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41.
Seasonal variations in sea level are often neglected in studies of coastal aquifers; however, they may have important controls on processes such as submarine groundwater discharge, sea water intrusion, and groundwater discharge to coastal springs and wetlands. We investigated seasonal variations in salinity in a groundwater‐fed coastal wetland (the RAMSAR listed Piccaninnie Ponds in South Australia) and found that salinity peaked during winter, coincident with seasonal sea level peaks. Closer examination of salinity variations revealed a relationship between changes in sea level and changes in salinity, indicating that sea level–driven movement of the fresh water‐sea water interface influences the salinity of discharging groundwater in the wetland. Moreover, the seasonal control of sea level on wetland salinity seems to override the influence of seasonal recharge. A two‐dimensional variable density model helped validate this conceptual model of coastal groundwater discharge by showing that fluctuations in groundwater salinity in a coastal aquifer can be driven by a seasonal coastal boundary condition in spite of seasonal recharge/discharge dynamics. Because seasonal variations in sea level and coastal wetlands are ubiquitous throughout the world, these findings have important implications for monitoring and management of coastal groundwater–dependent ecosystems.  相似文献   
42.
Western Kansas has an historical identification with cattle, with a focus on cattle ranching and more specifically since the 1950s, beef-cattle feedlots. Since the mid-1990s large dairy operations have moved into southwestern Kansas. Today more than twenty large dairies house more than 70,000 milk cows. These operate as confined feeding operations similar to beef-cattle feedlots. Regional advantages for the dairy industry include affordable land with wide-open space, local residents' cattle- and dairy-friendly attitudes, and other factors. Regional promoters have actively recruited dairies, and a dairy-business support system has emerged. The prospects for continued expansion of dairies in southwestern Kansas are unclear; despite the locational advantages and the possibility that the industry may continue to relocate here, as did the cattle-feeding industry several decades ago, further moves into the area may depend on continued resources availability and additional infrastructure development.  相似文献   
43.
The observations leading to, and confirming the discovery of, 1978 P 1 (Charon) are reviewed. The original interpretation of these observations remains valid. The circular orbit with synchronous revolution and rotation is in agreement with both observation and theory. The expectation that eclipse events are imminent is supported by our recent data.  相似文献   
44.

Background

Reactive oxygen species (ROS) are vital regulators of many cellular functions in the body. The intracellular ROS concentration is highly regulated by a balance between pro-oxidants and anti-oxidants. A chronic excess of pro-oxidants leads to elevated ROS concentrations and inflammation, possibly initiating or enhancing disease onset. Mineral-induced generation of ROS, the role of minerals in upregulating cellular ROS, and their role in the development of several occupational diseases are now widely recognized. However, there is no standard protocol to determine changes in ROS production in cells after exposure to mineral dust or earth materials in general. In this study, a new method for determining the degree of cellular toxicity (i.e., cytotoxicity) of particles is described that will help bridge the gap in knowledge.

Results

By measuring the production of ROS and the viability of cells, an inflammatory stress response (ISR) indicator is defined. This approach normalizes the ROS upregulation with respect to the number of viable cells at the time of measurement. We conducted experiments on a series of minerals and soils that represent materials that are inert (i.e., glass beads, anatase, and a soil with low trace element content), moderately reactive (i.e., soil with high trace element content), and highly reactive (i.e., pyrite). Inert materials generated the lowest ISR, averaging 350% compared to the control. Acid washed pyrite produced the highest ISR (1,100 fold higher than the control). The measurements conducted as a function of time showed a complex response. Most materials showed an increase in ISR with particle loading.

