Diurnal variations of the planetary boundary layer observed with anL-band clear-air doppler radar     

Hiroyuki Hashiguchi  Manabu D. Yamanaka  Toshitaka Tsuda  Mamoru Yamamoto  Takuji Nakamura  Tatsuhiro Adachi  Shoichiro Fukao  Toru Sato  Daniel L. Tobing 《Boundary-Layer Meteorology》1995,74(4):419-424

Based on continuous observations of the planetary boundary layer (PBL) with anL-band (1357.5 MHz) boundary-layer radar (BLR) at a hilly location in Japan, we have discovered that on clear days, a thin enhanced echo layer corresponding to the top of the PBL (or mixed layer) appeared at about 500 m height in the morning and ascended to about 1500 m in the afternoon. Strong upward velocities were observed below the echo layer (or inside the PBL), reaching 1500 m in the afternoon.  相似文献   

Sedimentary humic acid and fulvic acid as surface active substances     

Kohji Hayase  Hiroyuki Tsubota 《Geochimica et cosmochimica acta》1983,47(5):947-952

Surface tension of sedimentary fulvic acid (FA) and humic acid (HA) with molecular weight from < 10,000 to > 300,000 was measured at 5°C and 25°C, over a wide range of concentrations (0.114-107.4 g/l) at pH 8. HA was in the form of sodium humate. Surface tension decreases with an increase in HA and FA concentration and both HA and FA were found to be surface active materials with FA exhibiting the lowest surface tension (31 dynes/cm).Plots of surface tension vs. log concentration gave two straight lines with a break at a certain concentration similar to surfactants. From the concentration at the break point, aggregation concentration (AGC) was determined. For HA with molecular weight above 10,000, the AGC decreased with an increase in molecular weight. The more hydrophobic the HA, the greater was the tendency to form aggregates. Surface excess (surface concentration) was determined (2.3 × 10^?10?5.5 × 10^?10mol/cn²) from the slope of the plot of surface tension vs. log concentration for concentrations lower than the AGC. Adsorption of HA into the surface layer increased with increasing molecular weight of HA.  相似文献   

Ambient air measurements of six bifunctional carbonyls in a suburban area     

Ricardo Ortiz  Hiroyuki Hagino  Kazuhiko Sekiguchi  Qingyue Wang  Kazuhiko Sakamoto   《Atmospheric Research》2006,82(3-4):709

Low-molecular-weight carbonyl compounds, generated by photochemical reactions in the atmosphere and found in the exhaust of motor vehicles, have recently come to the attention of researchers because some of them are suspected carcinogens or mutagens. Six bifunctional carbonyl compounds were detected and measured in a suburban site 30 km northwest of the Tokyo metropolitan area. Samples were taken on five sunny days between 2 August and 11 August 2003 with a low-volume denuder and three-filter tandem system using O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBHA) as a sorbent. Bifunctional carbonyls were measured by gas chromatography–mass spectrometry after two derivatization processes with PFBHA and N,O-bis(trimethylsilyl)-trifluoroacetamide (BSTFA). The average total (gas plus particle) concentrations were 162.8 ng m^− 3 for pyruvic acid, 113.7 ng m^− 3 for methylglyoxal, 36.0 ng m^− 3 for glycolaldehyde and 58.6 ng m^− 3 for glyoxal.  相似文献   

Dynamic source inversion based on stable formulation and on identification of the resolution level via a multiscale approach     

Hiroyuki Goto  Sumio Sawada 《Geophysical Journal International》2006,167(2):779-793

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Monitoring Quiescent Volcanoes by Diffuse CO2 Degassing: Case Study of Mt. Fuji, Japan     

Kenji Notsu  Toshiya Mori  Sandie Chanchah Do Vale  Hiroyuki Kagi  Takamori Ito 《Pure and Applied Geophysics》2006,163(4):825-835

Since the 8th century, more than seventeen eruptions have been recorded for the Mt. Fuji volcano, with the most recent eruption occurring in 1707 (Hoei eruption). For the past 300 years the volcano has been in a quiescent stage and, since the early 1960s, has exhibited neither fumarolic nor thermal activity. However, the number of low-frequency earthquakes with a hypocentral depth of 10–20 km increased significantly beneath the northeastern flank of Mt. Fuji in 2000–2001, suggesting a possible resumption of magmatic activity. In this study, diffuse CO₂ efflux and thermal surveys were carried out in four areas of the volcano in 2001–2002 in order to detect possible signs of the upward movement of deep magma. At all survey points, the CO₂ efflux was below the detection limit with the exception of a few points with biological CO₂ emission, and ground temperatures at a depth of 20–30 cm were below ambient, indicating no surface manifestations of gas or heat emission. Should magma rise into the subsurface, the diffuse CO₂ efflux would be expected to increase, particularly along the tectonically weakened lineation on the Mt. Fuji volcano, allowing for the early detection of pre-eruptive degassing.  相似文献   

Estimation of episodic exfoliation rates of rock sheets on a granite dome in Korea from cosmogenic nuclide analysis   总被引：1，自引：0，他引：1  

Sachi Wakasa  Hiroyuki Matsuzaki  Yukiya Tanaka  Yukinori Matsukura 《地球表面变化过程与地形》2006,31(10):1246-1256

