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361.
362.
Highly siderophile and chalcogen element constraints on the origin of components of the Allende and Murchison meteorites
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187Re‐187Os systematics, abundances of highly siderophile elements (HSE: Re, PGE, and Au), chalcogen elements (Te, Se, and S), and some major and minor elements were determined in physically separated components of the Allende (CV3) and Murchison (CM2) carbonaceous chondrites. Substantial differences exist in the absolute and relative abundances of elements in the components, but the similarity of calculated and literature bulk rock abundances of HSE and chalcogens indicate that chemical complementarity exists among the components, with CI chondrite‐like ratios for many elements. Despite subsequent alteration and oxidation, the overall cosmochemical behavior of most moderately to highly siderophile elements during high‐temperature processing has been preserved in components of Allende at the sampling scale of the present study. The 187Re‐187Os systematics and element variations of Allende are less disturbed compared with Murchison, which reflects different degrees of oxidation and alteration of these meteorites. The HSE systematics (with the exception of Au) is controlled by two types of materials: Pd‐depleted condensates and CI chondrite‐like material. Enrichment and heterogeneous distribution of Au among the components is likely the result of hydrothermal alteration. Chalcogen elements are depleted compared with HSE in all components, presumably due to their higher volatility. Small systematic variations of S, Se, and Te in components bear the signature of fractional condensation/partial evaporation and metal–sulfide–silicate partitioning. 相似文献
363.
Lithium isotopes and light lithophile element abundances in shergottites: Evidence for both magmatic degassing and subsolidus diffusion
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Arya Udry Harry Y. McSween Jr. Richard L. Hervig Lawrence A. Taylor 《Meteoritics & planetary science》2016,51(1):80-104
Degassed magmatic water was potentially the major source of surficial water on Mars. We measured Li, B, and Be abundances and Li isotope profiles in pyroxenes, olivines, and maskelynite from four compositionally different shergottites—Shergotty, QUE 94201, LAR 06319, and Tissint—using secondary ion mass spectrometry (SIMS). All three light lithophile elements (LLE) are incompatible: Li and B are soluble in H2O‐rich fluids, whereas Be is insoluble. In the analyzed shergottites, Li concentration decreases and Be concentration increases from cores to rims in pyroxenes. However, B concentrations do not vary consistently with Li and Be abundances, except in QUE 94201 pyroxenes. Additionally, abundances of these three elements in olivines show a normal igneous‐fractionation trend consistent with the crystallization of olivine before magma ascent and degassing. We expect that kinetic effects would lead to fractionation of 6Li in the vapor phase compared to 7Li during degassing. The Li isotope profiles, with increasing δ7Li from cores to rims, as well as Li and B profiles indicate possible degassing of hydrous fluids only for the depleted shergottite QUE 94201, as also supported by degassing models. Conversely, Shergotty, LAR 06319, and Tissint appear to have been affected by postcrystallization diffusion, based on their LLE and Li isotope profiles, accompanied by diffusion models. This process may represent an overlay on a degassing pattern. The LLE profiles and isotope profiles in QUE 94201 support the hypothesis that degassing of some basaltic shergottite magmas provided water to the Martian surface, although evidence may be obscured by subsolidus diffusion processes. 相似文献
364.
Harry Pavlopoulos 《Advances in water resources》2011,34(8):990-1011
Spectral multi-scaling postulates a power-law type of scaling of spectral distribution functions of stationary processes of spatial averages, over nested and geometrically similar sub-regions of the spatial parameter space of a given spatio-temporal random field. Presently a new framework is formulated for down-scaling processes of spatial averages, following naturally from the postulate of spectral multi-scaling, and key ingredients required for its implementation are described. Moreover, results from an extensive diagnostic study are presented, seeking statistical evidence supportive of spectral multi-scaling. Such evidence emerges from two sources of data. One is a 13 year long historical record of radar observations of rainfall in southeastern UK (Chenies radar), with high spatial (2 km) and temporal (5 min) resolution. The other is an ensemble of rain rate fields simulated by a spatio-temporal random pulse model fitted to the historical data. The results are consistent between historical and simulated rainfall data, indicating frequency-dependent scaling relationships interpreted as evidence of spectral multi-scaling across a range of spatial scales. 相似文献
365.
