Degradation of common pharmaceuticals and personal care products in mixed solutions by advanced oxidation techniques   总被引：6，自引：6，他引：0  

R. R. Giri Ph.D.  H. Ozaki D.Eng.  S. Ota  R. Takanami M.Eng.  S. Taniguchi M.Eng. 《International Journal of Environmental Science and Technology》2010,7(2):251-260

Widespread detection of pharmaceutical compounds in water environment has been a serious concern recently, while conventional sewage treatments are ineffective for their elimination. But, advanced oxidation techniques are very promising to remove varieties of organic contaminants in water. This research aims to elucidate oxidation potentials of sixteen commonly used pharmaceutical compounds in mixed solutions by seven advanced oxidation techniques in laboratory batch experiments. The removal profiles exhibited four distinct patterns: a) easily degradable by all seven techniques, b) not easily degradable by all seven techniques, c) easily degradable by ozone-based techniques, but not by ultraviolet radiation-based techniques and d) easily degradable by ultraviolet radiation-based techniques, but not by ozone-based techniques. Ozone-based techniques rather than ultraviolet radiation-based techniques were very powerful for simultaneous removal of the compounds efficiently. Moreover, ozonation combined with ultraviolet radiation was the most appropriate technique for simultaneous removal of the tested compounds efficiently. Increased ozone dissolution and decomposition with ozone-based techniques did not always enhance the compounds’ removal. Physicochemical properties of the compounds and solution pH also presumably played an important role on the removal which merits further attention.  相似文献   

Coupled alkali-feldspar dissolution and secondary mineral precipitation in batch systems: 1. New experiments at 200 °C and 300 bars     

Qi Fu  Peng Lu  Hiromi Konishi  Robert Dilmore  Huifang Xu  W.E. Seyfried  Chen Zhu 《Chemical Geology》2009,258(3-4):125-135

Batch reactor experiments were conducted to assess perthitic alkali-feldspar dissolution and secondary mineral formation in an initially acidic fluid (pH = 3.1) at 200 °C and 300 bars. Temporal evolution of fluid chemistry was monitored by major element analysis of in situ fluid samples. Solid reaction products were retrieved from two identical experiments terminated after 5 and 78 days. Scanning electron microscopy revealed dissolution features and significant secondary mineral coverage on feldspar surfaces. Boehmite and kaolinite were identified as secondary minerals by X-ray diffraction and transmission electron microscopy. X-ray photoelectron spectroscopy analysis of alkali-feldspar surfaces before and after reaction showed a trend of increasing Al/Si ratios and decreasing K/Al ratios with reaction progress, consistent with the formation of boehmite and kaolinite.Saturation indices of feldspars and secondary minerals suggest that albite dissolution occurred throughout the experiments, while K-feldspar exceeded saturation after 216 h of reaction. Reactions proceeded slowly and full equilibrium was not achieved, the relatively high temperature of the experiments notwithstanding. Thus, time series observations indicate continuous supersaturation with respect to boehmite and kaolinite, although the extent of this decreased with reaction progress as the driving force for albite dissolution decreased. The first experimental evidence of metastable co-existence of boehmite, kaolinite and alkali feldspar in the feldspar hydrolysis system is consistent with theoretical models of mineral dissolution/precipitation kinetics where the ratio of the secondary mineral precipitation rate constant to the rate constant of feldspar dissolution is well below unity. This has important implications for modeling the time-dependent evolution of feldspar dissolution and secondary mineral formation in natural systems.  相似文献   

Late Holocene Asian monsoon variations recorded in Lake Rara sediment,western Nepal     

Atsunori Nakamura  Yusuke Yokoyama  Hideaki Maemoku  Hiroshi Yagi  Makoto Okamura  Hiromi Matsuoka  Nao Miyake  Toshiki Osada  Hirofumi Teramura  Danda Pani Adhikari  Vishnu Dangol  Yosuke Miyairi  Stephen Obrochta  Hiroyuki Matsuzaki 《第四纪科学杂志》2012,27(2):125-128

The Himalayas are a key location for understanding centennial‐ to millennial‐scale variations in the Asian monsoon, yet few studies of the late Holocene have been conducted in this sensitive area. Direct evidence for shifts in monsoonal wind strength is often limited to marine proxy records, while terrestrial reconstructions (e.g. lake levels and spleothems) focus on precipitation. Here, we present the first evidence of terrestrial summer monsoon wind strength changes from Lake Rara, western Nepal, based on Mn/Ti ratios, a proxy for lake stratification. These data indicate a link between the Arabian Sea and the Himalayas, suggesting that centennial‐ to millennial‐scale changes in wind strength occurred synchronously. Distinct similarity is also observed between Lake Rara and the southern part of China, which may support previous suggestions that the southern part of China is influenced by Indian summer monsoon. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Vertical segregation and population structure of ontogenetically migrating copepods Neocalanus cristatus,N. flemingeri,N. plumchrus,and Eucalanus bungii during the ice-free season in the Sea of Okhotsk     

