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151.
Alexander V. Krivov Ingo WardinskiFrank Spahn Harald KrügerEberhard Grün 《Icarus》2002,157(2):436-455
The outer region of the jovian system between ∼50 and 300 jovian radii from the planet is found to be the host of a previously unknown dust population. We used the data from the dust detector aboard the Galileo spacecraft collected from December 1995 to April 2001 during Galileo's numerous traverses of the outer jovian system. Analyzing the ion amplitudes, calibrated masses and speeds of grains, and impact directions, we found about 100 individual events fully compatible with impacts of grains moving around Jupiter in bound orbits. These grains have moderate eccentricities and a wide range of inclinations—from prograde to retrograde ones. The radial number density profile of the micrometer-sized dust is nearly flat between about 50 and 300 jovian radii. The absolute number density level (∼10 km−3 with a factor of 2 or 3 uncertainty) surpasses by an order of magnitude that of the interplanetary background. We identify the sources of the bound grains with outer irregular satellites of Jupiter. Six outer tiny moons are orbiting the planet in prograde and fourteen in retrograde orbits. These moons are subject to continuous bombardment by interplanetary micrometeoroids. Hypervelocity impacts create ejecta, nearly all of which get injected into circumjovian space. Our analytic and numerical study of the ejecta dynamics shows that micrometer-sized particles from both satellite families, although strongly perturbed by solar tidal gravity and radiation pressure, would stay in bound orbits for hundreds of thousands of years as do a fraction of smaller grains, several tenths of a micrometer in radius, ejected from the prograde moons. Different-sized ejecta remain confined to spheroidal clouds embracing the orbits of the parent moons, with appreciable asymmetries created by the radiation pressure and solar gravity perturbations. Spatial location of the impacts, mass distribution, speeds, orbital inclinations, and number density of dust derived from the data are all consistent with the dynamical model. 相似文献
152.
This paper addresses the problem of classifying minerals common in siliciclastic and carbonate rocks. Twelve chemical elements are mapped from thin sections by energy dispersive spectroscopy in a scanning electron microscope (SEM). Extensions to traditional multivariate statistical methods are applied to perform the classification. First, training and validation sets are grown from one or a few seed points by a method that ensures spatial and spectral closeness of observations. Spectral closeness is obtained by excluding observations that have high Mahalanobis distances to the training class mean. Spatial closeness is obtained by requesting connectivity. Second, class consistency is controlled by forcing each class into 5–10 subclasses and checking the separability of these subclasses by means of canonical discriminant analysis. Third, class separability is checked by means of the Jeffreys–Matusita distance and the posterior probability of a class mean being classified as another class. Fourth, the actual classification is carried out based on four supervised classifiers all assuming multinormal distributions: simple quadratic, a contextual quadratic, and two hierarchical quadratic classifiers. Overall weighted misclassification rates for all quadratic classifiers are very low for both the training (0.25–0.33%) and validation sets (0.65–1.13%). Finally, the number of rejected observations in routine runs is checked to control the performance of the SEM image acquisition and the classification. Although the contextual classifier performs marginally best on the validation set, the simple quadratic classifier is chosen in routine classifications because of the lower processing time required. The method is presently used as a routine petrographical analysis method at Norsk Hydro Research Centre. The data can be approximated by a Poisson distribution. Accordingly, the square root of the data has constant variance and a linear classifier can be used. Near orthogonal input data, enable the use of a minimum distance classifier. Results from both linear and quadratic minimum distance classifications are described briefly. 相似文献
153.
Pascal Richet Alan Whittington François Holtz Harald Behrens Susanne Ohlhorst Max Wilke 《Contributions to Mineralogy and Petrology》2000,138(4):337-347
A review of published and newly measured densities for 40 hydrous silicate glasses indicates that the room-temperature partial
molar volume of water is 12.0 ± 0.5 cm3/mol. This value holds for simple or mineral compositions as well as for complex natural glasses, from rhyolite to tephrite
compositions, prepared up to 10–20 kbar pressures and containing up to 7 wt% H2O. This volume does not vary either with the molar volume of the water-free silicate phase, with its degree of polymerization
or with water speciation. Over a wide range of compositions, this constant value implies that the volume change for the reaction
between hydroxyl ions and molecular water is zero and that, at least in glasses, speciation does not depend on pressure. Consistent
with data from Ochs and Lange (1997, 1999), systematics in volume expansion for SiO2–M2O systems (M=H, Li, Na, K) suggests that the partial molar thermal expansion coefficient of H2O is about 4 × 10−5 K−1 in silicate glasses.
Received: 30 June 1999 / Accepted: 5 November 1999 相似文献
154.
