The effect of Tschermak's substitution on assemblages in aluminous dolomites     

Judy Baker  T. J. B. Holland  Roger Powell 《Contributions to Mineralogy and Petrology》1994,118(1):48-59

A calculated petrogenetic grid for the system CaO-MgO-Al₂O₃-SiO₂-CO₂-H₂O (CaMASCH), incorporating Tschermak's substitutions in amphibole, chlorite, talc and clinopyroxene, is used to examine phase relationships in aluminous marbles. A series of diagrams illustrating the effect upon stable mineral assemblages of increasing the aluminium content of a bulk composition is used to show the way aluminous minerals enter mineral assemblages in progressively more aluminous rocks. The effects of changing pressure and the incorporation of Fe into the bulk composition on the stable mineral assemblages are also examined. The calculated equilibria are shown to be in reasonable agreement with natural assemblages, and the incorporation of new experimental data on amphiboles into the existing dataset is shown to improve the agreement between observed and natural amphibole compositions.  相似文献   

Long-term variation of macrobenthos in a mesohaline region of Chesapeake Bay     

A. F. Holland 《Estuaries and Coasts》1985,8(2):93-113

Macrobenthic species abundances and physical/chemical factors known of affect them were measured in a mesohaline region of the Chesapeake Bay from 1971 to 1982. Variation in species abundance due to station differences, seasonal patterns and year-to-year fluctuations in physical/chemical factors were quantified. The major source of variation in abundance of most species was that associated with seasonal recruitment cycles. Spatial variation in abundances of dominant species was small within habitats defined by sediment characteristics. However, abundance variation among sediment types was relatively large. All species showed significant year-to-year fluctuation in abundance, but no species had systematic long-term increases or decreases in abundance during the study period. Macrobenthos populations were persistent over the 11 years within abundance boundaries defined chiefly by fluctuations in salinity and dissolved oxygen concentration. Most species responded to salinity changes, especially those of an extreme nature, with predictable increases or decreases in abundance. Abundances of all species declined rapidly under conditions of low dissolved oxygen concentration (<2 ppm). Macrobenthos with planktonic developmental stages rapidly repopulated the region following periods of population decline. Repopulation by brooding species was slower.  相似文献   

Scale interaction in the Western Pacific Monsoon   总被引：9，自引：1，他引：9  

G. J. Holland 《Meteorology and Atmospheric Physics》1995,56(1-2):57-79

Summary The lower-tropospheric scale interactions occurring in the summer monsoon of the western North Pacific are reviewed and summarised in a conceptual model. Diabatic heating produces a circulation with similar characteristics to those that are observed. In the lower troposphere the advection of vorticity by the divergent wind produces a compact, and more intense response than in the upper levels. Subsequent phase dispersion westward, and group propagation eastwards, lead to a monsoon depression in convectively suppressed conditions, a westerly jet with cross-equatorial flow, and a strong confluence region to the east of the monsoon depression.I suggest that this confluence zone traps tropical waves in the mid-lower troposphere in a similar manner to the accumulation and emanation mechanisms described by Chang and Webster. The details of the convection in the confluence zone are of little direct consequence to the monsoon circulation, which is similar in scale to the deformation radius for the undisturbed tropics. However, mesoscale convective systems can both self organise into larger coherent structures and produce vortices of horizontal scale 100–200 km, which are long-lived and potentially have considerable indirect influence on both the monsoon and embedded systems, such as tropical cyclones. The confluence zone provides an excellent environment for tropical cyclone formation, which is enhanced by the presence of a previously developed tropical cyclone. Scale-interaction arising from the merger of developing vortices and the large monsoon depression can lead to development of a very large typhoon and rapid breakdown of the total monsoon circulation. The interaction of tropical cyclones with the mid-latitude systems is complex and not well understood, but recurving tropical cyclones may provide a major component of the emanation of energy to higher latitudes.With 16 Figures  相似文献   

Tropical soils could dominate the short-term carbon cycle feedbacks to increased global temperatures   总被引：4，自引：0，他引：4  

Alan R. Townsend  Peter M. Vitousek  Elisabeth A. Holland 《Climatic change》1992,22(4):293-303

Results of a simple model of the effects of temperature on net ecosystem production call into question the argument that the large stocks of soil carbon and greater projected warming in the boreal and tu ndra regions of the world willlead to rapid efflux of carbon from these biomes to the atmosphere. We show that low rates of carbon turnover in these regions and a relatively greater response of net primary production to changes in temperature may lead to carbon storage over some limited range of warming. In contrast, the high rates of soil respiration found in tropical ecosystems are highly sensitive to small changes in temperature, so that despite the less pronounced warming expected in equatorial regions, tropical soils are likely to release relatively large amounts of carbon to the atmosphere. Results for high-latitude biomes are highly sensitive to parameter values used, while the net efflux of carbon from the tropics appears robust.  相似文献   

