Late Quaternary faulting along the western margin of the Poronaysk Lowland in central Sakhalin, Russia     

Hiroyuki Tsutsumi  Yasuhiro Suzuki  Andrei I. Kozhurin  Mihail I. Strel'tsov  Takeyuki Ueki  Hideaki Goto  Koji Okumura  Rustam F. Bulgakov  Hiroyuki Kitagawa 《Tectonophysics》2005,407(3-4):257-268

Sakhalin Island straddles an active plate boundary between the Okhotsk and Eurasian plates. South of Sakhalin, this plate boundary is illuminated by a series of M_w 7–8 earthquakes along the eastern margin of the Sea of Japan. Although this plate boundary is considered to extend onshore along the length of Sakhalin, the location and convergence rate of the plate boundary had been poorly constrained. We mapped north-trending active faults along the western margin of the Poronaysk Lowland in central Sakhalin based on aerial photograph interpretation and field observations. The active faults are located east of and parallel to the Tym–Poronaysk fault, a terrane boundary between Upper Cretaceous and Neogene strata; the active faults appear to have reactivated the terrane boundary at depth in Quaternary time. The total length of the active fault zone on land is about 140 km. Tectonic geomorphic features such as east-facing monoclinal and fault scarps, back-tilted fluvial terraces, and numerous secondary faults suggest that the faults are west-dipping reverse faults. Assuming the most widely developed geomorphic surface in the study area formed during the last glacial maximum at about 20 ka based on similarities of geomorphic features with those in Hokkaido Island, we obtain a vertical component of slip rate of 0.9–1.4 mm/year. Using the fault dip of 30–60°W observed at an outcrop and trench walls, a net slip rate of 1.0–2.8 mm/year is obtained. The upper bound of the estimate is close to a convergence rate across the Tym–Poronaysk fault based on GPS measurements. A trenching study across the fault zone dated the most recent faulting event at 3500–4000 years ago. The net slip associated with this event is estimated at about 4.5 m. Since the last faulting event, a minimum of 3.5 m of strain, close to the strain released during the last event, has accumulated along the central portion of the active strand of the Tym–Poronaysk fault.  相似文献   

Source process of a long-period event at Kilauea volcano, Hawaii   总被引：1，自引：0，他引：1  

Hiroyuki Kumagai  Bernard A. Chouet  Phillip B. Dawson 《Geophysical Journal International》2005,161(1):243-254

  相似文献   

2,3-Dimethylbiphenyl: Kinetics of its cyclisation reaction and effects of maturation upon its relative concentration in sediments     

Robert Alexander  Steven James Fisher  Robert Ian Kagi 《Organic Geochemistry》1988,13(4-6)

The rate constants of the cyclisation reaction of 2,3-dimethylbiphenyl to give 1-methylfluorene under non-catalytic conditions have been obtained at five temperatures between 460 and 500°C. The activation energy, activation entropy and frequency factor for the reaction have been determined from the experimental data. These kinetic parameters were then used to calculate the temperature ranges where the reaction occurs under natural conditions in sedimentary sequences which have experienced different heating rates. The coincidence of the measured and calculated values has been taken as evidence that the cyclisation reaction occurs in sediments under non-catalytic conditions.  相似文献   

Calculation of Surface Waves For A Thin Basin Structure Using A Direct Boundary Element Method With Normal Modes   总被引：1，自引：0，他引：1  

Hiroyuki Fujiwara  Hiroshi Takenaka 《Geophysical Journal International》1994,117(1):69-91

  相似文献   

Heating rate effects on aromatic maturity indicators     

R. Alexander  M.G. Strachan  R.I. Kagi  W. Van Bronswijk 《Organic Geochemistry》1986,10(4-6)

Aromatic maturity indicators based upon dimethylnaphthalenes, trimethylnaphthalenes and methylphenanthrenes have been determined for two sedimentary sequences from northwest Western Australia. The rate of change of these indicators with depth has been modelled using a kinetic expression which accounts for the effects of continuously varying time and temperature. Activation energies and entropies of activation have been measured. Maturity indicators with similar and with very different kinetic parameters have been used to construct plots to illustrate their behaviours under a variety of thermal regimes. Maturity indicators with similar activation energies behave almost identically over a wide range of heating rates while those with substantial differences display more diverse behaviour. The former may be used to relate kerogen-based maturity indicators with those determined from crude oils, whereas the latter can provide information about the maximum palaeotemperatures and heating rates of sedimentary hydrocarbons. It was also observed that the kinetic parameters for particular aromatic maturity indicators differed between the two sedimentary sequences, suggesting that source and mineral matrix effects can influence their behaviour.  相似文献   

Acid catalysis of alkyl hydrogen exchange and configurational isomerisation reactions: acyclic isoprenoid acids     

Alfons V. Larcher  Robert Alexander  Steven J. Rowland  Robert I. Kagi 《Organic Geochemistry》1986,10(4-6)