Kristie L. Ebi Stephane Hallegatte Tom Kram Nigel W. Arnell Timothy R. Carter Jae Edmonds Elmar Kriegler Ritu Mathur Brian C. O’Neill Keywan Riahi Harald Winkler Detlef P. Van Vuuren Timm Zwickel 《Climatic change》2014,122(3):363-372
The scientific community is developing new global, regional, and sectoral scenarios to facilitate interdisciplinary research and assessment to explore the range of possible future climates and related physical changes that could pose risks to human and natural systems; how these changes could interact with social, economic, and environmental development pathways; the degree to which mitigation and adaptation policies can avoid and reduce risks; the costs and benefits of various policy mixes; and the relationship of future climate change adaptation and mitigation policy responses with sustainable development. This paper provides the background to and process of developing the conceptual framework for these scenarios, as described in the three subsequent papers in this Special Issue (Van Vuuren et al., 2013; O’Neill et al., 2013; Kriegler et al., Submitted for publication in this special issue). The paper also discusses research needs to further develop, apply, and revise this framework in an iterative and open-ended process. A key goal of the framework design and its future development is to facilitate the collaboration of climate change researchers from a broad range of perspectives and disciplines to develop policy- and decision-relevant scenarios and explore the challenges and opportunities human and natural systems could face with additional climate change. 相似文献
155.
Marc Peters Harald Strauss Sven Petersen Nicolai-Alexeji Kummer Christophe Thomazo 《Chemical Geology》2011,280(1-2):217-231
The Palinuro volcanic complex and the Panarea hydrothermal field, both located in the Tyrrhenian Sea (Italy), are associated with island arc magmatism and characterized by polymetallic sulfide mineralization. Dissolved sulfide concentrations, pH, and Eh measured in porewaters at both sites reveal a variable hydrothermal influence on porewater chemistry.Multiple sulfur isotopic measurements for disseminated sulfides (CRS: chromium reducible sulfur) extracted from sediments at Palinuro yielded a broad range in δ34S range between ?29.8 and + 10.2‰ and Δ33S values between + 0.015 and + 0.134‰. In contrast, sediments at Panarea exhibit a much smaller range in δ34SCRS with less negative values between ?11.3 and ?1.8‰. The sulfur isotope signatures are interpreted to reflect a mixture between hydrothermal and biogenic sulfide, with a more substantial biogenic contribution at Panarea.Multiple sulfur isotope measurements were performed on sulfides and elemental sulfur from drill core material from the Palinuro massive sulfide complex. δ34S and Δ33S values for pyrite between ?32.8 and ?1.1‰ and between ?0.012 to + 0.042‰, respectively, as well as for elemental sulfur with δ34S and Δ33S values between ?26.7 and ?2.1‰ and between + 0.035 and + 0.109‰, respectively, point to a microbial origin for much of the sulfide and elemental sulfur studied. Moreover, data suggest a coupling of bacterial sulfate reduction, sulfide oxidation and sulfur disproportionation. In addition, δ34S values for barite between + 25.0 and + 63.6‰ are also in agreement with high microbial turnover of sulfate at Palinuro.Although a magmatic SO2 contribution towards the formation of the Palinuro massive sulfide complex is very likely, the activity of different sulfur utilizing microorganisms played a fundamental role during its formation. Thus, porewater and multiple sulfur isotope data reveal differences in the hydrothermal activity at Palinuro and Panarea drill sites and underline the importance of microbial communities for the origin of massive sulfide mineralizations in the hydrothermal subsurface. 相似文献
156.
Electrical conductivity of hydrous basaltic melts: implications for partial melting in the upper mantle 总被引:1,自引:0,他引:1
Huaiwei Ni Hans Keppler Harald Behrens 《Contributions to Mineralogy and Petrology》2011,162(3):637-650
The Earth’s uppermost asthenosphere is generally associated with low seismic wave velocity and high electrical conductivity.
The electrical conductivity anomalies observed from magnetotelluric studies have been attributed to the hydration of mantle
minerals, traces of carbonatite melt, or silicate melts. We report the electrical conductivity of both H2O-bearing (0–6 wt% H2O) and CO2-bearing (0.5 wt% CO2) basaltic melts at 2 GPa and 1,473–1,923 K measured using impedance spectroscopy in a piston-cylinder apparatus. CO2 hardly affects conductivity at such a concentration level. The effect of water on the conductivity of basaltic melt is markedly
larger than inferred from previous measurements on silicate melts of different composition. The conductivity of basaltic melts
with more than 6 wt% of water approaches the values for carbonatites. Our data are reproduced within a factor of 1.1 by the
equation log σ = 2.172 − (860.82 − 204.46 w
0.5)/(T − 1146.8), where σ is the electrical conductivity in S/m, T is the temperature in K, and w is the H2O content in wt%. We show that in a mantle with 125 ppm water and for a bulk water partition coefficient of 0.006 between
minerals and melt, 2 vol% of melt will account for the observed electrical conductivity in the seismic low-velocity zone.