A numerical diffusion model for continuous releases     

C. J. P. Van Buijtenen  J. Holland  D. Van Leeuwen 《Boundary-Layer Meteorology》1973,5(3):275-283

The purpose of this study was to develop a diffusion model for a continuous point source which takes into account the increase of wind speed with height, and to compare this model with short-range diffusion experiments. The main problem was to find a good expression for the vertical diffusion coefficient. It turned out that good agreement between theory and experiment could only be obtained by introducing a settling speed W for the tracer combined with a conventional expression for the vertical diffusion (K(Z) = K ₀Z^1−p). An empirical relation was found between K ₀ and τ _vU and between W and bar σ _vU².  相似文献   

Product study of the reaction of OH radicals with isoprene in the atmosphere simulation chamber SAPHIR     

M. Karl  H.-P. Dorn  F. Holland  R. Koppmann  D. Poppe  L. Rupp  A. Schaub  A. Wahner 《Journal of Atmospheric Chemistry》2006,55(2):167-187

Atmospheric oxidation of isoprene and its oxidation products methacrolein (MACR) and methyl vinyl ketone (MVK) have an important impact on the photochemical activity in the boundary layer, in particular in forested areas. The oxidation of isoprene by OH radicals was investigated in chamber experiments conducted under tropospheric conditions in the atmosphere simulation chamber SAPHIR at the Research Center Jülich. The aim was to determine the product yield of MVK and MACR in the OH-induced isoprene oxidation and the rate constant of their reaction with OH under real atmospheric conditions. The recently published updated degradation scheme for isoprene from Geiger et al. (2003) was used to determine rate constants and product yields. The fractional yields in the isoprene peroxy radical reaction with NO were found to be 0.41±0.03 for MVK and 0.27±0.03 for MACR. The rate coefficient for MACR with OH was found to be in very good agreement with the recommended value of IUPAC Atkinson (Atkinson et al., 2005). while the rate coefficient for MVK with OH was 27% lower.  相似文献   

Discussion of “Thermodynamic parameters of CaMgSi2O6-Mg2Si2O6 pyroxenes based on regular solution and cooperative disordering models” by Holland,Navrotsky, and Newton     

Donald H. Lindsley  Paula M. Davidson  T. J. B. Holland  A. Navrotsky  R. C. Newton 《Contributions to Mineralogy and Petrology》1981,75(3):301-306

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Identification and description of macrobenthic communities in the calvert cliffs region of the Chesapeake Bay     

Nancy K. Mountford  A. F. Holland  J. A. Mihursky 《Estuaries and Coasts》1978,1(2):139-139

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Amphibole zonation in metabasites as a guide to the evolution of metamorphic conditions   总被引：2，自引：0，他引：2  

Timothy J. B. Holland  Stephen W. Richardson 《Contributions to Mineralogy and Petrology》1979,70(2):143-148

In low grade metabasites the amphibole components tremolite, glaucophane, edenite and tschermakite have their activities controlled by interactions with the excess components albite, clinozoisite, chlorite, quartz and H₂O vapor. Three types of reaction are involved, (i) Those in which only components of condensed phases take part: isopleths of equilibrium constant are straight lines in the P-T plane. (ii) Dehydration reactions in which entropy change due to change in Al coordination is of the same sign as that due to dehydration: isopleths of constant K are positive at low pressure and negative at high pressure. (iii) Dehydration reactions in which entropy change due to Al coordination change is opposite in sign to that of dehydration: isopleths of constant K loop in the P-T plane with positive slopes at low and at high pressure. Zonation in naturally occurring amphiboles records the evolution of metamorphic conditions in particular rocks. In an example from the eastern Alps (Austria) early conditions calculated as 15 kb, 200 ° C evolve upgrade to 6 kb, 525 ° C implying concurrent heating and erosion. The record of evolving conditions may span some 30 Ma of geological history.  相似文献   

Archimedes and the Tauern eclogites: the role of buoyancy in the preservation of exotic eclogite blocks     

P.C. England  T.J.B. Holland 《Earth and Planetary Science Letters》1979,44(2):287-294

The eclogite fragments of the Tauern Window formed at pressures around 20 kbar and temperatures in the region 600–650°C; these pressures are higher by 10–12 kbar than those experienced by the units now surrounding the eclogite-bearing zone. The eclogites probably formed in a subduction zone prior to the main Austroalpine collision: downward shearing forces dominated over buoyancy forces in the subduction zone mélange, permitting the subduction of relatively light material to great depth. At the cessation of subduction this buoyant material returned to the surface, carrying eclogite blocks that were too small to sink rapidly through it. A similar mechanism could account for the emplacement of certain Alpine-type garnet peridotites.  相似文献