The effect of TiO2 and Fe2O3 on metapelitic assemblages at greenschist and amphibolite facies conditions: mineral equilibria calculations in the system K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–Fe2O3     

White  Powell  Holland  Worley 《Journal of Metamorphic Geology》2000,18(5):497-511

Mineral equilibria calculations in the system K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–Fe₂O₃ (KFMASHTO) using thermocalc and its internally consistent thermodynamic dataset constrain the effect of TiO₂ and Fe₂O₃ on greenschist and amphibolite facies mineral equilibria in metapelites. The end‐member data and activity–composition relationships for biotite and chloritoid, calibrated with natural rock data, and activity–composition data for garnet, calibrated using experimental data, provide new constraints on the effects of TiO₂ and Fe₂O₃ on the stability of these minerals. Thermodynamic models for ilmenite–hematite and magnetite–ulvospinel solid solutions accounting for order–disorder in these phases allow the distribution of TiO₂ and Fe₂O₃ between oxide minerals and silicate minerals to be calculated. The calculations indicate that small to moderate amounts of TiO₂ and Fe₂O₃ in typical metapelitic bulk compositions have little effect on silicate mineral equilibria in metapelites at greenschist to amphibolite facies, compared with those calculated in KFMASH. The addition of large amounts of TiO₂ to typical pelitic bulk compositions has little effect on the stability of silicate assemblages; in contrast, rocks rich in Fe₂O₃ develop a markedly different metamorphic succession from that of common Barrovian sequences. In particular, Fe₂O₃‐rich metapelites show a marked reduction in the stability fields of staurolite and garnet to higher pressures, in comparison to those predicted by KFMASH grids.  相似文献   

The debris disc around τ Ceti: a massive analogue to the Kuiper Belt     

J. S. Greaves  M. C. Wyatt  W. S. Holland  W. R. F. Dent 《Monthly notices of the Royal Astronomical Society》2004,351(3):L54-L58

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Calculated phase equilibria in K₂O-FeO-MgO-Al₂O₃-SiO₂-H₂O for sapphirine-quartz-bearing mineral assemblages     

D. E. Kelsey  R. W. White  T. J. B. Holland  R. Powell 《Journal of Metamorphic Geology》2004,22(6):559-578

Sapphirine, coexisting with quartz, is an indicator mineral for ultrahigh‐temperature metamorphism in aluminous rock compositions. Here a new activity‐composition model for sapphirine is combined with the internally consistent thermodynamic dataset used by THERMOCALC, for calculations primarily in K₂O‐FeO‐MgO‐Al₂O₃‐SiO₂‐H₂O (KFMASH). A discrepancy between published experimentally derived FMAS grids and our calculations is understood with reference to H₂O. Published FMAS grids effectively represent constant a_H2O sections, thereby limiting their detailed use for the interpretation of mineral reaction textures in compositions with differing H₂O. For the calculated KFMASH univariant reaction grid, sapphirine + quartz assemblages occur at P–T in excess of 6–7 kbar and 1005 °C. Sapphirine compositions and composition ranges are consistent with natural examples. However, as many univariant equilibria are typically not ‘seen’ by a specific bulk composition, the univariant reaction grid may reveal little about the detailed topology of multi‐variant equilibria, and therefore is of limited use for interpreting the P–T evolution of mineral assemblages and reaction sequences. Calculated pseudosections, which quantify bulk composition and multi‐variant equilibria, predict experimentally determined KFMASH mineral assemblages with consistent topology, and also indicate that sapphirine stabilizes at increasingly higher pressure and temperature as X_Mg increases. Although coexisting sapphirine and quartz can occur in relatively iron‐rich rocks if the bulk chemistry is sufficiently aluminous, the P–T window of stability shrinks with decreasing X_Mg. An array of mineral assemblages and mineral reaction sequences from natural sapphirine + quartz and other rocks from Enderby Land, Antarctica, are reproducible with calculated pseudosections. That consistent phase diagram calculations involving sapphirine can be performed allows for a more thorough assessment of the metamorphic evolution of high‐temperature granulite facies terranes than was previously possible. The establishment of a a‐x model for sapphirine provides the basis for expansion to larger, more geologically realistic chemical systems (e.g. involving Fe³⁺).  相似文献   

Evaluation of geologic and geomorphologic influences on borehole productivity in crystalline bedrock aquifers of Limpopo Province, South Africa     

