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111.
Smruti?Sourav?RoutEmail authorView author&#;s OrcID profile Gerhard?W?rner 《Contributions to Mineralogy and Petrology》2018,173(11):95
Compositional zoning and exsolution patterns of alkali feldspars in carbonatite-bearing cognate syenites from the 6.3 km3 (D.R.E) phonolitic Laacher See Tephra (LST) deposit in western Germany (12.9 ka) are reported. These rocks represent the cooler outer portion and crystal-rich products of a cooling magma reservoir at upper crustal levels. Major and trace-element difference between cores and rims in sanidine crystals represent two generations of crystal growth separated by unmixing of a carbonate melt. Trace-element differences measured by LA–ICP–MS are in accordance with silicate–carbonate unmixing. Across the core–rim boundary, we extracted gray-scale profiles from multiple accumulations of back-scattered electron images. Gray scales directly represent K/Na ratios owing to low concentrations of Ba and Sr (<?30 ppm). Diffusion gradients are modeled to solve for temperature using known pre-eruptive U–Th zircon ages (0–20 ky) of each sample (Schmitt et al., J Petrol 51:1053–1085, 2010). Estimated temperatures range from 630 °C to 670 °C. For the exsolution boundaries, a diffusive homogenization model is constrained by the solvus temperature of ~ 712_725 °C and gives short time scales of only 15–50 days. Based on our results, we present a model for the temperature–time history of these rocks. The model also constrains the thermal variation across the cooling crystal-rich carapace of the magma reservoir over 20 ka and suggests a thermal reactivation of cumulates, the cooling carapace, and probably the entire system only a few years prior to the explosive eruption of the remaining molten core of the phonolitic magma reservoir. 相似文献
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113.
Artur?BenisekEmail authorView author&#;s OrcID profile Edgar?Dachs 《Contributions to Mineralogy and Petrology》2018,173(11):90
The internal energies and entropies of 21 well-known minerals were calculated using the density functional theory (DFT), viz. kyanite, sillimanite, andalusite, albite, microcline, forsterite, fayalite, diopside, jadeite, hedenbergite, pyrope, grossular, talc, pyrophyllite, phlogopite, annite, muscovite, brucite, portlandite, tremolite, and CaTiO3–perovskite. These thermodynamic quantities were then transformed into standard enthalpies of formation from the elements and standard entropies enabling a direct comparison with tabulated values. The deviations from reference enthalpy and entropy values are in the order of several kJ/mol and several J/mol/K, respectively, from which the former is more relevant. In the case of phase transitions, the DFT-computed thermodynamic data of involved phases turned out to be accurate and using them in phase diagram calculations yields reasonable results. This is shown for the Al2SiO5 polymorphs. The DFT-based phase boundaries are comparable to those derived from internally consistent thermodynamic data sets. They even suggest an improvement, because they agree with petrological observations concerning the coexistence of kyanite?+?quartz?+?corundum in high-grade metamorphic rocks, which are not reproduced correctly using internally consistent data sets. The DFT-derived thermodynamic data are also accurate enough for computing the P–T positions of reactions that are characterized by relatively large reaction enthalpies (>?100 kJ/mol), i.e., dehydration reactions. For reactions with small reaction enthalpies (a few kJ/mol), the DFT errors are too large. They, however, are still far better than enthalpy and entropy values obtained from estimation methods. 相似文献
114.
Yong Chen Jing Duan Junling An Huizhi Liu Ulrich G?rsdorf Franz H.Berger 《大气和海洋科学快报》2021,14(5):24-29
卫星估雨精度的不确定性受到当地降雨类型和像元内降雨非均匀性影响,而结合这两个关键因素开展半干旱草原卫星估雨的研究有限.2009年夏,我们在中国锡林郭勒半干旱草原用多部微雨雷达和雨量计构建了9 km卫星像元降雨观测网,观测了像元内降雨非均匀性(空间变异系数CV),并评估了卫星估雨精度.结果表明:(1)CV值受像元内平均降雨量,降雨类型,降雨云面积及移向等影响,如高Cv值的降雨过程大多为平均降雨量小,对流性降雨过程,降雨云边缘像元CV值较高;(2)TRMM 3B42V7卫星估雨产品适用性较好,CMORPH和PERSIANN次之,但TRMM 3B42V7易在半干旱草原湖泊处高估降雨. 相似文献
115.