Atsushi Tsuda  Hiroaki Saito  Hiromi Kasai  Jun Nishioka  Takeshi Nakatsuka 《Journal of Oceanography》2015,71(3):271-285

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Lead coprecipitation with iron oxyhydroxide nano-particles   总被引：1，自引：0，他引：1  

Peng Lu  Noel T. Nuhfer  Qin Li  Hiromi Konishi  Erika Elswick  Chen Zhu 《Geochimica et cosmochimica acta》2011,75(16):4547-4561

Pb²⁺ and Fe³⁺ coprecipitation was studied with sorption edge measurements, desorption experiments, sorbent aging, High Resolution Transmission and Analytical Electron Microscopy (HR TEM-AEM), and geochemical modeling. Companion adsorption experiments were also conducted for comparison. The macroscopic chemical and near atomic scale HRTEM data supplemented our molecule scale analysis with EXAFS (Kelly et al., 2008). Coprecipitation of Pb²⁺ with ferric oxyhydroxides occurred at ∼pH 4 and is more efficient than adsorption in removing Pb²⁺ from aqueous solutions at similar sorbate/sorbent ratios and pH. X-ray Diffraction (XRD) shows peaks of lepidocrocite and two additional broad peaks similar to fine particles of 2-line ferrihydrite (2LFh). HRTEM of the Pb-Fe coprecipitates shows a mixture of 2-6 nm diameter spheres and 8-20 by 200-300 nm needles, both uniformly distributed with Pb²⁺. Geochemical modeling shows that surface complexation models fit the experimental data of low Pb:Fe ratios when a high site density is used. Desorption experiments show that more Pb²⁺ was released from loaded sorbents collected from adsorption experiments than from Pb to Fe coprecipitates at dilute EDTA concentrations. Desorbed Pb²⁺ versus dissolved Fe³⁺ data show a linear relationship for coprecipitation (CPT) desorption experiments but a parabolic relationship for adsorption (ADS) experiments.Based on these results, we hypothesize that Pb²⁺ was first adsorbed onto the nanometer-sized, metastable, iron oxyhydroxide polymers of 2LFh with domain size of 2-3 nm. As these nano-particles assembled into larger particles, some Pb²⁺ was trapped in the iron oxyhydroxide structure and re-arranged to form solid solutions. Therefore, the CPT contact method produced more efficient removal of Pb²⁺ than the adsorption contact method, and Pb²⁺ bound in CPT solids represent a more stable sequestration of Pb²⁺ in the environment than Pb²⁺ adsorbed on iron oxyhydroxide surfaces.  相似文献   

Effects of ocean particles on the upwelling radiance and polarized radiance in the atmosphere-ocean system     

Chong Shi  Pucai Wang  Teruyuki Nakajima  Yoshifumi Ota  Saichun Tan  Guangyu Shi 《大气科学进展》2015,32(9):1186-1196

Based on a vector radiative transfer model of the atmosphere-ocean system, the influence of oceanic components on radiation processes, including polarization effects, was investigated in the wavelength region ranging from 0.380 to 0.865 μm. The components considered were phytoplankton, inorganic suspended material (sediment), and colored, dissolved organic matter. Due to their important roles in oceanic radiation processes, the sensitivity of the bidirectional reflectance to the rough ocean surface, represented by the wind velocity 10 m above the ocean surface, and aerosol, were taken into account. The results demonstrated that both radiance and polarized radiance just below the ocean surface were sensitive to the change of the concentrations of the considered components, while the dependence of polarized radiance on the observation geometry was more sensitive than radiance. Significant differences in the specular plane existed between the impacts of the phytoplankton and sediment on the degree of polarization just above the ocean surface at 670 nm. At the top of the atmosphere (TOA), polarization was relatively insensitive to changing concentrations of ocean particles at longer wavelengths. Furthermore, the radiance at the TOA in the solar plane was more sensitive to the aerosol optical thickness than wind velocity. In contrast, wind velocity strongly influenced the radiance at the TOA in the sun glint region, while the polarization degree showed less dependence in that region. Finally, a nonlinear optimal inversion method was proposed to simultaneously retrieve the aerosol and wind velocity using radiance measurement.  相似文献   

