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81.
82.
Natrocarbonatitic magmas are characterized by their extremely low viscosities and fast elemental diffusion, and as a consequence
of this, their chemistry and crystallinity can change significantly during residence in shallow reservoirs or even due to
cooling during lava flow emplacement. Here, we present the results of a series of crystallization experiments conducted at
1-atm confining pressure and in a temperature range between 630°C and 300°C. The experiments were set up to characterize the
chemistry and growth processes of the phenocryst phases present in natrocarbonatites. The results are applicable to (1) processes
occurring during residence in shallow magma reservoirs and/or (2) during lava flow emplacement. We show that during crystallization
of natrocarbonatites at atmospheric pressure, gregoryite is the first mineral to crystallize at 630°C, followed by nyerereite
at 595°C. Crystal size distributions of the gregoryites show that the crystals grow rapidly by textural coarsening (i.e.,
Ostwald ripening). As the crystallization is a continuous process at this pressure, the composition of the residual melt changes
in response to the crystallization. However, the experiments also show that individual crystals completely reequilibrate with
the changes in melt composition in as little time as <11 min. We therefore conclude that crystallization and diffusion are
extremely fast processes in the natrocarbonatitic system and that the measured chemical variations in phenocrysts from Oldoinyo
Lengai can be explained by different cooling histories. Finally, we model the rheological control on the emplacement of highly
crystallized natrocarbonatitic lavas at Oldoinyo Lengai. 相似文献
83.
Hans Burchard Frank Janssen Karsten Bolding Lars Umlauf Hannes Rennau 《Continental Shelf Research》2009
Only recently, medium intensity inflow events into the Baltic Sea have gained more awareness because of their potential to ventilate intermediate layers in the Southern Baltic Sea basins. With the present high-resolution model study of the Western Baltic Sea a first attempt is made to obtain model based realistic estimates of turbulent mixing in this area where dense bottom currents resulting from medium intensity inflow events are weakened by turbulent entrainment. The numerical model simulation which is carried out using the General Estuarine Transport Model (GETM) during nine months in 2003 and 2004 is first validated by means of three automatic stations at the Drogden and Darss Sills and in the Arkona Sea. In order to obtain good agreement between observations and model results, the 0.5×0.5 nautical mile bathymetry had to be adjusted in order to account for the fact that even at that scale many relevant topographic features are not resolved. Current velocity, salinity and turbulence observations during a medium intensity inflow event through the Øresund are then compared to the model results. Given the general problems of point to point comparisons between observations and model simulations, the agreement is fairly good with the characteristic features of the inflow event well represented by the model simulations. Two different bulk measures for mixing activity are then introduced, the vertically integrated decay of salinity variance, which is equal to the production of micro-scale salinity variance, and the vertically integrated turbulent salt flux, which is related to an increase of potential energy due to vertical mixing of stably stratified flow. Both measures give qualitatively similar results and identify the Drogden and Darss Sills as well as the Bornholm Channel as mixing hot spots. Further regions of strong mixing are the dense bottom current pathways from these sills into the Arkona Sea, areas around Kriegers Flak (a shoal in the western Arkona Sea) and north–west of the island of Rügen. 相似文献
84.
Hannes Laermanns Mikheil Elashvili Giorgi Kirkitadze Christopher P. Loveluck Simon Matthias May Daniel Kelterbaum Revaz Papuashvili Helmut Brückner 《Geoarchaeology》2024,39(3):335-350
Along the lower course of the Rioni and several minor rivers, more than 70 settlement mounds (local name: Dikhagudzuba) have been identified by field surveys and remote sensing techniques. They give evidence of a formerly densely populated landscape in the coastal lowlands on the Colchian plain (western Georgia) and have been dated to the Bronze Age. As yet, limited information is available on their internal architecture, the chronology of the different layers and their palaeoenvironmental context. Based on archaeological sources, remote sensing measurements of three mounds and sediment cores from one mound and its closer surroundings, our study presents a review of the relevant literature and reveals the internal structure, distribution and spatial extent of the mounds. Geochemical and sedimentological analyses of element contents (X-ray fluorescence) and granulometry helped to identify different stratigraphical layers and differentiate between natural facies and anthropogenic deposits; using the Structure-from-Motion technique the mounds' dimensions were calculated. The studied settlement mounds had relatively small dimension (varying from 30 to 100 m in diameter) and were similar in their stratigraphy. Measurement of elements that can identify types of human activity, notably metals and phosphorus, suggest changing intensities of human occupation, pastoral agriculture and metalworking through the occupation sequence. According to the 14C chronology, the formation of the settlements occurred during the first half of the second millennium B.C., which confirms the archaeological interpretation of their Bronze Age origin. The narrow age difference between the lowermost and uppermost anthropogenic layers indicates an intentional construction of the mounds, rather than a successive accumulation of construction debris due to the disintegration of loam bricks by weathering. Therefore, they are indeed mounds and not tells. It is most likely that the characteristic circular moats that surround them were the source of their construction material. Fluvial and alluvial processes in a warm and humid climate dominated the environment of the mounds. 相似文献
85.