The concentrations of Rh, Au and other highly siderophile elements (HSE: Re, Os, Ir, Ru, Pt, Rh, Pd and Au), and 187Os/188Os isotope ratios have been determined for samples from peridotite massifs and xenoliths in order to further constrain HSE abundances in the Earth's mantle and to place constraints on the distributions processes accounting for observed HSE variations between fertile and depleted mantle lithologies. Concentrations of Re, Os, Ir, Ru, Pt and Pd were determined by isotope dilution ICP-MS and N-TIMS. The monoisotopic elements Rh and Au were quantified by standardization relative to the concentrations of Ru and Ir, respectively, and were determined from the same digestion aliquot as other HSE. The measurement precision of the concentration data under intermediate precision conditions, as inferred from repeated analyses of 2 g test portions of powdered samples, is estimated to be better than 10% for Rh and better than 15% for Au (1 s).Fertile lherzolites display non-systematic variation of Rh concentrations and constant Rh/Ir of 0.34 ± 0.03 (1 s, n = 57), indicating a Rh abundance for the primitive mantle of 1.2 ± 0.2 ng/g. The data also suggest that Rh behaves as a compatible element during low to moderate degrees of partial melting in the mantle or melt–mantle interaction, but may be depleted at higher degrees of melting. In contrast, Au concentrations and Au/Ir correlate with peridotite fertility, indicating incompatible behaviour of Au during magmatic processes in the mantle. Fertile lherzolites display Au/Ir ranging from 0.20 to 0.65, whereas residual harzburgites have Au/Ir < 0.20. Concentrations of Au and Re are correlated with each other and suggest similar compatibility of both elements. The primitive mantle abundance of Au calculated from correlations displayed by Au/Ir with Al2O3 and Au with Re is 1.7 ± 0.5 ng/g (1 s).The depletion of Pt, Pd, Re and Au relative to Os, Ir, Ru and Rh displayed by residual harzburgites, suggests HSE fractionation during partial melting. However, the HSE abundance variations of fertile and depleted peridotites cannot be explained by a simple fractionation process. Correlations displayed by Pd/Ir, Re/Ir and Au/Ir with Al2O3 may reflect refertilization of previously melt depleted mantle rocks due to reactive infiltration of silicate melts.Relative concentrations of Rh and Au inferred for the primitive mantle model composition are similar to values of ordinary and enstatite chondrites, but distinct from carbonaceous chondrites. The HSE pattern of the primitive mantle is inconsistent with compositions of known chondrite groups. The primitive mantle composition may be explained by late accretion of a mixture of chondritic with slightly suprachondritic materials, or alternatively, by meteoritic materials mixed into mantle with a HSE signature inherited from core formation. 相似文献
366.
The recent loss of mountain glaciers in response to climate warming has been reported across a range of latitudes globally, but the processes involved are not always straightforward. In southern Pacific mid‐latitudes, twentieth‐century glacier fluctuations are thought to reflect the strength of westerly atmospheric circulation, which brings increased precipitation, leading to mass gains. We present a study of the response of Mangaehuehu Glacier, a cirque glacier on Mt Ruapehu, to climate over the last two decades. Glacier surface area fluctuated in size over this period, corresponding closely with mean end‐of‐summer snowlines in the Southern Alps. The key control on glacier extent appears to be ablation season temperature, itself controlled by regional atmospheric circulation, including El Niño‐Southern Oscillation, Interdecadal Pacific Oscillation (IPO), and to a lesser extent, Southern Annular Mode (SAM). Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
367.
In a recent paper, published in Astrophys. Space Sci. (337:107, 2012) (hereafter paper ZZX) and entitled “On the triangular libration points in photogravitational restricted three-body problem
with variable mass”, the authors study the location and stability of the generalized Lagrange libration points L
4 and L
5. However their study is flawed in two aspects. First they fail to write correctly the equations of motion of the variable
mass problem. Second they attribute a variable mass to the third body of the restricted three-body model, a fact that is not
compatible with the assumptions used in deriving the mathematical formulation of this model. 相似文献
368.
