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11.
Groundwater contamination with arsenic and other trace elements in an area of the pampa,province of Córdoba,Argentina 总被引:1,自引:0,他引:1
Hugo B. Nicolli Jose M. Suriano Miguel A. Gomez Peral Luis H. Ferpozzi Omar A. Baleani 《Environmental Geology》1989,14(1):3-16
A geochemical study of groundwater of the pampa in the province of Córdoba, Argentina, was performed; the area covered approximately 10,000 km2.Physical-chemical parameters, dissolved solids, and seven trace elements were determined in 60 selected water samples. Systematic and accurate measurements of arsenic, flourine, and vanadium were performed for the first time. Three trace element contaminants not reported earlier were found: an important one, selenium, and two others of less known effects, uranium and molybdenum.Eighty-four percent of the water analyzed showed arsenic contents over 0.05 mg/L, maximum contaminant level established by the U.S. Environmental Protection Agency (1982). The frequency distribution of trace elements was analyzed, and its fit to the lognormal distribution was proved by means of the Pearson and Kolmogorov-Smirnov test; the geographic distribution of the seven trace elements was mapped and its correlation with the anion-cation composition of the water was studied.The maximum arsenic, fluorine, vanadium, and uranium contents were found in the western part of the area under study, in waters containing dominant alkali metals in the cation composition. Maximum selenium and antimony contents were found in the eastern part of the area, while molybdenum distribution does not show any relationship with the other two groups. In addition, the geographic distribution of the trace elements seems to be related to the subsurface structure, which has been inferred using interactive digital analysis of Landsat imagery. The movements of the subsoil have disturbed surface and subsurface drainage influencing the water salinity and trace element contents.In order to investigate the origin of the contamination, 54 loess samples were collected in wells at depths ranging from the surface down to the water table. This loess, which has a high proportion of volcanic components, mainly rhyolitic glass, exhibits a chemical composition corresponding to that of a dacite.The loess and the volcanic glass show anomalous contents of all contaminant trace elements, mainly arsenic and selenium. For this reason loess is considered the most important contamination source in the groundwater under study. 相似文献
12.
Graeme Hugo 《The Australian geographer》2007,38(3):335-357
The Australian Census of Population and Housing is a census of people not places. However, where people live and work can be of major relevance in our search for explaining and understanding their behaviour. This paper argues that the place dimension in the Australian census has not been exploited very effectively in this respect. Three dimensions of the issue are addressed. Firstly, the spatial units commonly used for analysis of census data often are not appropriate to the problem being investigated. The spatial units in the Australian Standard Geographical Classification (ASGC) used for census data rarely represent meaningful social, economic and environmental regions. Secondly, the use of a simple urban/rural dichotomy is criticised as being a very blunt instrument to differentiate settlement types. Thirdly, the relationship between people and place in the census is discussed. While for the most part the census relates people to a single location—their place of usual residence—this is only one of the places with which people regularly interact. It is suggested that there is a need to adopt practices in the census which allow a range of population geographies to be defined. In conclusion it is argued that innovation in the Australian census, especially with the introduction of meshblocks and contemporary methodology and technology in Geographical Information Systems, makes it possible to analyse spatially referenced data in ways that can address these three issues. 相似文献
13.
14.
Alexander Garcia-Aristizabal Hiroyuki Kumagai Pablo Samaniego Patricia Mothes Hugo Yepes Michel Monzier 《Journal of Volcanology and Geothermal Research》2007
Guagua Pichincha, located 14 km west of Quito, Ecuador, is a stratovolcano bisected by a horseshoe-shaped caldera. In 1999, after some months of phreatic activity, Guagua Pichincha entered into an eruptive period characterized by the extrusion of several dacitic domes, vulcanian eruptions, and pyroclastic flows. We estimated the three-dimensional (3-D) P-wave velocity structure beneath Guagua Pichincha using a tomographic inversion method based on finite-difference calculations of first-arrival times. Hypocenters of volcano-tectonic (VT) earthquakes and long-period (LP) events were relocated using the 3-D P-wave velocity model. A low-velocity anomaly exists beneath the caldera and may represent an active volcanic conduit. Petrologic analysis of eruptive products indicates a magma storage region beneath the caldera, having a vertical extent of 7–8 km with the upper boundary at about sea level. This zone coincides with the source region of deeper VT earthquakes, indicating that a primary magma body exists in this region. LP swarms occurred in a cyclic pattern synchronous with ground deformation during magma extrusions. The correlation between seismicity and ground deformation suggests that both respond to pressure changes caused by the cyclic eruptive behavior of lava domes. 相似文献
15.
Dr. Leonard R. Solon Pedro Lilienfeld Hugo J. DiGiovanni 《Meteorology and Atmospheric Physics》1968,17(2-3):251-289
Summary An instrumental system for securing aerosol samples in the stratosphere by electrostatic precipitation has been developed. The system is designed to be balloon borne to altitudes between 30 km and 45 km and to collect with high efficiency the aerosol content of the stratosphere at these altitudes. Volumetric sampling rates of one meter3 sec–1 ambient air are obtained with the sampling configuration with collection efficiency in excess of 95 percent for particles between .01 microns (mmd) and 2 microns (mmd).Specially developed associated instrumentation for altitude and air flow measurement points to an important versatility in the application of gas discharges for low-pressure (or high altitude) altimetry and anemometry over a very wide range of air densities and tempertures.The theory, operation, and performance of the aerosol sampling system and associated subsytems are described. Certain new observations of low-density corona physics phenomena are reported and potential applications to other areas of research and technology are indicated.
