Phosphorus retention in calcareous soils and the effect of organic matter on its mobility   总被引：7，自引：0，他引：7  

Ray von Wandruszka 《Geochemical transactions》2006,7(1):6-8

A survey of the interactions between phosphorus (P) species and the components of calcareous soils shows that both surface reactions and precipitation take place, especially in the presence of calcite and limestone. The principal products of these reactions are dicalcium phosphate and octacalcium phosphate, which may interconvert after formation. The role of calcium carbonate in P retention by calcareous soils is, however, significant only at relatively high P concentrations – non-carbonate clays play a more important part at lower concentrations. In the presence of iron oxide particles, occlusion of P frequently occurs in these bodies, especially with forms of the element that are pedogenic in origin. Progressive mineralization and immobilization, often biological in nature, are generally observed when P is added as a fertilizer.  相似文献   

Understanding Perturbation on the Simplex: A Simple Method to Better Visualize and Interpret Compositional Data in Ternary Diagrams     

Hilmar von Eynatten  Vera Pawlowsky-Glahn  Juan José Egozcue 《Mathematical Geology》2002,34(3):249-257

Perturbation is an operation defined on the simplex and can be used for centering compositional data in a ternary diagram, applying objective criteria. Because a straight line in the original diagram is still astraight line in the perturbed diagram, gridlines or compositional fields defined by straight lines can easily be included in the operation. Simultaneous perturbation of data, gridlines, and/or compositional fields is shown to improve both visualization and graphical interpretation of compositions in ternary diagrams. This is illustrated by some examples using simulated as well as real data.  相似文献   

Acknowledgement     

Roland von Huene 《International Journal of Earth Sciences》2002,91(3):372

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A Case Study Of An On-Ice Air Flow Over The Arctic Marginal Sea-Ice Zone     

Timo Vihma  Jörg Hartmann  Christof Lüpkes 《Boundary-Layer Meteorology》2003,107(1):189-217

A case study of warm air advection over the Arctic marginalsea-ice zone is presented, based on aircraft observations with direct flux measurements carriedout in early spring, 1998. A shallow atmospheric boundary layer (ABL) was observed, which wasgradually cooling with distance downwind of the ice edge. This process was mainly connected with astrong stable stratification and downward turbulent heat fluxes of about 10–20 W m^-2, but wasalso due to radiative cooling. Two mesoscale models, one hydrostatic and the other non-hydrostatic,having different turbulence closures, were applied. Despite these fundamental differences betweenthe models, the results of both agreed well with the observed data. Various closure assumptions had amore crucial influence on the results than the differences between the models.Such an assumption was, for example,the parameterization of the surface roughness for momentum (z₀) and heat (z_T). This stronglyaffected the wind and temperature fields not only close to the surface but also within and abovethe temperature inversion layer. The best results were achieved using a formulation for z₀ that took intoaccount the form drag effect of sea-ice ridges together withz_T = 0.1z₀. The stability within theelevated inversion strongly depended on the minimum eddy diffusivity K_min. A simple ad hocparameterization seems applicable, where K_min is calculated as 0.005 timesthe neutral eddy diffusivity. Although the longwave radiative cooling was largest within the ABL, theapplication of a radiation scheme was less important there than above the ABL. This was related to theinteraction of the turbulent and radiative fluxes. To reproduce the strong inversion, it wasnecessary to use vertical and horizontal resolutions higher than those applied in most regional andlarge-scale atmospheric models.  相似文献   

Roll Vortices and Boundary-Layer Development during a Cold Air Outbreak     

Jörg Hartmann  Christoph Kottmeier  Siegfried Raasch 《Boundary-Layer Meteorology》1997,84(1):45-65

The development of the boundary layer during a cold air outbreak in the FramStrait is documented by aircraft measurements. The convection was organisedinto roll vortices with aspect ratios increasing from 2.9 near the ice edgeto more than 6 at 100 km further downstream. This increase coincides with anincrease of the latent heat release in the cloud layer. The stability parameter-zi/L varies from about zero at the ice edge to 30 at a distance of 200 kmdownstream over open water where the satellite picture still shows cloudstreets. The increase is mainly due to the deepening of the boundary layer.The turbulent vertical sensible and latent heat fluxes near the surface amountto 400 W m^-2 within a 300 km off-ice zone. 25% of the upward heat fluxin the subcloud layer is carried out by organised roll motions. Experimentswith a 2-dimensional non-hydrostatic model show a similar roll aspect ratio inthe first 50 km, but further downstream where condensational heating is moreimportant the modelled roll wavelengths are distinctly smaller than the observedones.  相似文献   

