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R. Herrero B. Cordero P. Lodeiro C. Rey-Castro M.E. Sastre de Vicente 《Marine Chemistry》2006,99(1-4):106
Samples of dead biomass from the marine brown algae Fucus ceranoides, Fucus vesiculosus and Fucus serratus were studied for their ability to remove cadmium from aqueous solutions. The metal sorption process is rapid, with 90% of the metal uptake completed within the first 25 min of contact. The kinetic data was described successfully by a pseudo second order chemical sorption process with rate constants of ca. 0.6 g mmol− 1 min− 1. At pH 4.5, the raw biomass of the three species exhibited equilibrium uptake capacities for Cd as high as 0.8 mmol g− 1 (90 mg g− 1), on a dry weight basis, without chemical pretreatment. These sorption capacities are much higher than those reported for activated carbon and chitin. The sorption of Cd was found to increase as pH increases, reaching a plateau at pH 5.Batch sorption experiments and continuous potentiometric titrations of acid-treated biomass samples in 0.05 M NaNO3 were used to derive thermodynamic binding parameters according to the NICCA model. The total amount of acid sites was 2.4–2.9 mmol g− 1, with median values of the affinity distribution for protons and cadmium ions, log K˜H and log K˜Cd, of 3.7 and 2.69, respectively (conditional values). The apparent heterogeneity of the sorbent was successfully taken into account by the empirical NICCA isotherm, which described very well the competition between protons and metal ions, in contrast with a simpler discrete competitive Langmuir model.The experimental results demonstrate that these seaweeds constitute a promising, efficient, cheap and biodegradable sorbent biomaterial for cadmium removal from wastewaters. This use would represent an example of exploitation of a renewable marine resource in water treatment technologies for the prevention of heavy metal pollution in the environment. 相似文献
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Clay mineral occurrence and burial transformations: reservoir potential of the Permo‐Triassic sediments of the Iberian Range 下载免费PDF全文
The diagenetic evolution of Permian (Autunian and Saxonian) and Triassic (Buntsandstein) sandstones and mudrocks have been studied over 1000 m sequence from the Sigüenza 44‐3 drill core in the Iberian Range, Spain. We compare and contrast the diagenetic processes in these different lithologies and the timing of clay mineral formation. Moreover, we establish the relationship between clay mineral diagenesis and reservoir potential. Both the Permian and Triassic successions are characterised by conglomerates, sandstones and interbedded mudstones of fluvial origin that change upwards into distal deposits of a fluvio‐deltaic system. The clay minerals are illite, illite‐smectite mixed layers, kaolinite and dickite. The illite content in all sequences is not related to diminished feldspars; it is owing to the initial detrital mineralogical composition of the Autunian sandstones. The effect of feldspar alteration to kaolin minerals has a strong influence on the lost of porosity‐permeability in the Saxonian facies. In contrast, illite and mixed layers illite‐smectite are the main clay rims preserving porosity in the Buntsandstein sandstones. However, fibrous illite is the dominant pore‐filling in the Permian Autunian facies, closing porosity and permeability. Kaolinite and dickite show opposite trends: dickite increases yet kaolinite decreases from Triassic to Permian sandstones. Dickite replaced kaolinite during burial‐thermal evolution of the succession. The δD and δ18O isotopic signatures from silt and clay fractions indicate a mixture of meteoric and marine waters, and suggest a minimum temperature range between 60 and 150 °C for diagenetic pore fluids. The Permian δD values (?24‰ to ?44‰) are relatively similar to Buntsandstein values (?24‰ to ?37‰). However, the Permian δ18O values (+7.6 and +15.3, average of +13.3‰) are generally higher by ca. 6.2‰ compared to the Buntsandstein data (4.8–10.1‰, average +7.1‰). Such a variation is interpreted as the result of mesodiagenetic pore fluid changes. The extensive dickitisation of kaolinite is attributed to increased hydrogen ions resulting from maturation of organic matter. The vitrinite reflectance of organic matter and the modelled thermal history suggest a maximum burial of 3400 m, accomplished 70 Ma ago. The Permo‐Triassic reached the gas window shortly before major uplift, at 65 Ma, when further maturation and hydrocarbon expulsion ceased. 相似文献
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We present in this contribution a revision of the origin, main properties and open issues in the field of winds of massive blue stars, with a particular emphasis in the ultraviolet observations 相似文献
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Simulation of glacial-interglacial cycles by simple relaxation models: consistency with observational results 总被引:1,自引:0,他引:1