Harry Varvoglis Vasiliki Sgardeli Kleomenis Tsiganis 《Celestial Mechanics and Dynamical Astronomy》2012,113(4):387-402
The recent discovery of free-floating planets and their theoretical interpretation as celestial bodies, either condensed independently or ejected from parent stars in tight clusters, introduced an intriguing possibility. Namely, that some exoplanets are not condensed from the protoplanetary disk of their parent star. In this novel scenario a free-floating planet interacts with an already existing planetary system, created in a tight cluster, and is captured as a new planet. In the present work we study this interaction process by integrating trajectories of planet-sized bodies, which encounter a binary system consisting of a Jupiter-sized planet revolving around a Sun-like star. To simplify the problem we assume coplanar orbits for the bound and the free-floating planet and an initially parabolic orbit for the free-floating planet. By calculating the uncertainty exponent, a quantity that measures the dependence of the final state of the system on small changes of the initial conditions, we show that the interaction process is a fractal classical scattering. The uncertainty exponent is in the range (0.2–0.3) and is a decreasing function of time. In this way we see that the statistical approach we follow to tackle the problem is justified. The possible final outcomes of this interaction are only four, namely flyby, planet exchange, capture or disruption. We give the probability of each outcome as a function of the incoming planet’s mass. We find that the probability of exchange or capture (in prograde as well as retrograde orbits and for very long times) is non-negligible, a fact that might explain the possible future observations of planetary systems with orbits that are either retrograde (see e.g. Queloz et?al. Astron. Astrophys. 417, L1, 2010) or tight and highly eccentric. 相似文献
369.
In order to investigate total organic carbon (TOC) exchange through the Strait of Gibraltar, samples were taken along two sections from the western (Gulf of Cádiz) and eastern (Western Alboran Sea) entrances of the Strait and at the middle of the Strait in April 1998. TOC was measured by using a high-temperature catalytic oxidation method. The results referenced here are based on a three-layer model of water mass exchange through the Strait, which includes the Atlantic inflow, Mediterranean outflow and an interface layer in between. All layers were characterised by a decrease of TOC concentrations from the Gulf of Cádiz to the Western Alboran Sea: from 60–79 to 59–66 μM C in the Atlantic inflow and from 40–60 to 38–52 μM C in the Mediterranean waters, respectively. TOC concentrations in the modified North Atlantic Central Water varied from 43 to 55 μM C. Intermediate TOC values were measured in the interface layer (43–60 μM C). TOC concentrations increased from the middle of the Strait towards continents indicating a contribution of organic carbon of photosynthetic origin along Spain and Morocco coasts or TOC accumulation due to upwelling in the northeastern part of the Strait. Our results indicate that the short-term variability caused by the tide greatly impacts the TOC distribution, particularly in the Gulf of Cádiz. The TOC input from the Atlantic Ocean to the Mediterranean Sea through the Strait of Gibraltar varies from 0.9×104 to 1.0×104 mol C s−1 (or 0.28×1012 to 0.35×1012 mol C year−1, respectively). This estimate suggests that the TOC inflow and outflow through the Strait of Gibraltar are two and three orders of magnitude higher than reported via the Turkish Straits and Mediterranean River inputs. 相似文献
370.
AbstractAccess to hydrometric information underpins many areas of effective water management. This paper explores the operational practices of one national hydrological information service, the UK National River Flow Archive, in collating, managing and providing access to river flow data. An information lifecycle approach to hydrometric data management is advocated, with the paper detailing current UK procedures in the areas of: monitoring network design and development; data sensing and recording; validation and archival; synthesis and analysis; and data dissemination. The methods and policies outlined herein are widely transferable to other hydrological data archives around the world.Editor D. KoutsoyiannisCitation Dixon, H., Hannaford, J., and Fry, M.J., 2013. The effective management of national hydrometric data: experiences from the United Kingdom. Hydrological Sciences Journal, 58 (7), 1383–1399. 相似文献