Distribution and sources of pre-anthropogenic lead isotopes in deep ocean water from FeMn crusts   总被引：3，自引：0，他引：3  

F. von Blanckenburg  R.K. O'nions  J.R. Heinz 《Geochimica et cosmochimica acta》1996,60(24):4957-4963

The lead isotope composition of ocean water is not well constrained due to contamination by anthropogenic lead. Here the global distribution of lead isotopes in deep ocean water is presented as derived from dated (ca. 100 ka) surface layers of hydrogenetic Fe-Mn crusts. The results indicate that the radiogenic lead in North Atlantic deep water is probably supplied from the continents by river particulates, and that lead in Pacific deep water is similar to that characteristic of island and continental volcanic arcs. Despite a short residence time in deep water (80–100 a), the isotopes of lead appear to be exceedingly well mixed in the Pacific basin. There is no evidence for the import of North Atlantic deep water-derived lead into the Pacific ocean, nor into the North Indian Ocean. This implies that the short residence time of lead in deep water prohibits advection over such long distances. Consequently, any climate-induced changes in deep-water flow are not expected to result in major changes in the seawater Pb-isotope record of the Pacific Ocean.  相似文献   

A parameterisation for the threshold shear velocity to initiate deflation of dry and wet sediment   总被引：1，自引：0，他引：1  

Wim M. Cornelis  Donald Gabriels  Roger Hartmann 《Geomorphology》2004,59(1-4):43

A new parameterisation for the threshold shear velocity to initiate deflation of dry and wet particles is presented. It is based on the balance of moments acting on particles at the instant of particle motion. The model hence includes a term for the aerodynamic forces, including the drag force, the lift force and the aerodynamic-moment force, and a term for the interparticle forces. The effect of gravitation is incorporated in both terms. Rather than using an implicit function for the effect of the aerodynamic forces as reported earlier in literature, a constant aerodynamic coefficient was introduced. From consideration of the van der Waals force between two particles, it was further shown that the effect of the interparticle cohesion force between two dry particles on the deflation threshold should be inversely proportional to the particle diameter squared. The interparticle force was further extended to include wet bonding forces. The latter were considered as the sum of capillary forces and adhesive forces. A model that expresses the capillary force as a function of particle diameter squared and the inverse of capillary potential was deduced from consideration of the well-known model of Fisher and the Young–Laplace equation. The adhesive force was assumed to be equal to tensile strength, and a function which is proportional to particle diameter squared and the inverse of the potential due to adhesive forces was derived. By combining the capillary-force model and the adhesive force model, the interparticle force due to wet bonding was simplified and written as a function of particle diameter squared and the inverse of matric potential. The latter was loglinearly related to the gravimetric moisture content, a relationship that is valid in the low-moisture content range that is important in the light of deflation of sediment by wind. By introducing a correction to force the relationship to converge to zero moisture content at oven dryness, the matric potential–moisture content relationship contained only one unknown model parameter, viz. moisture content at −1.5 MPa. Working out the model led to a rather simple parameterisation containing only three coefficients. Two parameters were incorporated in the term that applies to dry sediment and were determined by using experimental data as reported by Iversen and White [Sedimentology 29 (1982) 111]. The third parameter for the wet-sediment part of the model was determined from wind-tunnel experiments on prewetted sand and sandy loam aggregates. The model was validated using data from wind-tunnel experiments on the same but dry sediment, and on data obtained from simulations with the model of Chepil [Soil Sci. Soc. Am. Proc. 20 (1956) 288]. The experiments showed that soil aggregates should be treated as individual particles with a density equal to their bulk density. Furthermore, it was shown that the surface had to dry to a moisture content of about 75% of the moisture content at −1.5 MPa before deflation became sustained. The threshold shear velocities simulated with our model were found to be in good agreement with own observations and with simulations using Chepil's model.  相似文献   

Difference information criterion for the analysis of a seismotectonic influence on a radon time-series at the KSM site, Japan   总被引：3，自引：0，他引：3  

Jens Hartmann 《Geophysical Journal International》2005,160(3):891-900

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A statistical procedure for the analysis of seismotectonically induced hydrochemical signals: A case study from the Eastern Carpathians, Romania   总被引：3，自引：0，他引：3  

Jens Hartmann  Zsolt Berner  Doris Stüben  Norbert Henze   《Tectonophysics》2005,405(1-4):77-98