Martin Holland  Kai T. Witth��ser 《Hydrogeology Journal》2011,19(5):1065-1083

Geologically complex crystalline aquifers underlie large parts of the semi-arid Limpopo Province where some of the greatest groundwater needs in South Africa occur. It is important to identify potentially high-yielding zones that can be targeted for water supply. The study covered four distinct geologic and morpho-structural domains within Limpopo Province, together covering about 23,500?km². Results from over 2,500 pumping test analyses indicate that bedrock type (e.g. pegmatite), lithological setting (e.g. aureole of granitoids), proximity and orientation of dykes and lineaments, topographic setting (e.g. slopes or valleys) and proximity of surface-water drainages may exert an influence on borehole productivity. No correlation between borehole productivity and weathering depth was found. Lineaments and dykes striking perpendicular to the current maximum horizontal stress seem to be more favourable targets, which is inconsistent with the predicted regime. Due to the complex geologic history, it is difficult to link open discontinuities to a distinct recent or past tectonic event. Regional stress-field data, as in this case, may not account for local, possibly highly significant, stress-field variations. The hydrogeologic importance of several factors related to groundwater occurrence, here presented, can be used as a working reference for future groundwater development programmes.  相似文献   

Discussion of the article by A. C. Lasaga and H. Ohmoto on “The Oxygen Geochemical Cycle: Dynamics and Stability,” Geochim. Cosmochim. Acta66, 361-381, 2002     

Heinrich D. Holland 《Geochimica et cosmochimica acta》2003,67(4):787-789

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Measurement of the Sunyaev–Zel'dovich increment in massive galaxy clusters     

Michael Zemcov  Mark Halpern  Colin Borys  Scott Chapman  Wayne Holland  Elena Pierpaoli  Douglas Scott 《Monthly notices of the Royal Astronomical Society》2003,346(4):1179-1188

We have detected the Sunyaev–Zel'dovich (SZ) increment at 850 μm in two galaxy clusters (Cl 0016+16 and MS 1054.4−0321) using the Submillimetre Common User Bolometer Array (SCUBA) on the James Clerk Maxwell Telescope. Fits to the isothermal β model yield a central Compton y parameter of  (2.2 ± 0.7) × 10⁻⁴  and a central 850-μm flux of  Δ I ₀= 2.2 ± 0.7 mJy beam⁻¹  in Cl 0016. This can be combined with decrement measurements to infer   y = (2.38 ±^0.36_0.34) × 10⁻⁴  and   v _pec= 400±¹⁹⁰⁰₁₄₀₀ km s⁻¹  . In MS 1054 we find a peak 850-μm flux of  Δ I ₀= 2.0 ± 1.0 mJy beam⁻¹  and   y = (2.0 ± 1.0) × 10⁻⁴  . To be successful such measurements require large chop throws and non-standard data analysis techniques. In particular, the 450-μm data are used to remove atmospheric variations in the 850-μm data. An explicit annular model is fit to the SCUBA difference data in order to extract the radial profile, and separately fit to the model differences to minimize the effect of correlations induced by our scanning strategy. We have demonstrated that with sufficient care, SCUBA can be used to measure the SZ increment in massive, compact galaxy clusters.  相似文献   

Surf zone characterization from Unmanned Aerial Vehicle imagery     

Rob A. Holman  K. Todd Holland  Dave M. Lalejini  Steven D. Spansel 《Ocean Dynamics》2011,61(11):1927-1935

We investigate the issues and methods for estimating nearshore bathymetry based on wave celerity measurements obtained using time series imagery from small unmanned aircraft systems (SUAS). In contrast to time series imagery from fixed cameras or from larger aircraft, SUAS data are usually short, gappy in time, and unsteady in aim in high frequency ways that are not reflected by the filtered navigation metadata. These issues were first investigated using fixed camera proxy data that have been intentionally degraded to mimic these problems. It has been found that records as short as 50 s or less can yield good bathymetry results. Gaps in records associated with inadvertent look-away during unsteady flight would normally prevent use of the required standard Fast Fourier Transform methods. However, we found that a full Fourier Transform could be implemented on the remaining valid record segments and was effective if at least 50% of total record length remained intact. Errors in image geo-navigation were stabilized based on fixed ground fiducials within a required land portion of the image. The elements of a future method that could remove this requirement were then outlined. Two test SUAS data runs were analyzed and compared to survey ground truth data. A 54-s data run at Eglin Air Force Base on the Gulf of Mexico yielded a good bathymetry product that compared well with survey data (standard deviation of 0.51 m in depths ranging from 0 to 4 m). A shorter (30.5 s) record from Silver Strand Beach (near Coronado) on the US west coast provided a good approximation of the surveyed bathymetry but was excessively deep offshore and had larger errors (1.19 m for true depths ranging from 0 to 6 m), consistent with the short record length. Seventy-three percent of the bathymetry estimates lay within 1 m of the truth for most of the nearshore.  相似文献   

