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101.
We describe the interplanetary coronal mass ejections (ICMEs) that occurred as a result of a series of solar flares and eruptions from 4 to 8 November 2004. Two ICMEs/magnetic clouds occurring from these events had opposite magnetic orientations. This was despite the fact that the major flares related to these events occurred within the same active region that maintained the same magnetic configuration. The solar events include a wide array of activities: flares, trans-equatorial coronal loop disappearance and reformation, trans-equatorial filament eruption, and coronal hole interaction. The first major ICME/magnetic cloud was predominantly related to the active region 10696 eruption. The second major ICME/magnetic cloud was found to be consistent with the magnetic orientation of an erupting trans-equatorial filament or else a rotation of 160° of a flux rope in the active region. We discuss these possibilities and emphasize the importance of understanding the magnetic evolution of the solar source region before we can begin to predict geoeffective events with any accuracy.  相似文献   
102.
Understanding the effects of microbiota on mineral alteration requires the ability to recognize evidence of bacteria-promoted dissolution on mineral surfaces. Although siderophores are known to promote mineral dissolution, their effects on mineral surfaces are not well known. We have utilized atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and Mirau vertical scanning interferometry (VSI) to investigate surfaces after incubation with the siderophore desferrioxamine-B mesylate (DFAM) and under colonies of bacteria. Iron-silicate glass planchets chemically similar to hornblende were incubated in buffered growth medium with siderophore-producing bacteria (Bacillus sp.) for 46 days with parallel abiotic experiments conducted with and without 240 μM DFAM, with and without 0.01 g l− 1 of microbially produced extracellular polysaccharides (EPS, alginate or xanthan gum). Some glass planchets were protected by dialysis tubing from direct contact with the EPS. Weekly sampling and analysis of all filtered sample solutions showed negligible Fe and Al release in the control experiments and significant release of Fe and Al in the presence of DFAM, with negligible changes in pH. Concentration of Fe in the filtered solutions after incubation with bacteria was below detection, consistent with uptake of Fe by cells. Release of Fe, Al, and Si in control, xanthan-only, and alginate-only experiments was negligible. Release of these elements was enhanced in all experiments containing DFAM, and greatest in alginate + DFAM experiments.

AFM and VSI analyses reveal widespread, small etch pits and greater root mean squared roughness on siderophore-exposed surfaces and fewer, localized, larger etch pits on bacteria-exposed surfaces. This is the first documented case of etch pit development during siderophore-promoted dissolution. Roughness was not affected by the growth medium, alginate, or xanthan gum alone. The roughness trends among samples correlate with trends in Fe depletion documented by XPS. Enhanced dissolution and roughness cannot be attributed to direct contact with EPS because no significant chemical or physical differences were observed between surfaces directly exposed to EPS and those protected by dialysis tubing. Acetate released from the EPS may have enhanced the siderophore-promoted dissolution. Siderophores produced by Bacillus sp. may be responsible for some of the ‘biopits.’ The difference in size and distribution of the biopits may be related to colonization.  相似文献   

103.
Sediment from two deep boreholes (∼400 m) approximately 90 km apart in southern Bangladesh was analyzed by X-ray absorption spectroscopy (XAS), total chemical analyses, chemical extractions, and electron probe microanalysis to establish the importance of authigenic pyrite as a sink for arsenic in the Bengal Basin. Authigenic framboidal and massive pyrite (median values 1500 and 3200 ppm As, respectively), is the principal arsenic residence in sediment from both boreholes. Although pyrite is dominant, ferric oxyhydroxides and secondary iron phases contain a large fraction of the sediment-bound arsenic between approximately 20 and 100 m, which is the depth range of wells containing the greatest amount of dissolved arsenic. The lack of pyrite in this interval is attributed to rapid sediment deposition and a low sulfur flux from riverine and atmospheric sources. The ability of deeper aquifers (>150 m) to produce ground water with low dissolved arsenic in southern Bangladesh reflects adequate sulfur supplies and sufficient time to redistribute the arsenic into pyrite during diagenesis.  相似文献   
104.