The model of Paillard and Parrenin (Earth Planet Sci Lett 227:263–271, 2004) was modified to obtain a closer fit to δ18O and CO2 time series for the last 800 kyr. The model performance can be improved if its CO2 sensitivity to I65 insolation is eliminated and if different response times are assumed for ablation/accumulation of ice. Correlations between simulated and experimental time series for CO2 and ice volume V increase from 0.59 and 0.63 to 0.79 and 0.88, respectively. According to these models, terminations are produced by I65 amplification through CO2-T and T-CO2 feedbacks, in synergy with an extra CO2 contribution from the deep ocean. This contribution is strongly dependent on ice-sheet extent and ice volume (or alternatively, CO2 concentration, which is a good proxy of Antarctic temperature) but is insensitive to Southern Ocean (SO) insolation on 21 February (I60). Change of deep SO state may be the “order parameter” for nonlinear deglacial changes. According to these models, 100 kyr periodicity of glacial cycles arises from the characteristic time of Antarctic ice sheet advance to the continental slope. 相似文献
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Lead isotope study of Zn-Pb ore deposits associated with the Basque-Cantabrian basin and Paleozoic basement, Northern Spain 总被引:2,自引:0,他引:2
A total of forty-three galena samples from syngenetic and epigenetic Pb-Zn mineralizations emplaced in the Lower Cretaceous Basque-Cantabrian basin and Paleozoic basement of the Cinco Villas massif in the western Pyrenees, have been analyzed for Pb-isotopic composition. Galena from sedex mineralizations hosted in Carboniferous clastic rocks in the Cinco Villas massif display an homogeneous lead isotopic signature (206Pb/2044Pb 18.43, 207Pb/204Pb 15.66, 208Pb/ 204Pb 38.69) suggesting a single lead reservoir. These values are slightly more radiogenic than lead from other European Hercynian deposits, possibly reflecting the influence of a more evolved upper crustal source. Underlying Paleozoic sediments are proposed as lead source for the Cinco Villas massif ores. Analyses from twenty-six galena samples from the four strata-bound ore districts hosted in Mesozoic rocks reveal the existence of two populations regarding their lead isotopic composition. Galena from the western Santander districts (e.g., Reocin) is characterized by more radiogenic isotope values (206Pb/204Pb 18.74, 207Pb/204Pb 15.67, 208Pb/ 204Pb 38.73) than those from the central and eastern districts (Troya-Legorreta, Central and Western Vizcaya, 206Pb/204Pb 18.59, 207Pb/204Pb 15.66, 208Pb/ 204Pb 38.73). In all districts, the most likely source for these mineralizations was the thick sequence of Lower Cretaceous clastic sediments. The existence of two separate lead isotopic populations could be the result of regional difference in the composition of the basement rocks and the clastic sediments derived of it or different evolution histories. In both sub-basins, isotopic ratios indicate an increase in crustal influence as the age of the ores decreases. 相似文献
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Llanes Francesca V. Eco Rodrigo Herrero Tatum Miko Briones Jo Brianne Louise Escape Carmille Marie Sulapas Jolly Joyce Galang Jan Albert Macario Ortiz Iris Jill Sabado Jasmine May Lagmay Alfredo Mahar Francisco Rodolfo Kelvin 《Natural Hazards》2022,114(1):665-690
Natural Hazards - In October 2015, heavy rains brought by Typhoon Koppu generated landslides and debris flows in the municipalities of Bongabon, Laur, and Gabaldon in Nueva Ecija province.... 相似文献
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D. Moret‐Fernández J. Vicente B. Latorre F. Lera C. Castañeda M. V. López J. Herrero 《水文研究》2012,26(2):246-254
The water retention curve (θ(ψ)), which defines the relationship between soil volumetric water content (θ) and matric potential (ψ), is of paramount importance in characterizing the hydraulic behaviour of soils. However, few methods are so far available for estimating θ(ψ) in undisturbed soil samples. We present a new design of TDR‐pressure cell (TDR‐Cell) for estimating θ(ψ) in undisturbed soil samples. The TDR‐Cell consists of a 50‐mm‐long and 50‐mm internal diameter stainless steel cylinder (which constitutes the outer frame of a coaxial line) attached to a porous ceramic disc and closed at the ends with two aluminium lids. A 49‐mm‐long and 3‐mm‐diameter stainless steel rod, which runs longitudinally through the centre of the cylinder, constitutes the inner rod of a coaxial TDR probe. The TDR‐Cell was used to determine the θ(ψ) curves of a packed sand and seven undisturbed soil samples from three profiles of agricultural soils. These θ(ψ) curves were subsequently compared to those obtained from the corresponding 2‐mm sieved soils using the pressure plate method. Measurements of bulk electrical conductivity, σa, as a function of the water content, σa(θ), of the undisturbed soil samples were also performed. An excellent correlation (R2 = 0·988) was found between the θ values measured by TDR on the different undisturbed soils and the corresponding θ obtained from the soil gravimetric water content. A typical bimodal θ(ψ) function was found for most of the undisturbed soil samples. Comparison between the θ(ψ) curves measured with the TDR‐Cell and those obtained from the 2‐mm sieved soils showed that the pressure plate method overestimates θ at low ψ values. The σa(θ) relationship was well described by a simple power expression (R2 > 0·95), in which the power factor, defined as tortuosity, ranged between 1·18 and 3·75. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献