Acid-catalysed alkyl hydrogen exchange and configurational isomerisation has been studied in a series of acyclic isoprenoid acids when they were heated at 160°C in the presence of a montmorillonite. Hydrogen exchange occurred between the adsorbed water of the clay surface and the a position of the isoprenoid acids. In cases where this position was chiral, exchange was accompanied by configurational isomerisation. Configurational isomerisation occurred more slowly in experiments conducted without a clay matrix in the presence of water. These results have been rationalized in terms of a reaction mechanism involving protonation of the carbonyl oxygen causing enolization and consequent hydrogen exchange at the a position of the acids. This mechanism was used to account for the relatively fast rate of isomerisation of C-2 chiral centres in sedimentary acyclic isoprenoid acids during maturation.  相似文献   

Identification of some diterpenoid hydrocarbons in petroleum     

Rohinton A. Noble  Robert Alexander  Robert Ian Kagi  John K. Nox 《Organic Geochemistry》1986,10(4-6)

19-Norisopimarane and isopimarane have been synthesized from isopimara-9(11), 15-diene-3β, 19-diol. Analysis of the alkane fractions of an Australian crude oil by GC-MS showed the presence of nine diterpenoid hydrocarbons (diterpanes), of which one was bicyclic two were tricyclic and six were tetracyclic.19-Norisopimarane and isopimarane were identified by comparison of their mass spectra and GC retention times with those of the synthetic standards. ent-Beyerane, 16a(H)-phyllocladane, 16)β(H)-phyllocladane, ent-16α(H)-kaurane and labdane were also identified by comparison with authentic reference compounds. The remaining two compounds were tentatively identified as rimuane and as a 17-nortetracyclic diterpane on the basis of mass spectral evidence. The diterpanes are probably derived from conifer resins.  相似文献   

Diurnal variations of the planetary boundary layer observed with anL-band clear-air doppler radar     

Hiroyuki Hashiguchi  Manabu D. Yamanaka  Toshitaka Tsuda  Mamoru Yamamoto  Takuji Nakamura  Tatsuhiro Adachi  Shoichiro Fukao  Toru Sato  Daniel L. Tobing 《Boundary-Layer Meteorology》1995,74(4):419-424

Based on continuous observations of the planetary boundary layer (PBL) with anL-band (1357.5 MHz) boundary-layer radar (BLR) at a hilly location in Japan, we have discovered that on clear days, a thin enhanced echo layer corresponding to the top of the PBL (or mixed layer) appeared at about 500 m height in the morning and ascended to about 1500 m in the afternoon. Strong upward velocities were observed below the echo layer (or inside the PBL), reaching 1500 m in the afternoon.  相似文献   

Sedimentary humic acid and fulvic acid as surface active substances     

Kohji Hayase  Hiroyuki Tsubota 《Geochimica et cosmochimica acta》1983,47(5):947-952

Surface tension of sedimentary fulvic acid (FA) and humic acid (HA) with molecular weight from < 10,000 to > 300,000 was measured at 5°C and 25°C, over a wide range of concentrations (0.114-107.4 g/l) at pH 8. HA was in the form of sodium humate. Surface tension decreases with an increase in HA and FA concentration and both HA and FA were found to be surface active materials with FA exhibiting the lowest surface tension (31 dynes/cm).Plots of surface tension vs. log concentration gave two straight lines with a break at a certain concentration similar to surfactants. From the concentration at the break point, aggregation concentration (AGC) was determined. For HA with molecular weight above 10,000, the AGC decreased with an increase in molecular weight. The more hydrophobic the HA, the greater was the tendency to form aggregates. Surface excess (surface concentration) was determined (2.3 × 10^?10?5.5 × 10^?10mol/cn²) from the slope of the plot of surface tension vs. log concentration for concentrations lower than the AGC. Adsorption of HA into the surface layer increased with increasing molecular weight of HA.  相似文献   

Ambient air measurements of six bifunctional carbonyls in a suburban area     

Ricardo Ortiz  Hiroyuki Hagino  Kazuhiko Sekiguchi  Qingyue Wang  Kazuhiko Sakamoto   《Atmospheric Research》2006,82(3-4):709

Low-molecular-weight carbonyl compounds, generated by photochemical reactions in the atmosphere and found in the exhaust of motor vehicles, have recently come to the attention of researchers because some of them are suspected carcinogens or mutagens. Six bifunctional carbonyl compounds were detected and measured in a suburban site 30 km northwest of the Tokyo metropolitan area. Samples were taken on five sunny days between 2 August and 11 August 2003 with a low-volume denuder and three-filter tandem system using O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBHA) as a sorbent. Bifunctional carbonyls were measured by gas chromatography–mass spectrometry after two derivatization processes with PFBHA and N,O-bis(trimethylsilyl)-trifluoroacetamide (BSTFA). The average total (gas plus particle) concentrations were 162.8 ng m^− 3 for pyruvic acid, 113.7 ng m^− 3 for methylglyoxal, 36.0 ng m^− 3 for glycolaldehyde and 58.6 ng m^− 3 for glyoxal.  相似文献