretic mobility measurements in NaNO₃ (0.001-0.1 M). Equilibrium thermodynamics (Donnan model) were applied to describe the specific chemical reactions that occur at the water-bacteria interface. Acid-base titrations were used to determine deprotonation constants and site concentrations for the important cell wall functional groups, while electrophoretic mobility data were used to further constrain the model. We observe that with increasing pH and ionic strength, the buffering capacity increases and the electrophoretic mobility decreases. We develop a single surface complexation model to describe proton interactions with the cells, both as a function of pH and ionic strength. Based on the model, the acid-base properties of the cell wall of A. flavithermus can best be characterized by invoking three distinct types of cell wall functional groups, with pK_a values of 4.94, 6.85, and 7.85, and site concentrations of 5.33, 1.79, and 1.42 × 10⁻⁴ moles per gram of dry bacteria, respectively. A. flavithermus imparts less buffering capacity than pure mesophilic bacteria studied to date because the thermophile possesses a lower total site density (8.54 × 10⁻⁴ moles per dry gram bacteria).  相似文献   

Continuous field estimation of dissolved organic carbon concentration and biochemical oxygen demand using dual‐wavelength fluorescence,turbidity and temperature          下载免费PDF全文

Kieran Khamis  Chris Bradley  Rob Stevens  David M. Hannah 《水文研究》2017,31(3):540-555

Dissolved organic matter (DOM) quality and quantity is not measured routinely in‐situ limiting our ability to quantify DOM process dynamics. This is problematic given legislative obligations to determine event based variability; however, recent advances in field deployable optical sensing technology provide the opportunity to address this problem. In this paper, we outline a new approach for in‐situ quantification of DOM quantity (Dissolved Organic Carbon: DOC) and a component of quality (Biochemical Oxygen Demand: BOD) using a multi‐wavelength, through‐flow fluorescence sensor. The sensor measured tryptophan‐like (Peak T) and humic‐like (Peak C) fluorescence, alongside water temperature and turbidity. Laboratory derived coefficients were developed to compensate for thermal quenching and turbidity interference (i.e., light attenuation and scattering). Field tests were undertaken on an urban river with ageing wastewater and stormwater infrastructure (Bourn Brook; Birmingham, UK). Sensor output was validated against laboratory determinations of DOC and BOD collected by discrete grab sampling during baseflow and stormflow conditions. Data driven regression models were then compared to laboratory correction methods. A combination of temperature and turbidity compensated Peak T and Peak C was found to be a good predictor of DOC concentration (R² = 0.92). Conversely, using temperature and turbidity correction coefficients provided low predictive power for BOD (R² = 0.46 and R² = 0.51, for Peak C and T, respectively). For this study system, turbidity appeared to be a reasonable proxy for BOD, R² = 0.86. However, a linear mixed effect model with temperature compensated Peak T and turbidity provided a robust BOD prediction (R² = 0.95). These findings indicate that with careful initial calibration, multi‐wavelength fluorescence, coupled with turbidity, and temperature provides a feasible proxy for continuous, in‐situ measurement of DOC concentration and BOD. This approach represents a cost effective monitoring solution, particularly when compared to UV – absorbance sensors and DOC analysers, and could be readily adopted for research and industrial applications.  相似文献   

Floods in the Southern Alps of New Zealand: the importance of atmospheric rivers          下载免费PDF全文

Daniel. G. Kingston  David A. Lavers  David M. Hannah 《水文研究》2016,30(26):5063-5070

Extremely high precipitation occurs in the Southern Alps of New Zealand, associated with both orographic enhancement and synoptic‐scale weather processes. In this study, we test the hypothesis that atmospheric rivers (ARs) are a key driver of floods in the Southern Alps of New Zealand. Vertically integrated water vapour and horizontal water vapour transport, and atmospheric circulation, are investigated concurrently with major floods on the Waitaki River (a major South Island river). Analysis of the largest eight winter maximum floods between 1979 and 2012 indicates that all are associated with ARs. Geopotential height fields reveal that these ARs are located in slow eastward moving extratropical cyclones, with high pressure to the northeast of New Zealand. The confirmation of ARs as a contributor to Waitaki flooding indicates the need for their further exploration to better understand South Island hydrometeorological extremes. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

The Alpine nappe stack in western Austria: a crustal-scale cross section     

Hannah Pomella  Hugo Ortner  Michael Zerlauth  Bernhard Fügenschuh 《International Journal of Earth Sciences》2015,104(3):733-745

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Application of hybrid numerical and analytical solutions for the simulation of coupled thermal,hydraulic, mechanical and chemical processes during fluid flow through a fractured rock     

Christopher McDermott  Alexander Bond  Andrew Fraser Harris  Neil Chittenden  Kate Thatcher 《Environmental Earth Sciences》2015,74(12):7837-7854

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Wildfire-Migration Dynamics: Lessons from Colorado's Fourmile Canyon Fire     

Raphael J. Nawrotzki  Hannah Brenkert-Smith  Lori M. Hunter  Patricia A. Champ 《社会与自然资源》2014,27(2):215-225

The number of people living in wildfire-prone wildland–urban interface (WUI) communities is on the rise. However, no prior study has investigated wildfire-induced residential relocation from WUI areas after a major fire event. To provide insight into the association between sociodemographic and sociopsychological characteristics and wildfire-related intention to move, we use data from a survey of WUI residents in Boulder and Larimer counties, Colorado. The data were collected 2 months after the devastating Fourmile Canyon fire destroyed 169 homes and burned more than 6,000 acres of public and private land. Although this study is working with a small migrant sample, logistic regression models demonstrate that survey respondents intending to move in relation to wildfire incidence do not differ sociodemographically from their nonmigrant counterparts. They do, however, show significantly higher levels of risk perception. Investigating destination choices shows a preference for short-distance moves.  相似文献