Geology of the Kokchetav UHP-HP metamorphic belt, Northern Kazakhstan     

Y. Kaneko  S. Maruyama  M. Terabayashi  H. Yamamoto  M. Ishikawa  R. Anma  †  C. D. Parkinson  T. Ota  Y. Nakajima  I. Katayama  J. Yamamoto and  K. Yamauchi 《Island Arc》2000,9(3):264-283

Abstract Ultrahigh-pressure metamorphic (UHPM) rocks of the Kokchetav Massif of Kazakhstan contain metamorphic microdiamond and coesite inclusions inside rigid capsules such as garnet and zircon. Precambrian protoliths of the UHPM rocks were metamorphosed at around 530 Ma, at pressures of about 7 GPa, which suggests that crustal protoliths were subducted to depths of over 200 km. Primary UHPM minerals are poorly preserved due to partial obliteration by subsequent Barrovian overprint during exhumation and later collision events in Caledonian times. We report the results of detailed mapping of the Kokchetav Massif and use structural data to propose intrusion and exhumation mechanisms for the UHPM rocks. Detailed mapping revealed that many subvertical structures in the ultrahigh-pressure–high-pressure (UHP–HP) units were formed due to later folding. The primary structure appears to be subhorizontal and the total thickness of the UHP rocks is estimated at around 2 km. The first order structure is sandwich-like; that is, the UHP–HP units are separated from underlying low-P metamorphic rocks of the Daulet Series and from feebly metamorphosed to unmetamorphosed sedimentary strata on the top by subhorizontal faults. Kinematic indicators show top-to-the-south sense of shear along the top, and top-to-the-north displacement along the bottom boundaries. These shear senses, together with the observed metamorphic gradients, suggest that the thin UHPM sheet was extruded toward the north. We consider wedge extrusion to have been the most effective mechanism for the exhumation of the UHPM rocks.  相似文献   

Seismic Hazard of Honduras     

Cáceres  Diego  Kulhánek  Ota 《Natural Hazards》2000,22(1):49-69

In this paper we have described the proceduresused, input data applied and results achieved in ourefforts to develop seismic hazard maps of Honduras.The probabilistic methodology of Cornell is employed.Numerical calculations were carried out by making useof the computer code SEISRISK III. To examine theimpact of uncertainties in seismic and structuralcharacteristics, the logic tree formalism has beenused. We compiled a de-clustered earthquake cataloguefor the region comprising 1919 earthquakes occurringduring the period from 1963 to 1997. Unified momentmagnitudes were introduced. Definition of aseismotectonic model of the whole region under review,based on geologic, tectonic and seismic information,led to the definition of seven seismogenetic zones forwhich seismic characteristics were determined. Fourdifferent attenuation models were considered. Resultsare expressed in a series of maps of expected PGA for60% and 90% probabilities of nonexceedence in a50-year interval which corresponds to return periodsof 100 and 475 years, respectively. The highest PGAvalues of about 0.4g (90% probability ofnon-exceedence) are expected along the borders withGuatemala and El Salvador.  相似文献   

Book review     

Ota Kulhanek 《Geophysical Journal International》1991,106(1):301-302

Book Reviewed in this Article:
Observatory seismology Ed. Litehiser, J. J., University of California Press, 1990, x + 379 pp, ISBN 0520 065824, US$ 48.  相似文献   

Role of end-use technologies in long-term GHG reduction scenarios developed with the BET model     

Hiromi Yamamoto  Masahiro Sugiyama  Junichi Tsutsui 《Climatic change》2014,123(3-4):583-596

In this study, we develop a new integrated assessment model called the BET model (Basic Energy systems, Economy, Environment, and End-use Technology Model). It is a multi-regional, global model based on Ramsey’s optimal growth theory and includes not only traditional end-use technologies but also advanced end-use technologies such as heat-pump water heaters and electric vehicles. Using the BET model, we conduct simulations and obtain the following results. (1) Advanced end-use technologies have an important role in containing carbon prices as well as GDP losses when GHG (greenhouse gas) constraints are stringent. (2) Electrification based on energy services progresses rapidly in scenarios with stringent GHG constraints. This is because electricity can be supplied by various methods of non-fossil power generation, and advanced end-use technologies can drastically improve energy-to-service efficiencies. The BET’s results indicate the importance of analyses that systematically combine environmental constraints, end-use technologies, supply energy technologies, and economic development.  相似文献