Coping with climate variability and climate change in La Ceiba,Honduras     

Joel B. Smith  Kenneth M. Strzepek  Julio Cardini  Mario Castaneda  Julie Holland  Carlos Quiroz  Tom M. L. Wigley  Jose Herrero  Peter Hearne  John Furlow 《Climatic change》2011,108(3):457-470

La Ceiba, Honduras, a city of about 200,000 people, lies along the Caribbean Sea, nestled against a mountain range and the Rio Cangrejal. The city faces three flooding risks: routine flooding of city streets due to the lack of a stormwater drainage system; occasional major flooding of the Rio Cangrejal, which flows through the city; and flooding from heavy rainfall events and storm surges associated with tropical cyclones. In this study, we applied a method developed for the U.S. Agency for International Development and then worked with stakeholders in La Ceiba to understand climate change risks and evaluate adaptation alternatives. We estimated the impacts of climate change on the current flooding risks and on efforts to mitigate the flooding problems. The climate change scenarios, which addressed sea level rise and flooding, were based on the Intergovernmental Panel on Climate Change estimates of sea level rise (Houghton et al. 2001) and published literature linking changes in temperature to more intense precipitation (Trenberth et al., Bull Am Meteorol Soc, 84:1205–1217, 2003) and hurricanes (Knutson and Tuleya, J Clim, 17:3477–3495, 2004). Using information from Trenberth et al., Bull Am Meteorol Soc, 84:1205–1217, (2003) and Knutson and Tuleya, J Clim, 17:3477–3495, 2004, we scaled intense precipitation and hurricane wind speed based on projected temperature increases. We estimated the volume of precipitation in intense events to increase by 2 to 4% in 2025 and by 6 to 14% by 2050. A 13% increase in intense precipitation, the high scenario for 2050, could increase peak 5-year flood flows by about 60%. Building an enhanced urban drainage system that could cope with the estimated increased flooding would cost one-third more than building a system to handle current climate conditions, but would avoid costlier reconstruction in the future. The flow of the Rio Cangrejal would increase by one-third from more intense hurricanes. The costs of raising levees to protect the population from increased risks from climate change would be about $1 million. The coast west of downtown La Ceiba is the most vulnerable to sea level rise and storm surges. It is relatively undeveloped, but is projected to have rapid development. Setbacks on coastal construction in that area may limit risks. The downtown coastline is also at risk and may need to be protected with groins and sand pumping. Stakeholders in La Ceiba concluded that addressing problems of urban drainage should be a top priority. They emphasized improved management of the Rio Cangrejal watershed and improved storm warnings to cope with risks from extreme precipitation and cyclones. Adoption of risk management principles and effective land use management could also help reduce risks from current climate and climate change.  相似文献   

Kaolinite clayrocks in the Triassic Banks Wall sandstone of the western blue mountains,New South Wales     

F. C. Loughnan  R. Goldbery  W. N. Holland 《Australian Journal of Earth Sciences》2013,60(4):393-402

Fine‐grained and coarsely oolitic kaolinite clayrocks that closely resemble in composition, texture, and structure those of the Garie Formation in the southern part of the Sydney Basin are described from the Western Blue Mountains of New South Wales. The kaolinite clayrocks form part of a fine‐grained unit, here designated the Docker Head Claystone Member. It is concluded that the kaolinite clayrocks are the equivalent of the Garie Formation and represent fluviatile accumulations of detritus derived from the same highly weathered source rocks that gave rise to the Garie Formation.  相似文献   

Recent intense hurricane response to global climate change   总被引：1，自引：0，他引：1  

Greg Holland  Cindy L. Bruyère 《Climate Dynamics》2014,42(3-4):617-627

An Anthropogenic Climate Change Index (ACCI) is developed and used to investigate the potential global warming contribution to current tropical cyclone activity. The ACCI is defined as the difference between the means of ensembles of climate simulations with and without anthropogenic gases and aerosols. This index indicates that the bulk of the current anthropogenic warming has occurred in the past four decades, which enables improved confidence in assessing hurricane changes as it removes many of the data issues from previous eras. We find no anthropogenic signal in annual global tropical cyclone or hurricane frequencies. But a strong signal is found in proportions of both weaker and stronger hurricanes: the proportion of Category 4 and 5 hurricanes has increased at a rate of ~25–30 % per °C of global warming after accounting for analysis and observing system changes. This has been balanced by a similar decrease in Category 1 and 2 hurricane proportions, leading to development of a distinctly bimodal intensity distribution, with the secondary maximum at Category 4 hurricanes. This global signal is reproduced in all ocean basins. The observed increase in Category 4–5 hurricanes may not continue at the same rate with future global warming. The analysis suggests that following an initial climate increase in intense hurricane proportions a saturation level will be reached beyond which any further global warming will have little effect.  相似文献