We have measured concentrations of cosmogenic ¹⁰Be and ²⁶Al produced in situ at bare bedrock surfaces of successive sheets developing on a granite dome in Korea and calculated the exfoliation rate of sheeting joints. The exfoliation rate was obtained using a simple model in which the sheeting joints experience intermittent denudation, i.e. peeling off along the bedrock face. We find that the average exfoliation (erosion) rate of the episodic peeling‐off process is 5·6 cm/ka^?1. The analysis is useful for understanding the evolution of granite sheeting structures on this dome in Korea. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Intergranular trace elements in mantle xenoliths from Russian Far East: Example for mantle metasomatism by hydrous melt     

Junji  Yamamoto  Shun'ichi  Nakai  Koshi  Nishimura  Ichiro  Kaneoka  Hiroyuki  Kagi  Keiko  Sato  Tasuku  Okumura  Vladimir S.  Prikhod'ko  Shoji  Arai 《Island Arc》2009,18(1):225-241

Based on both major and trace element chemistry, the occurrence of the intergranular component in mantle-derived xenoliths from far eastern Russia has been constrained. Whole-rock trace element measurements of one xenolith show apparent negative anomalies in Ce, Th, and high field strength elements on normalized trace element patterns. The trace element pattern of the whole rock differs from those of constituent minerals, indicating that the anomalies in the whole rock are attributable to the presence of an intergranular component. That assumption was confirmed using in situ analysis of trace elements in the intergranular substance and melt inclusion using laser ablation inductively coupled plasma–mass spectrometry. Both the intergranular component and the melt inclusions have identical trace element patterns, which mean that these materials are a cognate metasomatizing agent. The anomalies are regarded as mantle metasomatism related to an aqueous fluid. Hydrous minerals were observed on the wall of the melt inclusions using micro-Raman spectroscopy, indicating that the melt inclusions contained a large amount of water. Thus, this study reveals a trace element composition of a hydrous metasomatizing agent in the mantle.  相似文献   

Natural and experimental structural evolution of dispersed organic matter in mudstones: The Shimanto accretionary complex,southwest Japan     

Yoshihiro Nakamura  Hidetoshi Hara  Hiroyuki Kagi 《Island Arc》2019,28(5)

Structural changes induced by thermal maturation of dispersed organic matter (OM) in the Shimanto accretionary complex, southwest Japan, were investigated using micro‐Fourier‐transform infrared spectroscopy and micro‐Raman spectroscopy. Natural dispersed OM exhibits systematic structural changes inferred from D1‐ and G‐band FWHM values, Raman band separation (RBS), and intensity ratios of the D1‐ and G‐bands (I_D1/I_G ratio) from diagenetic zone to anchizone (IC values: 0.75–0.30). Infrared spectra indicate a loss of aliphatic CH _x, aromatic CH _x, and oxygen‐containing structures as temperature increases. These changes are consistent with discontinuities in thermal structures bounded by out‐of‐sequence thrusts. Kinetic pyrolysis experiments indicate that the I_D1/I_G ratio of synthesized OM has a power law relationship with heat treatment time. Kinetic models of temperature dependence were fitted using the I_D1/I_G ratio, and an effective activation energy of 106 ±17 kJ/mol was estimated using an Arrhenius equation. The activation energies estimated by power law rate and Avrami models have a least‐square correlation coefficient of 0.93, indicating the temperature dependence of carbonization. The estimated effective activation energy is consistent with that of coal, lignin, cellulose, and hemicellulose during thermal degradation. On the other hand, RBS, and D1‐ and G‐band FWHM values of OM display more complex changes with increasing heating temperature and time, and it is difficult to constrain rate parameters during pyrolysis experiments. Our data indicate that the I_D1/I_G ratio is controlled by a simple thermally activated process, whereas RBS and D1‐ and G‐band FWHM values can be affected by lithostatic pressure, fluid activity, hydrogen index, and host lithology, as well as temperature. Structural evolution of dispersed OM in mudstones differs between natural and anhydrous closed experimental systems. Natural carbonization based on micro‐Raman spectroscopy should be applied for a limited indicator of thermal maturation, especially for dispersed OM in diagenetic zone.  相似文献   

The XUV Doppler Telescope (XDT)     

Sakao  T.  Tsuneta  S.  Hara  H.  Shimizu  T.  Kano  R.  Kumagai  K.  Yoshida  T.  Nagata  S.  Kobayashi  K. 《Solar physics》1999,187(2):303-333

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A method for extending a general constitutive model to consider the electro-chemo-mechanical phenomena of mineral crystals in expansive soils     

Hiroyuki Kyokawa  Shintaro Ohno  Ichizou Kobayashi 《国际地质力学数值与分析法杂志》2020,44(6):749-771

The mechanical behavior of expansive soils varies according to the chemical composition of the pore fluid. It is well known that electrochemical phenomena on the surface of clay mineral crystals considerably affect their macrostructural behavior. In particular, a change in the pore fluid composition causes osmotic consolidation or swelling. In this study, a model is constructed to describe the characteristic behavior of expansive soils by coupling the interlaminar behavior of clay mineral crystals and the soil skeleton behavior. The interlaminar behavior is derived from the electro-chemo-mechanical coupling equilibrium of mineral crystals, and the soil skeleton behavior is given by a general elastoplastic constitutive model for soils. This modeling approach extends a general model to consider the electro-chemo-mechanical phenomena of mineral crystals. Oedometer tests with the replacement of the cell fluid and the swelling pressure and deformation tests on expansive clays are simulated with the proposed model. The simulation results indicate that the proposed method can reasonably represent the typical behavior of expansive soils.  相似文献