The distribution of Fe and Mg between olivine and lunar basaltic liquids     

John Longhi  David Walker  James F. Hays 《Geochimica et cosmochimica acta》1978,42(10):1545-1558

We have examined the Fe and Mg distribution between coexisting olivine and lunar basaltic liquids produced by equilibrium partial melting of natural lunar samples. In agreement with the findings of Roeder and Emslie (Contrib. Mineral. Petrol. 29, 275–289) on terrestrial compositions, the logarithms of the conventional distribution coefficients, K_ol-L^Fe and K_ol-L^Fe-Mg, are nearly linear functions of inverse temperature; and the exchange coefficient, K_D = K_ol-L^Fe-Mg, is nearly independent of temperature and composition within a given magma group. There are, however, small but significant differences in conventional and exchange distribution coefficients from one magma group to another, e.g. low-Ti vs high-Ti lunar basalts. It is possible to achieve slightly greater precision for the inverse temperature functions by including terms approximating silica activity in the conventional distribution coefficients. The term ($\text{2Si}\text{O}\text{)}{}_{\mathrm{L}}$ is apparently the best simple approximation for silica activity in olivine-saturated liquids based upon data for Fe, Mg, Mn, Ca, Ti and Cr. Pressure has noticeable effects upon Fe and Mg distribution between olivine and liquid only above 5 kbar.The excellent linear correlation of the logarithms of the distribution coefficients with inverse temperature allows calculation of approximate values of $\text{Δ}\text{H}\text{?}{}^0$ for the reactions : 2MgO_L + SiO_2LaiMg₂SiO_4ol and 2FeO_L + SiO_2LaiFe₂SiO_4ol. Values obtained, approx ?26 kcal/mole, are comparable with values of the heats of fusion of forsterite and fayalite calculated by Bradley (Am. J. Sci.260, 550–554) and measured by Orr (J. Am. Chem. Soc. 75, 528–529).The exchange distribution coefficient for Fe and Mg, K_D, is sensitive to large changes in liquid chemistry. Although K_D is explicitly independent of silica activity, K_D apparently changes with silica concentration. This change is a reflection of changes in the mixing properties of Fe and Mg in liquids with different chemistry and hence structure. Regular solution theory predicts that as the mixing properties of an element in a solution change, the most radical changes in activity coefficients occur in the range of dilute concentrations. Therefore, the distribution coefficients for trace elements will also be dependent upon large changes in liquid chemistry, even if corrections for silica and other liquid component activities are applied.  相似文献   

Evaluation of 14th-order harmonics in the geopotential     

D.G. King-Hele  Doreen M.C. Walker  R.H. Gooding 《Planetary and Space Science》1979,27(1):1-18

The Earth's gravitational potential is now usually expressed in terms of a double series of tesseral harmonics with several hundred terms, up to order and degree at least 20. The harmonics of order 14 can be evaluated by analysing changes in satellite orbits which experience 14th-order resonance, when the track over the Earth repeats after 14 revolutions.In this paper we describe our first evaluation of individual 14th-order coefficients in the geopotential from analysis of the variations in inclination and eccentricity of satellite orbits passing through 14th-order resonance under the action of air drag. Using results from eleven satellites, we find the following values for normalized coefficients of harmonics of order 14 and degree l, C?_{l, 14} and S?_{l, 14}, for l=14, 154. 22:

Luminescence dating of the last earthquake of the Sabzevar thrust fault, NE Iran     

Morteza Fattahi  Richard T. Walker 《Quaternary Geochronology》2007,2(1-4):284-289

Iran is one of the world's most tectonically active regions, yet dating past earthquakes for neotectonic studies has been limited. One of the main reasons for this is that organic material suitable for radiocarbon dating of deformed sediments is rare. We investigate the use of infrared stimulated luminescence (IRSL) from coarse-grained feldspars to date colluvial deposits associated with the Sabzevar thrust fault in northeastern Iran. The single-aliquot regenerative (SAR) dose measurement procedure was used for this study. The current study investigates monitoring and correcting for sensitivity changes, recovering a known laboratory dose and equivalent dose estimation using three SAR IRSL methods. It is shown that SAR has recovered a given laboratory dose using a range of preheat temperatures but D_e determination of natural samples requires its own preheat plateaus for two of these SAR methods. The SAR IRSL method provided an age of 1.7±0.3 ka for colluvium, predating the last earthquake event on the Sabzevar fault. This result suggests that this fault is likely to be responsible for an earthquake that destroyed Sabzevar city in AD 1052.  相似文献   

A decade of the Super Dual Auroral Radar Network (SuperDARN): scientific achievements, new techniques and future directions   总被引：2，自引：0，他引：2  

G. Chisham  M. Lester  S. E. Milan  M. P. Freeman  W. A. Bristow  A. Grocott  K. A. McWilliams  J. M. Ruohoniemi  T. K. Yeoman  P. L. Dyson  R. A. Greenwald  T. Kikuchi  M. Pinnock  J. P. S. Rash  N. Sato  G. J. Sofko  J.-P. Villain  A. D. M. Walker 《Surveys in Geophysics》2007,28(1):33-109

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