Aude?ValadeEmail authorView author&#;s OrcID profile Sebastiaan?Luyssaert Patrick?Vallet Sylvestre?Njakou Djomo Ingride?Jesus Van Der Kellen Valentin?Bellassen 《Carbon balance and management》2018,13(1):26
Background
Concern about climate change has motivated France to reduce its reliance on fossil fuel by setting targets for increased biomass-based renewable energy production. This study quantifies the carbon costs and benefits for the French forestry sector in meeting these targets. A forest growth and harvest simulator was developed for French forests using recent forest inventory data, and the wood-use chain was reconstructed from national wood product statistics. We then projected wood production, bioenergy production, and carbon balance for three realistic intensification scenarios and a business-as-usual scenario. These intensification scenarios targeted either overstocked, harvest-delayed or currently actively managed stands.Results
All three intensification strategies produced 11.6–12.4 million tonnes of oil equivalent per year of wood-based energy by 2026, which corresponds to the target assigned to French wood-energy to meet the EU 2020 renewable energy target. Sustaining this level past 2026 will be challenging, let alone further increasing it. Although energy production targets can be reached, the management intensification required will degrade the near-term carbon balance of the forestry sector, compared to continuing present-day management. Even for the best-performing intensification strategy, i.e., reducing the harvest diameter of actively managed stands, the carbon benefits would only become apparent after 2040. The carbon balance of a strategy putting abandoned forests back into production would only break even by 2055; the carbon balance from increasing thinning in managed but untended stands would not break even within the studied time periods, i.e. 2015–2045 and 2046–2100. Owing to the temporal dynamics in the components of the carbon balance, i.e., the biomass stock in the forest, the carbon stock in wood products, and substitution benefits, the merit order of the examined strategies varies over time.Conclusions
No single solution was found to improve the carbon balance of the forestry sector by 2040 in a way that also met energy targets. We therefore searched for the intensification scenario that produces energy at the lowest carbon cost. Reducing rotation time of actively managed stands is slightly more efficient than targeting harvest-delayed stands, but in both cases, each unit of energy produced has a carbon cost that only turns into a benefit between 2060 and 2080.116.
Schubert Michael Michelsen Nils Schmidt Axel Eichenauer Laura Knoeller Kay Arakelyan Alexander Harutyunyan Lilith Schüth Christoph 《Hydrogeology Journal》2021,29(7):2517-2527
Within the Ararat Valley (Armenia), a continuously growing water demand (for irrigation and fish farming) and a simultaneous decline in groundwater recharge (due to climate change) result in increasing stress on the local groundwater resources. This detrimental development is reflected by groundwater-level drops and an associated reduction of the area with artesian conditions in the valley centre. This situation calls for increasing efforts aimed at more sustainable water resources management. The aim of this baseline study was the collection of data that allows for study on the origin and age distribution of the Ararat Valley groundwater based on environmental tracers, namely stable (δ2H, δ18O) and radioactive (35S, 3H) isotopes, as well as physical-chemical indicators. The results show that the Ararat Valley receives modern recharge, despite its (semi-)arid climate. While subannual groundwater residence times could be disproved (35S), the detected 3H pattern suggests groundwater ages of several decades, with the oldest waters being recharged around 60 years ago. The differing groundwater ages are reflected by varying scatter of stable isotope and hydrochemical signatures. The presence of young groundwater (i.e., younger that the 1970s), some containing nitrate, indicates groundwater vulnerability and underscores the importance of increased efforts to achieve sustainable management of this natural resource. Since stable isotope signatures indicate the recharge areas to be located in the mountains surrounding the valley, these efforts must not be limited to the central part of the valley where most of the abstraction wells are located.
相似文献117.
118.
GIS-based assessment of landslide susceptibility on the base of the Weights-of-Evidence model 总被引：4，自引：2，他引：2
The major scope of the study is the assessment of landslide susceptibility of Flysch areas including the Penninic Klippen in the Vienna Forest (Lower Austria) by means of Geographical Information System (GIS)-based modelling. A statistical/probabilistic method, referred to as Weights-of-Evidence (WofE), is applied in a GIS environment in order to derive quantitative spatial information on the predisposition to landslides. While previous research in this area concentrated on local geomorphological, pedological and slope stability analyses, the present study is carried out at a regional level. The results of the modelling emphasise the relevance of clay shale zones within the Flysch formations for the occurrence of landslides. Moreover, the distribution of mass movements is closely connected to the fault system and nappe boundaries. An increased frequency of landslides is observed in the proximity to drainage lines, which can change to torrential conditions after heavy rainfall. Furthermore, landslide susceptibility is enhanced on N-W facing slopes, which are exposed to the prevailing direction of wind and rainfall. Both of the latter geofactors indirectly show the major importance of the hydrological conditions, in particular, of precipitation and surface runoff, for the occurrence of mass movements in the study area. Model performance was checked with an independent validation set of landslides, which are not used in the model. An area of 15% of the susceptibility map, classified as highly susceptible, “predicted” 40% of the landslides. 相似文献
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120.
The ability of turbulent nuées ardentes (surges) to transport coarse pyroclasts has been questioned on the basis that settling velocities of coarse fragments in the deposits are much too high for them to have been supported by turbulence in a dilute gas suspension. A computer model is used to evaluate the settling velocity of pyroclasts in suspensions of varying concentration and temperature. Since suspension of grains in low-concentration surges occurs if the shear velocity exceeds the settling velocity, the shear velocities related to the 16th and 84th percentiles, and the mean of the grain-size distribution are compared in surge deposits of the Vulsini, with the shear velocity necessary to move the coarsest grain on the bed surface (the Shields criterion). The results show that the settling velocities do not vary significantly in gaseous suspensions having volume concentrations lower than 15%, and that an increase in concentration to 25% is not sufficient to decrease the settling velocity of the coarser fraction, if it represents flow shear velocity. It is shown that the settling velocity of the mean grain size (M
z
) best depicts the shear velocity of a dilute turbulent suspension. Applying the results to the May 1902 paroxysmal nuées ardentes of Mount Pelée shows that the estimated mean velocities are well within the observed velocities, and sufficient to support all the clasts in dilute, turbulent suspensions. 相似文献