Changes in the stress field of an aquifer system induced by seismotectonic activity may change the mixing ratio of groundwaters with different compositions in a well, leading to hydrochemical signals which in principle could be related to discrete earthquake events. Due to the complexity of the interactions and the multitude of involved factors the identification of such relationships is a difficult task. In this study we present an empiric statistical approach suitable to analyse if there is an interdependency between changes in the chemical composition of monitoring wells and the regional seismotectonic activity of a considered area. To allow a rigorous comparison with hydrochemistry the regional earthquake time series was aggregated into an univariate time series. This was realized by expressing each earthquake in form of a parameter “e”, taking into consideration both energetic (magnitude of a seismic event) and spatial parameters (position of epi/hypocentrum relative to the monitoring site). The earthquake and the hydrochemical time-series were synchronised aggregating the e-parameters into “earthquake activity” functions E, which takes into account the time of sampling relative to the earthquakes which occurred in the considered area. For the definition of the aggregation functions a variety of different “e” parameters were considered. The set of earthquake functions E was grouped by means of factor analysis to select a limited number of significant and representative earthquake functions E to be used further on in the relation analysis with the multivariate hydrochemical data set. From the hydrochemical data a restricted number of hydrochemical factors were extracted. Factor scores allow to represent and analyse the variation of the hydrochemical factors as a function of time. Finally, regression analysis was used to detect those hydrochemical factors which significantly correlate with the aggregated earthquake functions.This methodological approach was tested with a hydrochemical data set collected from a deep well monitored for two years in the seismically active Vrancea region, Romania. Three of the hydrochemical factors were found to correlate significantly with the considered earthquake activities. A screening with different time combinations revealed that correlations are strongest when the cumulative seismicity over several weeks was considered. The case study also showed that the character of the interdependency depends sometimes on the geometrical distribution of the earthquake foci. By using aggregated earthquake information it was possible to detect interrelationships which couldn't have been identified by analysing only relations between single geochemical signals and single earthquake events. Further on, the approach allows to determine the influence of different seismotectonic patterns on the hydrochemical composition of the sampled well. The method is suitable to be used as a decision instrument in assessing if a monitoring site is suitable or not to be included in a monitoring net within a complex earthquake prediction strategy.  相似文献   

Structure of Palaeogene sediments in east Ellesmere Island: Constraints on Eurekan tectonic evolution and implications for the Nares Strait problem     

K. Saalmann  F. Tessensohn  K. Piepjohn  W. von Gosen  U. Mayr 《Tectonophysics》2005,406(1-2):81-113

The “Nares Strait problem” represents a debate about the existence and magnitude of left-lateral movements along the proposed Wegener Fault within this seaway. Study of Palaeogene Eurekan tectonics at its shorelines could shed light on the kinematics of this fault. Palaeogene (Late Paleocene to Early Eocene) sediments are exposed at the northeastern coast of Ellesmere Island in the Judge Daly Promontory. They are preserved as elongate SW–NE striking fault-bounded basins cutting folded Early Paleozoic strata. The structures of the Palaeogene exposures are characterized by broad open synclines cut and displaced by steeply dipping strike-slip faults. Their fold axes strike NE–SW at an acute angle to the border faults indicating left-lateral transpression. Weak deformation in the interior of the outliers contrasts with intense shearing and fracturing adjacent to border faults. The degree of deformation of the Palaeogene strata varies markedly between the northwestern and southeastern border faults with the first being more intense. Structural geometry, orientation of subordinate folds and faults, the kinematics of faults, and fault-slip data suggest a multiple stage structural evolution during the Palaeogene Eurekan deformation: (1) The fault pattern on Judge Daly Promontory is result of left-lateral strike-slip faulting starting in Mid to Late Paleocene times. The Palaeogene Judge Daly basin formed in transtensional segments by pull-apart mechanism. Transpression during progressive strike-slip shearing gave rise to open folding of the Palaeogene deposits. (2) The faults were reactivated during SE-directed thrust tectonics in Mid Eocene times (chron 21). A strike-slip component during thrusting on the reactivated faults depends on the steepness of the fault segments and on their obliquity to the regional stress axes.Strike-slip displacement was partitioned to a number of sub-parallel faults on-shore and off-shore. Hence, large-scale lateral movements in the sum of 80–100 km or more could have been accommodated by a set of faults, each with displacements in the order of 10–30 km. The Wegener Fault as discrete plate boundary in Nares Strait is replaced by a bundle of faults located mainly onshore on the Judge Daly Promontory.  相似文献