Binding of thorium(IV) to carboxylate, phosphate and sulfate functional groups from marine exopolymeric substances (EPS)   总被引：2，自引：0，他引：2  

Nicols G. Alvarado Quiroz  Chin-Chang Hung  Peter H. Santschi 《Marine Chemistry》2006,100(3-4):337

Th(IV) isotopes are important proxies in oceanographic investigations, and are used as tracers of particle dynamics and particulate organic matter (POC) fluxes out of the euphotic zone through the use of ²³⁴Th/POC ratios. These approaches rely on empirically determined and variable POC to ²³⁴Th ratios, which might be controlled, in parts, by the abundance of exopolymeric substances (EPS). EPS contain acidic polysaccharides (APS) and are excreted by both phytoplankton and bacteria. To this end, radiotracer experiments with EPS from microbial cultures were conducted to determine the binding environment of ²³⁴Th(IV)-binding ligands in colloids and suspended particles in marine systems. In these experiments, the ²³⁴Th distribution during isoelectric focusing (IEF) and polyacrylamide gel electrophoresis (PAGE) was related to the functional group composition of EPS and of colloidal organic matter (COM) isolated from the Gulf of Mexico (GOM) using cross-flow ultrafiltration. EPS was extracted from phytoplankton (Emiliania huxleyi and Synechococcus elongatus) and bacteria (Sagittula stellata and Roseobacter gallaeciensis) cultures by repeated alcohol precipitation. Phosphate and sulfate concentrations were determined using ion chromatography (IC). IEF profiles indicated that 49% to 65% of the ²³⁴Th-labeled EPS from plankton and bacteria as well as COM samples from the GOM was found concentrated below pH of 4, near an isoelectric point, pH_IEP, of about 2. The carboxylic acid maxima for extracted EPS and COM samples appeared close to the pH_IEF of ²³⁴Th(IV). The phosphate maximum appeared at the same pH_IEF as ²³⁴Th(IV) for EPS from R. gallaeciensis and S. elongatus. The sulfate maximum was found at the same pH_IEF as ²³⁴Th(IV) for EPS from S. elongatus and COM. The molecular weight (MW) of the strongly Th(IV)-binding ligand varied from 1 to 14 kDa, depending on the species, but was about 10 kDa in COM. Thus, depending on the species of plankton or bacteria, the MW and specific functional group composition of the strongly ²³⁴Th(IV)-binding amphiphilic biomolecule can vary. Therefore, different acidic functional groups can, at times, contribute to the binding of Th(IV) to the EPS chelating ligand, which can also have different MWs. This implies that the binding environment for Th(IV), which is present at total concentrations at least a million times lower than the acid functional groups, consists of strong polydentate chelate complexes in clustered structures of carboxylate, sulfates and/or phosphates. The combination of strongly chelating groups and amphiphilicity gives this biomolecule the unique properties of a “sticky” ligand.  相似文献   

Primary production in the Kuroshio current surrounding Taiwan     

Tsu-Chang Hung 《Journal of Oceanography》1975,31(6):255-258

Primary production in the Kuroshio current flowing around Taiwan Island was measured by using the radiocarbon method. High values of the daily primary production were found in both the aquacultural area at the western coast and the polluted area with raw rubbish heaps at the Keelung-Patoutzu coast. In the upwelling region of southeastern coast, low values of the primary production were observed. In the eastern coast, the rate of photosynthesis for an unit amount of chlorophylla under the saturated light was in the range of 1.2±0.2 mg C/mg chlorophylla/hr. Some discussions are made on the observed results.  相似文献   

Waterfall notch-filtering for restoration of acoustic backscatter records from Admiralty Bay,Antarctica     

Luciano Fonseca  Edson Mintsu Hung  Arthur Ayres Neto  Fábio José Guedes Magrani 《Marine Geophysical Researches》2018,39(1-2):139-149

A series of multibeam sonar surveys were conducted from 2009 to 2013 around Admiralty Bay, Shetland Islands, Antarctica. These surveys provided a detailed bathymetric model that helped understand and characterize the bottom geology of this remote area. Unfortunately, the acoustic backscatter records registered during these bathymetric surveys were heavily contaminated with noise and motion artifacts. These artifacts persisted in the backscatter records despite the fact that the proper acquisition geometry and the necessary offsets and delays were applied during the survey and in post-processing. These noisy backscatter records were very difficult to interpret and to correlate with gravity-core samples acquired in the same area. In order to address this issue, a directional notch-filter was applied to the backscatter waterfall in the along-track direction. The proposed filter provided better estimates for the backscatter strength of each sample by considerably reducing residual motion artifacts. The restoration of individual samples was possible since the waterfall frame of reference preserves the acquisition geometry. Then, a remote seafloor characterization procedure based on an acoustic model inversion was applied to the restored backscatter samples, generating remote estimates of acoustic impedance. These remote estimates were compared to Multi Sensor Core Logger measurements of acoustic impedance obtained from gravity core samples. The remote estimates and the Core Logger measurements of acoustic impedance were comparable when the shallow seafloor was homogeneous. The proposed waterfall notch-filtering approach can be applied to any sonar record, provided that we know the system ping-rate and sampling frequency.  相似文献   

Sedimentation in the floodplains of the Mekong Delta,Vietnam. Part I: suspended sediment dynamics          下载免费PDF全文

Nguyen Nghia Hung  José Miguel Delgado  Andreas Güntner  Bruno Merz  András Bárdossy  Heiko Apel 《水文研究》2014,28(7):3132-3144