Hannes Taubenböck Michael Wurm Christian Geiß Stefan Dech Stefan Siedentop 《International Journal of Digital Earth》2019,12(6):679-698
Measuring spatial patterns is a crucial task in spatial sciences. Multiple indicators have been developed to measure patterns in a quantitative manner. However, most comparative studies rely on relative comparisons, limiting their explanatory power to specific case studies. Motivated by advancements in earth observation providing unprecedented resolutions of settlement patterns, this paper suggests a measurement technique for spatial patterns to overcome the limits of relative comparisons. We design a model spanning a feature space based on two metrics – largest patch index and number of patches. The feature space is defined as ‘dispersion index’ and covers the entire spectrum of possible two-dimensional binary (settlement) patterns. The model configuration allows for an unambiguous ranking of each possible pattern with respect to spatial dispersion. As spatial resolutions of input data as well as selected areas of interest influence measurement results, we test dependencies within the model. Beyond, common other spatial metrics are selected for testing whether they allow unambiguous rankings. For scenarios, we apply the model to artificially generated patterns representing all possible configurations as well as to real-world settlement classifications differing in growth dynamics and patterns. 相似文献
86.
Dissolved organic matter dynamics during the spring snowmelt at a boreal river valley mire complex in Northwest Russia
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Armine Avagyan Benjamin R. K. Runkle Nina Hennings Hannes Haupt Tarmo Virtanen Lars Kutzbach 《水文研究》2016,30(11):1727-1741
Boreal mire landscapes are rich in soil carbon and significantly contribute to the carbon input of aquatic ecosystems. They are composed of different mesoscale ecohydrological subunits, whose individual contributions to the water and carbon export of mire catchments are not well understood. The spring snowmelt period is the major hydrological event in the annual water cycle of the boreal regions and strongly influences the carbon flux between the terrestrial and aquatic systems. The aim of this study was (1) to provide a conceptual understanding of the spatial and temporal dynamics of the surface water chemistry along a swamp forest‐fen‐bog gradient during the snowmelt period, (2) to quantify the exported dissolved organic carbon (DOC) content in the runoff and (3) to identify the ecohydrological landscape unit that contributes most to DOC export during the snowmelt period in a heterogeneous mire complex in Northwest Russia. The highest DOC concentrations were detected in the swamp forest, and the lowest concentrations were observed at the treeless bog by the end of the snowmelt period (swamp forest: 37–43 mg l?1, bog: 13–17 mg l?1). During the spring snowmelt period, a significant amount (~1.7 g C m?2) of DOC was transferred by the ~74 mm of runoff from the catchment into the river. Variability in the thawing periods led to differences in the relative contributions of each ecohydrological zone to the carbon export measured at a stream channel draining the studied part of the mire complex. An increased understanding of the variation in DOC concentrations and contributions from the mesoscale ecohydrological subunits to carbon export can help to predict the potential regional loss of DOC based on land cover type under climate change. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
87.
