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411.
The paper derives probability distributions for height and period for the highest wave occurring at a fixed location when the sea state varies. Short-term distributions of height and period are derived using a data base of waverider data from the Norwegian Sea. The derived theoretical relationships are illustrated by various examples of measured long-term statistics of the sea state.  相似文献   
412.
The principal features of the marine ecosystems in the Barents and Norwegian Seas and some of their responses to climate variations are described. The physical oceanography is dominated by the influx of warm, high-salinity Atlantic Waters from the south and cold, low-salinity waters from the Arctic. Seasonal ice forms in the Barents Sea with maximum coverage typically in March–April. The total mean annual primary production rates are similar in the Barents and Norwegian Seas (80–90 g C m−2), although in the Barents, the production is higher in the Atlantic than in the ice covered Arctic Waters. The zooplankton is dominated by Calanus species, C. finmarchicus in the Atlantic Waters of the Norwegian and Barents Seas, and C. glacialis in the Arctic Waters of the Barents Sea. The fish species in the Norwegian Sea are mostly pelagics such as herring (Clupea harengus) and blue whiting (Micromesistius poutassou), while in the Barents Sea there are both pelagics (capelin (Mallotus villosus Müller), herring, and polar cod (Boreogadus saida Lepechin)) and demersals (cod (Gadus morhua L.) and haddock (Melanogrammus aeglefinus)). The latter two species spawn in the Norwegian Sea along the slope edge (haddock) or along the coast (cod) and drift into the Barents Sea. Marine mammals and seabirds, although comprising only a relatively small percentage of the biomass and production in the region, play an important role as consumers of zooplankton and small fish. While top-down control by predators certainly is significant within the two regions, there is also ample evidence of bottom-up control. Climate variability influences the distribution of several fish species, such as cod, herring and blue whiting, with northward shifts during extended warm periods and southward movements during cool periods. Climate-driven increases in primary and secondary production also lead to increased fish production through higher abundance and improved growth rates.  相似文献   
413.
Springtime measurements of NOx, ozone, PAN,J(NO2), and other compounds were made near Ny-Ålesund,Svalbard (78°54N, 11°53E), in 1994 and Poker Flat,Alaska (65°08N, 147°29W), in 1995. At Svalbard medianmixing ratios for PAN and NOx of 237 and 23.7 pptv,respectively, were observed. The median mixing ratios at Poker Flat for PANand NOx were 79.5 and 85.9 pptv, respectively. These data areused to estimate thermal PAN decomposition using several differentapproaches. At Svalbard PAN decomposition was very small, while at PokerFlat up to 30 pptv/h PAN decomposed. At both sites the NOx/PANratio increased with temperature between –10 and 20°C implyingthat PAN decomposition is an important NOx source. In-situozone production was calculated from the measured NO, NO2,O3, J(NO2), and temperature data, using thesteady state assumption Median ozone production was 605 pptv/h at PokerFlat, and one order of magnitude smaller at Svalbard during the daytime.Only at Poker Flat could a direct influence on the diurnal ozone cycle beobserved from in-situ production. These results imply that PAN decompositionis a major source of NOx in the high latitude troposphere, andthat this contributes to the observed spring maximum in surface ozone.  相似文献   
414.
