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11.
12.
David L. Finnegan Janet P. Kotra Diane M. Hermann William H. Zoller 《Bulletin of Volcanology》1989,51(2):83-87
A simple system was designed using7LiOH-impregnated filters to collect acidic gases from ambient air and from highly concentrated volcanic plumes or gas streams. These filters were developed for analysis using instrumental neutron activation analysis, but other analytical techniques could be used as well. The sampling system was designed to use a series of 1–3 M7LiOH-impregnated filters to collect high concentrations of acidic gases found in gas plumes of active volcanoes. The filters are quantitative for SO2 and the halide acids when sufficient base is present to neutralize the acidic species. Extremely high concentrations of SO2 may not be collected quantitatively since SO2 is a relatively weak Lewis acid compared to the halide acids. The acidic oxides of Sb, As, and Se were also collected quantitatively. A particle filter preceded the impregnated filters in order to remove particles from the fumes. This system has proven effective under difficult sampling conditions and, since it is portable and light weight, it could be used for many volcanological applications where high levels of acidic gaseous phase species need to be collected. 相似文献
13.
A. A. Held P. Steduto F. Orgaz A. Matista T. C. Hsiao 《Theoretical and Applied Climatology》1990,42(4):203-213
Summary This paper describes a Bowen ratio/energy balance (BREB) system which, in conjunction with an infra-red gas analyzer (IRGA), is referred to as BREB+ and is used to estimate evapotranspiration (ET) and net CO2 flux (NCF) over crop canopies. The system is composed of a net radiometer, soil heat flux plates, two psychrometers based on platinum resistance thermometers (PRT), bridge circuits to measure resistances, an IRGA, air pumps and switching valves, and a data logger. The psychrometers are triple shielded and aspirated, and with aspiration also between the two inner shields. High resistance (1 000 ohm) PRT's are used for dry and wet bulbs to minimize errors due to wiring and connector resistances. A high (55 K ohm) fixed resistance serves as one arm of the resistance bridge to ensure linearity in output signals. To minimize gaps in data, to allow measurements at short (e.g., 5 min) intervals, and to simplify operation, the psychrometers were fixed at their upper and lower position over the crop and not alternated. Instead, the PRT's, connected to the bridge circuit and the data logger, were carefully calibrated together. Field tests using a common air source showed appartent effects of the local environment around each psychrometer on the temperatures measured.
ET rates estimated with the BREB system were compared to those measured with large lysimeters. Daily totals agreed within 5%. There was a tendency, however, for the lysimeter measurements to lag behind the BREB measurements. Daily patterns ofNCF estimated with the BREB+ system are consistent with expectations from theories and data in the literature. Side-by-side comparisons with a stirred Mylar canopy chamber showed similarNCF patterns. On the other hand, discrepancies between the results of the two methods were quite marked in the morning or afternoon on certain dates. Part of the discrepancies may be attributed to inaccuracies in the psychrometric temperature measurements. Other possible causes include the highly artificial air turbulence in the canopy chamber and possible associated stomatal response. More work is necessary to identify conclusively the causes. In spite of these uncertainties, the BREB+ technique appears well suited for the automated and simultaneous tracking of photosynthetic performance and water economy of crops in their virtually undisturbed natural environment.To whom reprint requests should be sent.With 7 Figures 相似文献
14.
Chemical degradations of coal resins, coal asphaltenes and coal residues have been performed with selective, non-oxidative reagents. The coal comprise samples a rank interval 0.30–1.21 %Rm. Degraded low-molecular-weight compounds were analyzed by GC-MS. The distributions of pentacyclic terpanes, isoprenoids, n-alkanes, acids and alcohols obtained as degradation products illustrate a considerable variability between the macromolecular coal fractions. A structural study on the molecular level of the degraded compounds from coal resins and coal asphaltenes show their potential to generate hydrocarbons during coalification process. 相似文献
15.
Besides systematic instrumental and environmental effects in high-precision levellings and gravimetry, some theoretical problems are decisive in the evaluation and interpretation of recent vertical crustal movements. In view of the increased accuracy of recently developed portable instruments for absolute gravity measurements, some global effects on gravity may no longer be neglected, necessitating additional time-dependent reductions for polar motion effects. Another problem concerns the evaluation of recent vertical crustal movements from repeated geodetic measurements: a rigorous treatment of the problem demands both repeated levellings and gravity measurements; only under additional hypotheses can these limitating prerequisites be eliminated. 相似文献
16.
The OECD soil, which is standardised for use in the sediment toxicity with the midge Chironomus riparius revealed inhibition of the nematode Caenorhabditis elegans in body growth length and egg production of 41.0% and 84%, respectively. 18 formulated sediments were tested to optimise the sediment composition for growth and reproduction of C. elegans. Their components were chosen to simulate native sediments, whereby different quantities and different clay minerals were tested. The mixture that we found to be optimal in our experiments consisted of 5% sphagnum peat, 70% calcitic sand, 0.5% dolomite limestone, 4.5% iron(III) oxide, and a clay combination of 1.5% chlorite and 18.5% aluminium(III) oxide. When applying this mixture to C. riparius, the new formulated sediment improved also growth in comparison to the OECD sediment. 相似文献
17.
18.
Hermann Harder 《International Journal of Earth Sciences》1955,43(2):515-518
Zusammenfassung Sedimentäre Eisenerze können durch Ausflocken von Fe+++haltigen Solen und durch Ausfällen von Fe++haltigen Lösungen gebildet werden. Aus Solen gebildete Erze werden als Begleitelemente Kieselsäure und Aluminium anreichern, während aus Lösungen gebildete Erze manganreicher sind und Kieselsäure und Aluminium zurücktreten. 相似文献
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20.
This study uses a numerical model to investigate the groundwater flow and salt transport mechanisms below islands in the Okavango Delta. Continuous evapotranspiration on the islands results in accumulation of solutes and the formation of a saline boundary layer, which may eventually become unstable. A novel Lagrangian method is employed in this study and compared to other numerical methods. The numerical results support the geophysical observations of density fingering on Thata Island. However, the process is slow and it takes some hundreds of years until density fingering is triggered. The results are sensitive to changes of the hydraulic gradient and the evapotranspiration rate. Small changes may lead to different plume developments. Results further demonstrate that density effects may be entirely overridden by lateral flow on islands embedded in a sufficiently high regional hydraulic gradient. 相似文献