A series of reference materials are proposed for intercomparison and quality control purposes during the quantification of lignin oxidation products (LOP) from diverse environmental matrices. These materials are all easily accessible and certified for diverse organic constituents (NIST and IHSS). They represent a suite of natural environmental matrices (from solids to aqueous) and are characterized by a wide range of organic carbon and lignin concentrations with abundant proportions of all major LOP. The variability of LOP concentrations and signatures for all these materials averages 3–5% and does not exceed 10%. Using these standards, a new quantification method was developed and validated for the determination of low-level CuO oxidation products using capillary gas chromatography–tandem mass spectrometry (GC/MS–MS). Tandem mass spectrometry provides both the high sensitivity and selectivity required for the identification and quantification of trace levels of dissolved lignin. The method is particularly useful for removing interference from co-eluting isotopes generated from the DOM matrix and during glucose amendment procedures of low-carbon samples. Such glucose amendment is not necessary, however, when the CuO to organic carbon weight-to-weight ratio can be kept at a value < 200–300. 相似文献
The moisture transport history to the south of the Tibetan Plateau was modeled using the meteorological data provided by NCEP in this paper, and the modeled results were compared with the measured δ18O in the south of the Tibetan Plateau. The relation between δ18O in precipitation in the south of the Tibetan Plateau and moisture trajectories was discussed. The results show that the extremely low δ18O in precipitation in the south of the Tibetan Plateau is always related to the moisture from the low-level sea surface evaporation. The long-distance transport of moisture also contributes to low δ18O in precipitation probably due to the rainout process during moisture transport. It is also found that low δ18O in precipitation is also related with deep layer transport of moisture, and with intensive condensation in the upper layers of the atmosphere, resulting in low δ18O because of depletion of heavy isotopes in deep condensation. However, high δ18O in precipitation whether in monsoon period or not is always companied with moisture coming from the upper layers, and the moisture is from northern or western sides of the plateau. The interpretation of the modeled results is in agreement with the isotope fractionation processes.
In the era of economic globalization, the concept of Economic Polarized Area comes into being as an effective vehicle to agglomerate
the economic elements and sustain the economic lifeline of the region. Based on the region’s specific development mode and
construction form the concept is working in such a way that it will contribute to guide the economic development of the country
and will play an important role in competing with other regions or countries in the world. Due to the high speed development
of the last 30 years, the Yangtze Delta Region starts to show the features of Economic Polarized Area. But, compared with
other world-class Economic Polarized Areas, the economic strength and the ability of the Yangtze Delta Region to drive the
country’s economic development is still very low and the competitive power is still very limited. Expanding the boundaries
of the Economic Polarized Area of the Yangtze Delta may extend the economic hinterland of the core area of the Yangtze Delta
Region, will lighten the pressures from the limited resource and promote the rationalization of the industrial structure in
the Yangtze Delta Region’s core area. With regard to the reasonable boundaries of the Yangtze Delta Region, there are different
opinions and controversial arguments in political and academic circles. Starting from the idea of increasing the competitive
power and improving the economic strength of the Yangtze Delta Region, the paper firstly is discussing the requirements to
become a world-class Economic Polarized Area. In a second step an analysis of functional complementation and economic collaboration
between the cities of an “extended” Yangtze Delta Region has been carried out by in particular considering the feasibility
of integrating these “newly included” cities. The final result of the study is, that the Region should be expanded from the
number of 16 cities to 37 cities, and the appended cities should be divided up into two categories: Wenzhou, Jinhua, Yancheng,
Huaian, Maanshan, Wuhu, Tongling, Chaohu, Hefei, Chuzhou, Xuancheng should be taken as Preferred Extending Area, and Suqian,
Xuzhou, Lianyungang, Lishui, Quzhou, Chizhou, Anqing, Bengbu, Huangshan, Suzhou (Anhui Province) should be taken as Retained
Qualification Area. 相似文献