Annual cycles of convectively important atmospheric parameters have been computed for a variety of from the National Center for Atmospheric Research (NCAR)/National Centers for Environmental Prediction (NCEP) global reanalysis, using 7 years of reanalysis data. Regions in the central United States show stronger seasonality in combinations of thermodynamic parameters than found elsewhere in North America or Europe. As a result, there is a period of time in spring and early summer when climatological mean conditions are supportive of severe thunderstorms.The annual cycles help in understanding the large-scale processes that lead to the combination of atmospheric ingredients necessary for strong convection. This, in turn, lays groundwork for possible changes in distribution of the environments associated with possible global climate change.  相似文献   
105.
106.
Quasi-continuous fugacity of CO2 (fCO2) data were collected in the eastern Weddell Gyre and southern Antarctic Circumpolar Current (ACC) of the Southern Ocean during austral autumn 1996. Full depth Total CO2 (TCO2) sections are presented for austral autumn and winter (1992) cruises. Pronounced fCO2 gradients were observed at the Southern Ocean fronts. In the Weddell Gyre, fCO2 regimes appeared to coincide with surface and subsurface hydrographic regimes. The southern ACC was supersaturated with respect to CO2, as was part of the northern Weddell Gyre. The southern Weddell Gyre was markedly undersaturated. The great potential of autumn cooling for generating undersaturation and CO2 uptake from the atmosphere was demonstrated. In the northeastern Weddell Gyre, upwelling of CO2- and salt-rich deep water was shown to play a role as the horizontal fCO2 distribution closely resembled that of the surface salinity. The total uptake of atmospheric CO2 by the Weddell Gyre in autumn (45 days) was calculated to be 7·1012 g C. The deep TCO2 distribution noticeably reflected the different water masses in the region. A new deep TCO2 maximum was detected in the ACC, which apparently characterizes the boundary between the equatorward flowing Antarctic Bottom Water (AABW) and the Circumpolar Deep Water (CDW). East of the Weddell Gyre, the AABW stratum is much thicker (>2000 m) than more to the west, on the prime meridian (<300 m).  相似文献   
107.
108.
Little is known regarding hormone export from tile‐drained agricultural fields despite the widespread presence of tile drains in the Midwestern United States. By intensively measuring water flow rates and hormone concentrations in four subsurface tile drains and three receiving ditches at a working Midwest farm, hormone fluxes and loads from the tile‐drained fields were quantified. Before and during the 17‐month study period (January 2009 – May 2010), the associated farm fields received various animal waste applications (beef, dairy, poultry, sheep, and swine). Hormones monitored included the estrogens17β‐ and 17α‐estradiol, estrone, and estriol; the natural androgens testosterone, and androstenedione; and the synthetic androgens 17β‐ and 17α‐trenbolone, and trendione. Hormone loads measured in the ditches for three drainage areas during the entire 17‐month study period were in ranges of 16–58 mg/ha for total estrogens, 6.8–19 mg/ha for natural androgens, and 4.2–44 mg/ha for synthetic androgens. Because higher hormone concentrations generally occurred during discrete periods of increased flow, high flow rates often were associated with a disproportionately high hormone flux. For example, 80% of total estrogens and natural androgens exported into the ditches occurred during only 9–26% of the study period, coinciding with the most significant storm events. In addition, hormone fluxes were highest during storm events that occurred shortly after animal waste applications. Therefore, to effectively reduce hormone loads exported to downstream aquatic ecosystems in the absence of any application reduction, the short periods during which high‐flow events occur must be targeted. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
109.
110.
The Musgrave Province developed at the nexus of the North,West and South Australian cratons and its Mesoproterozoic evolution incorporates a 100 Ma period of ultra-high temperature(UHT) metamorphism from ca.1220 to ca.1120 Ma.This was accompanied by high-temperature A-type granitic magmatism over an 80 Ma period,sourced in part from mantle-derived components and emplaced as a series of pulsed events that also coincide with peaks in UHT metamorphism.The tectonic setting for this thermal event(the Musgrave Orogeny) is thought to have been intracontinental and the lithospheric architecture of the region is suggested to have had a major influence on the thermal evolution.We use a series of two dimensional,fully coupled thermo-mechanical-petrological numerical models to investigate the plausibility of initiating and prolonging UHT conditions under model setup conditions appropriate to the inferred tectonic setting and lithospheric architecture of the Musgrave Province.The results support the inferred tectonic framework for the Musgrave Orogeny,predicting periods of UHT metamorphism of up to 70 Ma,accompanied by thin crust and extensive magmatism derived from both crustal and mantle sources.The results also appear to be critically dependent upon the specific location of the Musgrave Province,constrained between thicker cratonic masses.  相似文献   
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