A new type of isotopic anomaly in shergottite sulfides     

Heather B. Franz  Nanping Wu  James Farquhar  Anthony J. Irving 《Meteoritics & planetary science》2019,54(12):3036-3051

The isotopic composition and abundance of sulfur in extraterrestrial materials are of interest for constraining models of both planetary and solar system evolution. A previous study that included phase‐specific extraction of sulfur from 27 shergottites found the sulfur isotopic composition of the Martian mantle to be similar to that of terrestrial mid‐ocean ridge basalts, the Moon, and nonmagmatic iron meteorites. However, the presence of positive Δ³³S anomalies in igneous sulfides from several shergottites, indicating incorporation of atmospherically processed sulfur into the subsurface, complicated this interpretation. The current study expands upon the previous work through analyses of 20 additional shergottites, enabling tighter constraints on the isotopic composition of juvenile Martian sulfur. The updated composition (δ³⁴S = ?0.24 ± 0.05‰, Δ³³S = 0.0015 ± 0.0016‰, and Δ³⁶S = 0.039 ± 0.054‰, 2 s.e.m.), representing the weighted mean for all shergottites within the combined population of 47 without significant Δ³³S anomalies, strengthens our earlier result. The presence of sulfur isotopic anomalies in igneous sulfides of some meteorites suggests that their parent magmas may have assimilated crustal material. We observed small negative Δ³³S anomalies in sulfides from two meteorites, NWA 7635 and NWA 11300. Although negative Δ³³S anomalies have been observed in nakhlites and ALH 84001, previous anomalies in shergottites have all shown positive values of Δ³³S. Because NWA 7635 has formation age of 2.4 Ga and is much more ancient than shergottites analyzed previously, this finding expands our perspective on the continuity of Martian atmospheric sulfur photochemistry over geologic time.  相似文献   

Dietary pattern recognition on Twitter: a case example of before,during, and after four natural disasters     

Turner-McGrievy  Gabrielle  Karami  Amir  Monroe  Courtney  Brandt  Heather M. 《Natural Hazards》2020,103(1):1035-1049

Natural Hazards - Little is known about what foods/beverages (F&B) are common during natural disasters. The goal of this study was to track high-frequency F&B mentions during four...  相似文献   

Multi-attribute machine learning analysis for weak BSR detection in the Pegasus Basin,Offshore New Zealand     

Chenin  Julian  Bedle  Heather 《Marine Geophysical Researches》2020,41(4):1-15

Marine Geophysical Research - Much of our knowledge of gas hydrate in the Dongsha area of the South China Sea has been gained through intensive geophysical surveys and drilling. However, many...  相似文献   

How Does Large Flaring Activity from the Same Active Region Produce Oppositely Directed Magnetic Clouds?     

Louise K. Harra  Nancy U. Crooker  Cristina H. Mandrini  Lidia van Driel-Gesztelyi  Sergio Dasso  Jingxiu Wang  Heather Elliott  Gemma Attrill  Bernard V. Jackson  Mario M. Bisi 《Solar physics》2007,244(1-2):95-114

We describe the interplanetary coronal mass ejections (ICMEs) that occurred as a result of a series of solar flares and eruptions from 4 to 8 November 2004. Two ICMEs/magnetic clouds occurring from these events had opposite magnetic orientations. This was despite the fact that the major flares related to these events occurred within the same active region that maintained the same magnetic configuration. The solar events include a wide array of activities: flares, trans-equatorial coronal loop disappearance and reformation, trans-equatorial filament eruption, and coronal hole interaction. The first major ICME/magnetic cloud was predominantly related to the active region 10696 eruption. The second major ICME/magnetic cloud was found to be consistent with the magnetic orientation of an erupting trans-equatorial filament or else a rotation of 160° of a flux rope in the active region. We discuss these possibilities and emphasize the importance of understanding the magnetic evolution of the solar source region before we can begin to predict geoeffective events with any accuracy.  相似文献   

Etch pit formation on iron silicate surfaces during siderophore-promoted dissolution   总被引：1，自引：0，他引：1  

Heather L. Buss  Andreas Lüttge  Susan L. Brantley   《Chemical Geology》2007,240(3-4):326-342

Understanding the effects of microbiota on mineral alteration requires the ability to recognize evidence of bacteria-promoted dissolution on mineral surfaces. Although siderophores are known to promote mineral dissolution, their effects on mineral surfaces are not well known. We have utilized atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and Mirau vertical scanning interferometry (VSI) to investigate surfaces after incubation with the siderophore desferrioxamine-B mesylate (DFAM) and under colonies of bacteria. Iron-silicate glass planchets chemically similar to hornblende were incubated in buffered growth medium with siderophore-producing bacteria (Bacillus sp.) for 46 days with parallel abiotic experiments conducted with and without 240 μM DFAM, with and without 0.01 g l^− 1 of microbially produced extracellular polysaccharides (EPS, alginate or xanthan gum). Some glass planchets were protected by dialysis tubing from direct contact with the EPS. Weekly sampling and analysis of all filtered sample solutions showed negligible Fe and Al release in the control experiments and significant release of Fe and Al in the presence of DFAM, with negligible changes in pH. Concentration of Fe in the filtered solutions after incubation with bacteria was below detection, consistent with uptake of Fe by cells. Release of Fe, Al, and Si in control, xanthan-only, and alginate-only experiments was negligible. Release of these elements was enhanced in all experiments containing DFAM, and greatest in alginate + DFAM experiments.