Suspended sediment is the primary source for a sustainable agro‐ecosystem in the Mekong Delta by providing nutrient input for the subsequent cropping season. In addition, the suspended sediment concentration (SSC) plays an important role in the erosion and deposition processes in the Delta; that is, it influences the morphologic development and may counteract the deltaic subsidence and sea level rise. Despite this importance, little is known about the dynamics of suspended sediment in the floodplains of the Mekong Delta. In particular, quantitative analyses are lacking mainly because of data scarcity with respect to the inundation processes in the floodplains. In 2008, therefore, a comprehensive in situ system to monitor the dynamics of suspended sediment in a study area located in the Plain of Reeds was established, aiming at the characterization and quantification of suspended sediment dynamics in the deeply inundated parts of the Vietnamese part of the Mekong Delta. The monitoring system was equipped with seven water quality–monitoring stations. They have a robust design and autonomous power supply suitable for operation on inundated floodplains, enabling the collection of reliable data over a long period of time with a high temporal resolution. The data analysis shows that the general seasonal dynamics of suspended sediment transport in the Delta is controlled by two main mechanisms: the flood wave of the Mekong River and the tidal backwater influences from the coast. In the channel network, SSC decreases exponentially with distance from the Mekong River. The anthropogenic influence on SSC could also be identified for two periods: at the start of the floodplain inundation and at the end of the flood period, when subsequent paddy rice crops are prepared. Based on the results, we recommend an operation scheme for the sluice gates, which intends to distribute the sediment and thus the nutrients equally over the floodplain. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Isotopic constraints of vein carbonates on fluid sources and processes associated with the ongoing brittle deformation within the accretionary wedge of Taiwan   总被引：1，自引：0，他引：1  

Pei‐Ling Wang  Jia‐Jing Wu  En‐Chao Yeh  Sheng‐Rong Song  Yue‐Gau Chen  Li‐Hung Lin 《地学学报》2010,22(4):251-256

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THE TEA PLANTATION SYSTEM IN CEYLON: PERSISTENCE AND CHANGE*     

Frederick Hung 《The Professional geographer》1968,20(5):321-325

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Cao Dinh Trieu  Pham Nam Hung 《大地测量与地球动力学》2009,29(5):11-17

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Flood simulation using the gauge‐adjusted radar rainfall and physics‐based distributed hydrologic model     

Byung Sik Kim  Bo Kyung Kim  Hung Soo Kim 《水文研究》2008,22(22):4400-4414

This paper reports the results of an investigation into flood simulation by areal rainfall estimated from the combination of gauged and radar rainfalls and a rainfall–runoff model on the Anseong‐cheon basin in the southern part of Korea. The spatial and temporal characteristics and behaviour of rainfall are analysed using various approaches combining radar and rain gauges: (1) using kriging of the rain gauge alone; (2) using radar data alone; (3) using mean field bias (MFB) of both radar and rain gauges; and (4) using conditional merging technique (CM) of both radar and rain gauges. To evaluate these methods, statistics and hyetograph for rain gauges and radar rainfalls were compared using hourly radar rainfall data from the Imjin‐river, Gangwha, rainfall radar site, Korea. Then, in order to evaluate the performance of flood estimates using different rainfall estimation methods, rainfall–runoff simulation was conducted using the physics‐based distributed hydrologic model, Vflo^?. The flood runoff hydrograph was used to compare the calculated hydrographs with the observed one. Results show that the rainfall field estimated by CM methods improved flood estimates, because it optimally combines rainfall fields representing actual spatial and temporal characteristics of rainfall. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Unsupervised fuzzy neural network structural active pulse controller     

Shih‐Lin Hung  C. M. Lai 《地震工程与结构动力学》2001,30(4):465-484

Applying active control systems to civil engineering structures subjected to dynamic loading has received increasing interest. This study proposes an active pulse control model, termed unsupervised fuzzy neural network structural active pulse controller (UFN‐SAP controller), for controlling civil engineering structures under dynamic loading. The proposed controller combines an unsupervised neural network classification (UNC) model, an unsupervised fuzzy neural network (UFN) reasoning model, and an active pulse control strategy. The UFN‐SAP controller minimizes structural cumulative responses during earthquakes by applying active pulse control forces determined via the UFN model based on the clusters, classified through the UNC model, with their corresponding control forces. Herein, we assume that the effect of the pulses on structure is delayed until just before the next sampling time so that the control force can be calculated in time, and applied. The UFN‐SAP controller also averts the difficulty of obtaining system parameters for a real structure for the algorithm to allow active structural control. Illustrative examples reveal significant reductions in cumulative structural responses, proving the feasibility of applying the adaptive unsupervised neural network with the fuzzy classification approach to control civil engineering structures under dynamic loading. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

A strategy for the use of bomb-produced radiocarbon as a tracer for the transport of fossil fuel CO₂ into the deep-sea source regions     

Wallace S. Broecker  Tsung Hung Peng  Taro Takahashi 《Earth and Planetary Science Letters》1980,49(2):463-468

Because the equilibration time for CO₂ gas between the surface ocean and atmosphere is an order of magnitude shorter than the equilibration time for the isotopes of carbon, bomb-produced radiocarbon cannot be simply used as a tracer for fossil fuel CO₂. This difference is especially important for the areas of deep water formation. In this paper we derive the relationship between the isotopic equilibration time and chemical equilibration times for carbon between sea and air. We also show that if the distribution of a second transient tracer is measured, it is possible to circumvent the ambiguity associated with this exchange time difference. Tritium, while adequate in purely diffusive models, is not ideal as the second transient in models involving advection (i.e., downwelling). For such models⁸⁵Kr or freon is a much better choice.  相似文献