However, for plausible higher water contents, stronger water partitioning into the melt or melt segregation in tube-like structures,
even less than 1 vol% of hydrous melt, may be sufficient to produce the observed conductivity. We also show that ~1 vol% of
hydrous melts are likely to be stable in the low-velocity zone, if the uncertainties in mantle water contents, in water partition
coefficients, and in the effect of water on the melting point of peridotite are properly considered. 相似文献
157.
158.
In the initial period of mining activities in the Idrija basin (the16th and the first half of the17th centuries), Hg ore processing was performed at various small-scale roasting sites in the woods surrounding Idrija, by roasting ore in earthen vessels. The recovery rate of this method was very low; about half of Hg was lost, causing soil contamination and considerable amounts of waste material that could potentially leach Hg into the surrounding environment. The main aims of present geochemical study were to determine the contents, vertical distribution and speciation of Hg in soils at the roasting site at Frbej?ene trate in order to verify the extreme pollution of ancient Hg ore roasting sites in the Idrija area and to establish their significance in the wider spatial contamination of soils and aquatic systems. Soil sampling was performed at the area of the former roasting site. The organic matter-rich surface soil layer (SOM) and underlying mineral soil were sampled at 63 sampling locations. Mercury speciation was performed using Hg thermo-desorption-AAS to distinguish cinnabar from potentially bioavailable forms. The results indicate extremely high Hg concentrations with a maximum of 37,000 mg/kg in SOM and 19,900 mg/kg in mineral soil. The established Hg median in soil was 370 mg/kg and in SOM 96.3 mg/kg. Spatial distributions of Hg in SOM and soil showed very high Hg contents in the central area and decreased rapidly with distance. The results of Hg thermo-desorption measurements indicated the presence of cinnabar (HgS) and Hg bound to organic or mineral soil matter. A significant portion (35–40%) of Hg in the investigated soil and SOM samples was comprised of non-cinnabar compounds, which are potentially bioavailable. It has been shown that soils contain high amounts of potentially transformable non-cinnabar Hg, which is available for surface leaching and runoff into the surrounding environment. Therefore, contaminated soils and roasted residues at the studied area are important for persistent Hg release into the aquatic ecosystem. 相似文献
159.
Meteorological effects on seasonal displacements of the ?knes rockslide, western Norway 总被引:1,自引:1,他引:0
In the alpine topography along one of the long fjords with steep and high mountain sides in western Norway the large ?knes
rockslide area is defined by a distinct back scarp rising from 800 to 1,000 m a.s.l. In 2004, an extensive monitoring program
started, including establishment of a meteorological station above the upper tension crack, 900 m a.s.l. This paper evaluates
the significance of meteorological conditions affecting the displacements recorded by five extensometers and two laser sensors
in the tension crack from November 2004 to August 2008. Meteorological factors of importance for the recorded activity in
the tension crack are found to be melt water in spring and large temperature fluctuations around the freezing point in spring,
autumn, and early winter. The records show less acceleration phases in the measured distance across the tension crack in the
second half of the analyzed period even though annual displacements are increasing, indicating that other processes, like
disintegration of irregularities along unfilled joints and disintegration of intact rock bridges in the sliding plane have
become more important. 相似文献
160.
Key factors affecting the future provision of tree-based forest ecosystem goods and services 总被引:1,自引:0,他引:1
The continuous provisioning of forest ecosystem goods and services (EGS) is of considerable interest to society. To provide insights on how much EGS provision will change with a changing climate and which factors will influence this change the most, we simulated forest stands on six climatically different sites in Central Europe under several scenarios of species diversity, management, and climate change. We evaluated the influence of these factors on the provision of a range of tree-based EGS, represented by harvested basal area, total biomass, stand diversity, and productivity. The most influential factor was species diversity, with diverse forest stands showing a lower sensitivity to climate change than monocultures. Management mainly influenced biomass, with the most intensively managed stands retaining more of their original biomass than others. All three climate-change scenarios yielded very similar results. We showed that (1) only few factor combinations perform worse under climate-change conditions than others, (2) diversity aspects are important for adaptive management measures, but for some indicators, management may be more important than diversity, and (3) at locations subject to increasing drought, the future provision of EGS may decrease regardless of the factor combination. This quantitative evaluation of the influence of different factors on changes in the provision of forest EGS with climate change represents an important step towards the design of more focused adaptation strategies and highlights key factors that should be considered in simulation studies under climate change. 相似文献