AFM and VSI analyses reveal widespread, small etch pits and greater root mean squared roughness on siderophore-exposed surfaces and fewer, localized, larger etch pits on bacteria-exposed surfaces. This is the first documented case of etch pit development during siderophore-promoted dissolution. Roughness was not affected by the growth medium, alginate, or xanthan gum alone. The roughness trends among samples correlate with trends in Fe depletion documented by XPS. Enhanced dissolution and roughness cannot be attributed to direct contact with EPS because no significant chemical or physical differences were observed between surfaces directly exposed to EPS and those protected by dialysis tubing. Acetate released from the EPS may have enhanced the siderophore-promoted dissolution. Siderophores produced by Bacillus sp. may be responsible for some of the ‘biopits.’ The difference in size and distribution of the biopits may be related to colonization.  相似文献   

Arsenic incorporation into authigenic pyrite, Bengal Basin sediment, Bangladesh     

Heather A. Lowers  George N. Breit  John Whitney  Md. Nehal Uddin 《Geochimica et cosmochimica acta》2007,71(11):2699-2717

Sediment from two deep boreholes (∼400 m) approximately 90 km apart in southern Bangladesh was analyzed by X-ray absorption spectroscopy (XAS), total chemical analyses, chemical extractions, and electron probe microanalysis to establish the importance of authigenic pyrite as a sink for arsenic in the Bengal Basin. Authigenic framboidal and massive pyrite (median values 1500 and 3200 ppm As, respectively), is the principal arsenic residence in sediment from both boreholes. Although pyrite is dominant, ferric oxyhydroxides and secondary iron phases contain a large fraction of the sediment-bound arsenic between approximately 20 and 100 m, which is the depth range of wells containing the greatest amount of dissolved arsenic. The lack of pyrite in this interval is attributed to rapid sediment deposition and a low sulfur flux from riverine and atmospheric sources. The ability of deeper aquifers (>150 m) to produce ground water with low dissolved arsenic in southern Bangladesh reflects adequate sulfur supplies and sufficient time to redistribute the arsenic into pyrite during diagenesis.  相似文献   

Climatological aspects of convective parameters from the NCAR/NCEP reanalysis   总被引：1，自引：0，他引：1  

Harold E. Brooks  Aaron R. Anderson  Kathrin Riemann  Irina Ebbers  Heather Flachs 《Atmospheric Research》2007,83(2-4):294-305

Annual cycles of convectively important atmospheric parameters have been computed for a variety of from the National Center for Atmospheric Research (NCAR)/National Centers for Environmental Prediction (NCEP) global reanalysis, using 7 years of reanalysis data. Regions in the central United States show stronger seasonality in combinations of thermodynamic parameters than found elsewhere in North America or Europe. As a result, there is a period of time in spring and early summer when climatological mean conditions are supportive of severe thunderstorms.The annual cycles help in understanding the large-scale processes that lead to the combination of atmospheric ingredients necessary for strong convection. This, in turn, lays groundwork for possible changes in distribution of the environments associated with possible global climate change.  相似文献   

Shipping policies of the Arab oil producing countries     

A. D. Couper 《GeoJournal》1978,2(2):107-110

The arab oil producing countries have characteristics of both less developed and more developed countries. They are diversifying their economies and entering into shipping. There are arguments for and against some participation in shipping, but industrialisation generates shipping requirements. These are being met on a Pan Arab basis and by joint ventures with traditional maritime nations.  相似文献   

Hormone loads exported by a tile‐drained agroecosystem receiving animal wastes          下载免费PDF全文

Heather E. Gall  Stephen A. Sassman  Byron Jenkinson  Linda S. Lee  Chad T. Jafvert 《水文研究》2014,28(3):1318-1328

Little is known regarding hormone export from tile‐drained agricultural fields despite the widespread presence of tile drains in the Midwestern United States. By intensively measuring water flow rates and hormone concentrations in four subsurface tile drains and three receiving ditches at a working Midwest farm, hormone fluxes and loads from the tile‐drained fields were quantified. Before and during the 17‐month study period (January 2009 – May 2010), the associated farm fields received various animal waste applications (beef, dairy, poultry, sheep, and swine). Hormones monitored included the estrogens17β‐ and 17α‐estradiol, estrone, and estriol; the natural androgens testosterone, and androstenedione; and the synthetic androgens 17β‐ and 17α‐trenbolone, and trendione. Hormone loads measured in the ditches for three drainage areas during the entire 17‐month study period were in ranges of 16–58 mg/ha for total estrogens, 6.8–19 mg/ha for natural androgens, and 4.2–44 mg/ha for synthetic androgens. Because higher hormone concentrations generally occurred during discrete periods of increased flow, high flow rates often were associated with a disproportionately high hormone flux. For example, 80% of total estrogens and natural androgens exported into the ditches occurred during only 9–26% of the study period, coinciding with the most significant storm events. In addition, hormone fluxes were highest during storm events that occurred shortly after animal waste applications. Therefore, to effectively reduce hormone loads exported to downstream aquatic ecosystems in the absence of any application reduction, the short periods during which high‐flow events occur must be targeted. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Groundwater cooling of a supercomputer in Perth,Western Australia: hydrogeological simulations and thermal sustainability     

Heather A. Sheldon  Peter M. Schaubs  Praveen K. Rachakonda  Michael G. Trefry  Lynn B. Reid  Daniel R. Lester  Guy Metcalfe  Thomas Poulet  Klaus Regenauer-Lieb 《Hydrogeology Journal》2015,23(8):1831-1849

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