Juraj Majzlan Hannes Schlicht Maria Wierzbicka-Wieczorek Gerald Giester Herbert Pöllmann Beatrix Brömme Stephen Doyle Gernot Buth Christian Bender Koch 《Mineralogy and Petrology》2013,107(2):221-233
Voltaite is a mineral of fumaroles, solfatares, coal-fire gas vents, and acid-mine drainage systems. The nominal composition is K2Fe5 2+Fe3 3+Al(SO4)12·18H2O and the nominal symmetry is cubic, $Fd\overline{3}c$ . The tetragonal (I41/acd) superstructure of voltaite is known as the mineral pertlikite. In this study, we investigated 22 synthetic voltaite samples in which Fe2+ was partially or completely replaced by Mg, Zn, Mn, or Cd, by single-crystal and powder X-ray diffraction (both in-house and synchrotron). Two samples contained NH4 + instead of K+. The structure of voltaite is based on a framework defined by kröhnkite-like heteropolyhedral chains which host both M3+ and M2+ in octahedral coordination. Unit cell dimensions of the end-members scale almost linearly with the size of M2+. In the Fe2+-Mg-Zn solid solutions, the Fe2+-Mg and Fe2+-Zn solutions are linear (ideal) in terms of their lattice-parameter variations. The Mg-Zn solid solution, however, is strongly non-ideal. A detailed analysis of the topology of the chains showed that this behavior originates in expansion and contraction of individual M2+-O bonds within the chains. In the Mg-Zn solid solution, some of the M2+-O bonds expand while none contract. In the other solid solutions, expansion of some M2+-O bonds is always compensated by contraction of the other ones. Parts of the nominally cubic crystals are optically anisotropic and their symmetry is found to be tetragonal by single crystal X-ray diffraction measurements. The coexistence of cubic and tetragonal sectors within a single crystal without any detectable difference in their chemical composition is difficult to explain in terms of growth of such composite crystals. Mössbauer and infrared spectra collected on our synthetic crystals conform with previously published data. 相似文献
88.
The spatialCopula toolbox contains a set of Matlab functions that provides utilities for copula-based analysis of spatially referenced data, a topic which has re cently attracted much attention in spatial statistics. These tools have been developed to support the work flow in parameter estimation, spatial interpolation and visualization. They offer flexible and user-friendly software for dealing with non-Gaussian and extreme value data that possibly contain a spatial trend or geometric anisotropy. The objective of this paper is to give an introduction to the concept behind the software and to outline the functionality of the toolbox. We illustrate its usefulness by analyzing a data set here referred to as the Gomel data set, which includes moderately skewed radioactivity measurements in the region of Gomel, Belarus. The source codes are freely available in Matlab language on the author’s website (fam.tuwien.ac.at/~hakazian/software.html). 相似文献
89.
Wannenmacher Helmut Entfellner Manuel Hauer Hannes 《Geotechnical and Geological Engineering》2022,40(9):4377-4391
Geotechnical and Geological Engineering - The Semmering Base Tunnel (SBT), with a total length of 27.3 km, is one of the leading construction projects of the Baltic-Adriatic Railway... 相似文献
90.
To better understand the role of the German Bight (GB) as a nursery area for juvenile North Sea sprat Sprattus sprattus we sought to determine whether the area may receive only locally or also externally produced offspring. We sampled juveniles during 3 trawl surveys in the GB in August, September, and October 2004 and applied otolith microstructure analysis in order to reconstruct their distributions of the day-of-first-increment-formation (dif). These were contrasted with spatial and seasonal patterns of sprat egg abundance in the GB and its adjacent areas, observed during 6 monthly plankton surveys. It was found that the majority of juveniles originated mainly from April/May 2004, coinciding with high spawning activity west of the GB, whereas spawning and larval production inside the GB peaked notably later, in May/June. This indicated that a large proportion of juveniles was produced outside the GB and transported subsequently into it through passive and/or active migration. Shifts to later mean difs from one survey to the next and length distributions indicative of the simultaneous presence of multiple cohorts, supported the notion that the GB is a complex retention and nursery area for sprat offspring from different North Sea spawning grounds and times. Later born juveniles had significantly faster initial growth rates than earlier born conspecifics, which was likely temperature-mediated, given the strong correlation between back-calculated growth histories and sea surface temperature as a proxy for thermal histories of juveniles (r2 = 0.52). 相似文献