A first experimental study was conducted to determine the equilibrium iron isotope fractionation between pyrrhotite and silicate melt at magmatic conditions. Experiments were performed in an internally heated gas pressure vessel at 500 MPa and temperatures between 840 and 1000 °C for 120-168 h. Three different types of experiments were conducted and after phase separation the iron isotope composition of the run products was measured by MC-ICP-MS. (i) Kinetic experiments using 57Fe-enriched glass and natural pyrrhotite revealed that a close approach to equilibrium is attained already after 48 h. (ii) Isotope exchange experiments—using mixtures of hydrous peralkaline rhyolitic glass powder (∼4 wt% H2O) and natural pyrrhotites (Fe1 − xS) as starting materials— and (iii) crystallisation experiments, in which pyrrhotite was formed by reaction between elemental sulphur and rhyolitic melt, consistently showed that pyrrhotite preferentially incorporates light iron. No temperature dependence of the fractionation factor was found between 840 and 1000 °C, within experimental and analytical precision. An average fractionation factor of Δ 56Fe/54Fepyrrhotite-melt = −0. 35 ± 0.04‰ (2SE, n = 13) was determined for this temperature range. Predictions of Fe isotope fractionation between FeS and ferric iron-dominated silicate minerals are consistent with our experimental results, indicating that the marked contrast in both ligand and redox state of iron control the isotope fractionation between pyrrhotite and silicate melt. Consequently, the fractionation factor determined in this study is representative for the specific Fe2+/ΣFe ratio of our peralkaline rhyolitic melt of 0.38 ± 0.02. At higher Fe2+/ΣFe ratios a smaller fractionation factor is expected. Further investigation on Fe isotope fractionation between other mineral phases and silicate melts is needed, but the presented experimental results already suggest that even at high temperatures resolvable variations in the Fe isotope composition can be generated by equilibrium isotope fractionation in natural magmatic systems.  相似文献   
415.
The effect of pressure and composition on the viscosity of both anhydrous and hydrous andesitic melts was studied in the viscosity range of 108 to 1011.5 Pa · s using parallel plate viscometry. The pressure dependence of the viscosity of three synthetic, iron-free liquids (andesite analogs) containing 0.0, 1.06, and 1.96 wt.% H2O, respectively, was measured from 100 to 300 MPa using a high-P-T viscometer. These results, combined with those from Richet et al. (1996), indicate that viscosities of anhydrous andesitic melts are independent of pressure, whereas viscosities of hydrous melts slightly increase with increasing pressure. This trend is consistent with an increased degree of depolymerization in the hydrous melts. Compositional effects on the viscosity were studied by comparing iron-free and iron-bearing compositions with similar degrees of depolymerization. During experiments at atmospheric and at elevated pressures (100 to 300 MPa), the viscosity of iron-bearing anhydrous melts preequilibrated in air continuously increased, and the samples became paramagnetic. Analysis of these samples by transmission electron microscopy showed a homogeneous distribution of crystals (probably magnetite) with sizes in the range of 10 to 50 nm. No significant difference in the volume fractions of crystals was found in samples after annealing for 170 to 830 min at temperatures ranging from 970 to 1122 K. An iron-bearing andesite containing 1.88 wt.% H2O, which was synthesized at intrinsic fO2 conditions in an internally heated pressure vessel, showed a similar viscosity behavior as the anhydrous melts. The continuous increase in viscosity at a constant temperature is attributed to changes of the melt structure due to exsolution of iron-rich phases. By extrapolating the time evolution of viscosity down to the time at which the run temperature was reached, for both the anhydrous (at 1055 K) and the hydrous (at 860 K) iron-bearing andesite, the viscosity is 0.7 log units lower than predicted by the model of Richet et al. (1996). This may be explained by differences in structural properties of Fe2+ and Fe3+ and their substitutes Mg2+, Ca2+, and Al3+, which were used in the analogue composition.The effect of iron redox state on the viscosity of anhydrous, synthetic andesite melts was studied at ambient pressure using a dilatometer. Reduced iron-bearing samples were produced by annealing melts in graphite crucibles in an Ar/CO atmosphere for different run times. In contrast to the oxidized sample, no variation of viscosity with time and no exsolution of iron oxide phases was observed for the most reduced glasses. This indicates that trivalent iron promotes the exsolution of iron oxide in supercooled melts. With decreasing Fe3+/ΣFe ratio from 0.58 to 0.34, the viscosity decreases by ∼1.6 log units in the investigated temperature range between 964 and 1098 K. A more reduced glass with Fe3+/ΣFe = 0.21 showed no additional decrease in viscosity. Our conclusion from these results is that the viscosity of natural melts may be largely overestimated when using data obtained from samples synthesized in air.  相似文献   
416.
417.
A short general explanation of tidal forces and tidal effects is given. The influences of Earth tides and ocean tides on the Earth's rotation vector are presented. Today, the theoretical models for periodic variations in the Earth's rotation and in polar motion can be compared with precise measurements done by modern space techniques. Secular changes of the Earth's rotation due to interactions within the Earth-Moon-system are also discussed.  相似文献   
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