Conclusions

The amount of cellularly generated ROS and cell viability combined provide a better understanding of particle-induced oxidative stress. The results indicate that some earth materials may solicit an initial burst of ROS, followed by a second phase in which cell viability decreases and ROS production increases, leading to a high ISR value. Hence, measurements conducted over a range of particle loading combined with multiple data measurements up to 24 hours can provide new insights in the possible effect of exposure to earth materials on human health.  相似文献   
45.
46.
Hydrogen peroxide and hydroxyl radical are readily formed during the oxidation of pyrite with molecular oxygen over a wide range of pH conditions. However, pretreatment of the pyrite surface influences how much of the intermediates are formed and their fate. Acid-washed pyrite produces significant amounts of hydrogen peroxide and hydroxyl radical when suspended in air-saturated water. However, the hydrogen peroxide concentration shows an exponential decrease with time. Suspensions made with partially oxidized pyrite yield significantly lower amounts of hydrogen peroxide product. The presence of Fe(III)-oxide or Fe(III)-hydroxide patches facilitates the conversion of hydrogen peroxide to oxygen and water. Hence, the degree to which a pyrite surface is covered with patches of Fe(III)-oxide or Fe(III)-hydroxide patches is an important control on the concentration of hydrogen peroxide in solution.Hydrogen peroxide appears to be an important intermediate in the four-electron transfer from pyrite to molecular oxygen. Addition of catalase, an enzyme that decomposes hydrogen peroxide to water and molecular oxygen, to a pyrite suspension reduces the oxidation rate by 40%. By contrast, hydroxyl radical does not appear to play a significant role in the oxidation mechanism. It is estimated on the basis of a molecular oxygen and sulfate mass balance that 5-6% of the molecular oxygen is consumed without forming sulfate.  相似文献   
47.
Long-term spatial and temporal trends in frost indices in Kansas, USA   总被引:2,自引:0,他引:2  
Frost indices such as number of frost days (nFDs), number of frost-free days (nFFDs), last spring freeze (LSF), first fall freeze (FFF), and growing-season length (GSL) were calculated using daily minimum air temperature (Tmin) from 23 centennial weather stations across Kansas during four time periods (through 1919, 1920–1949, 1950–1979, and 1980–2009). A frost day is defined as a day with Tmin?<?0 °C. The long- and short-term trends in frost indices were analyzed at monthly, seasonal, and annual timescales. Probability of occurrence of the indices was analyzed at 5 %, 25 %, 50 %, 75 %, and 95 %. Results indicated a general increase in Tmin from 1900 through 2009 causing a decrease in nFDs. LSF and FFF occurred earlier and later than normal in the year, respectively, thereby resulting in an increase in GSL. In general, northwest Kansas recorded the greatest nFD and lowest Tmin, whereas southeast Kansas had the lowest nFD and highest Tmin; however, the magnitude of the trends in these indices varied with location, time period, and time scales. Based on the long-term records in most stations, LSF occurred earlier by 0.1–1.9 days/decade, FFF occurred later by 0.2–0.9 day/decade, and GSL was longer by 0.1–2.5 day/decade. At the 50 % probability level, Independence in the south-eastern part of Kansas had the earliest LSF (6 April), latest FFF (29 October) and longest GSL (207 days). Oberlin (north-western Kansas) recorded the shortest GSL (156 days) and earliest FFF (7 October) had the latest LSF (2 May) at the 50 % probability level. A positive correlation was observed for combinations of indices (LSF and GSL) and elevation, whereas a negative correlation was found between FFF and elevation.  相似文献   
48.
Carbonaceous chondrites of the Vigarano group (CV) are primitive (nearly un-metamorphosed) meteorites that provide a wealth of information about the early solar system, including constraints on chondrule formation, origin of calcium-aluminum inclusions, stability of organic compounds, and redox conditions. The US Antarctic meteorite collection contains 119 CV samples from 15 dense collection areas (DCAs) from the TransAntarctic Mountains; these samples have been assigned a preliminary classification as CVs, but not to the subgroups oxidized A, oxidized B, and reduced. Furthermore, variation in petrologic grade can be determined non-destructively using Raman spectroscopy. To update the classification of both subgroups and petrologic types in the collection, we have acquired magnetic susceptibility, metal and sulfide compositions, and Raman spectra. Overall, there are 55 oxidized A samples, 18 oxidized B samples, and 46 reduced samples. Several of the CVs are quite primitive (Lewis Cliffs Ice Tongue and MacAlpine Hills) but are also very small. Multiple pairing groups have been identified in the Miller Range (MIL), Queen Alexandra Range, and Larkman Nunatak DCAs, including all of the subgroups. In MIL 090981, there is evidence for multiple lithologies. We make suggested updates for all the samples, knowing that this information will help to better guide researchers interested in studying the CV chondrites in the US Antarctic meteorite collection.  相似文献   
49.
The Mars 2020/Mars Sample Return (MSR) Sample Depot Science Community Workshop was held on September 28 and 30, 2022, to assess the Scientifically-Return Worthy (SRW) value of the full collection of samples acquired by the rover Perseverance at Jezero Crater, and of a proposed subset of samples to be left as a First Depot at a location within Jezero Crater called Three Forks. The primary outcome of the workshop was that the community is in consensus on the following statement: The proposed set of ten sample tubes that includes seven rock samples, one regolith sample, one atmospheric sample, and one witness tube constitutes a SRW collection that: (1) represents the diversity of the explored region around the landing site, (2) covers partially or fully, in a balanced way, all of the International MSR Objectives and Samples Team scientific objectives that are applicable to Jezero Crater, and (3) the analyses of samples in this First Depot on Earth would be of fundamental importance, providing a substantial improvement in our understanding of Mars. At the conclusion of the meeting, there was overall community support for forming the First Depot as described at the workshop and placing it at the Three Forks site. The community also recognized that the diversity of the Rover Cache (the sample collection that remains on the rover after placing the First Depot) will significantly improve with the samples that are planned to be obtained in the future by the Perseverance rover and that the Rover Cache is the primary target for MSR to return to Earth.  相似文献   
50.
采用产业经济学、计量经济学、统计学中的相关方法,对伊犁河谷1956-2008年期间产业结构演进的特征进行了定量评价,并针对伊犁河谷产业结构演进的三个阶段及其特征进行了研究.利用指标计算分析了三次产业及其内部结构、就业产业结构、产业结构升级转换等层面的动态演进过程,然后运用偏离-份额分析法计算了1956-1978年、1979-1992年和1993-2008年三个代表时段产业结构演进的数量特征.结果表明,伊犁河谷产业结构演进特征具有以下特点:1.一产比重一直呈现明显的下降趋势,二产业比重总体上处于上升趋势,第三产业比第二产业上升快,但内部结构不合理;2.产业结构和就业结构发展表现出极强的不均衡性;3.产业结构转换速度逐渐变缓,特别是1993年以后,随着经济活动日趋正常化、规模化、成熟化,产业结构转换速度相对较小;4.产业结构一直是靠着传统的农牧业在发展演进,落后的工业和不发达的第三产业严重制约着伊犁河谷产业结构的演进.  相似文献   
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