With 16 Figures
This work has been supported by the Division of Biology and Medicine, U. S. Atomic Energy Commission, under contract at (30-1)-2363 with Del Electronics. 相似文献
Zusammenfassung Es wurde ein Instrument entwickelt, mit dem man Aerosolproben aus der Stratosphäre durch elektrostatischen Niederschlag erhalten kann. Das System wird von einem Ballon in Höhen zwischen 30 und 45 km getragen und sammelt mit hoher Wirksamkeit Proben des Aerosolgehalts in diesen Höhen. Mit dem Instrument wird eine Sammelgeschwindigkeit von 1 m3/sek erreicht bei einer Sammelwirksamkeit von mehr als 95% für Partikel von Größen zwischen 0,01 und 2 Mikron.Besonders entwickelte angeschlossene Instrumente zur Messung der Höhe und der Luftströmungen zeigen die wesentliche Vielseitigkeit der Anwendung von Gasentladungen für die Höhenmessung und Windmessung bei niedrigem Druck (oder in großen Höhen) in einem großen Bereich der Luftdichte und der Temperatur.Es werden die Theorie, die Arbeitsweise und die Ausführung des Aerosolprobeninstrumentes und der angeschlossenen Hilfssysteme beschrieben. Es wird über einige neue Beobachtungen aus dem Bereich der Phänomene der Gasentladungen bei niedriger Dichte berichtet und neue mögliche Anwendungen in anderen Zweigen der Forschung und Technologie werden angegeben.
Résumé On a construit un instrument au moyen duquel on peut obtenir des échantillons d'aérosole stratosphérique par précipitation électrostatique. Le système est emporté par un ballon à des altitudes de 30 à 45 km et rassemble avec efficacité des echantillons du contenu de l'aérosole à ces altitudes. Avec cet appareil, on obtient une vitesse de prise de 1 m3/sec avec une efficacité de plus de 95% pour les particules comprises entre 0,01 et 2 microns.Des appareils spéciaux annexes permettent de mesurer la hauteur et les courants d'air. Ils démontrent les possibilités multiples de l'utilisation de la décharge dans un gaz pour la mesure de l'altitude et des vents par pression très faible (ou à très haute altitude) dans un domaine étendu tant de la densité de l'air que de la température.On décrit dans ce mémoire la théorie, le mode de travail et l'exécution de cet instrument de prise d'échantillons d'aérosoles ainsi que des systèmes auxiliaires annexes. On rapporte sur quelques nouvelles observations faites dans le domaine des phénomènes connexes à la décharge dans un gaz par faible densité. On indique en outre de nouvelles possibilités d'utilisation du système dans d'autres branches de la recherche ou de la technologie.
With 16 Figures
This work has been supported by the Division of Biology and Medicine, U. S. Atomic Energy Commission, under contract at (30-1)-2363 with Del Electronics. 相似文献
16.
Joint estimation of transmissivity (T) and storativity (S) in a confined aquifer is done via maximum likelihood (ML). The differential equation of groundwater flow is discretized by the finite-element method, leading to equation t+x
t=u
t. Elements of matrices and , as well as estimated covariance matrix of noise termu
t, are functions of T and S. By minimizing the negative loglikelihood function corresponding to discretized groundwater flow equation with respect to T and S, ML estimators are obtained. The ML approach is found to yield accurate estimates of T and S (within 9 and 10% of their actual values, respectively) and showed quadratic convergence in Newton's search technique. Prediction of aquifer response, using ML estimators, results in estimated piezometric heads accurate to ±0.5 m from their actual, exact values. Statistical properties of ML estimators are derived and some basic results for statistical inference are given. 相似文献
17.
Camps A. Skou N. Torres F. Corbella I. Duffo N. Vall-llossera M. 《Geoscience and Remote Sensing Letters, IEEE》2006,3(2):259-261
Accurate measurement of the antenna voltage patterns of large-aperture synthesis radiometers is critical in order to achieve good radiometric accuracy, and a very time consuming and expensive task. Measurement requirements and a tradeoff study relating radiometric accuracy degradation and number of elements to be measured are presented. 相似文献
18.
Carl P. Beitelshees C.Judson King Hugo H. Sephton 《International Journal of Mineral Processing》1981,8(2):97-110
An experimental study was made to identify surfactants which are effective for removal of copper from dilute aqueous solution (100–500 ppm) by precipitate flotation as the sulfide, and which at the same time can be recovered from the CuS product for recycle. Batch flotation experiments confirmed that a cationic surfactant was necessary for flotation of CuS from such dilute suspensions; however, no satisfactory way could be found for recovering cationic surfactants from the CuS. This led to consideration of amphoteric surfactants, which are cationic at low pH and anionic at high pH. It was found that a change to negative, rather than simply neutral, charge was required for efficient surfactant recovery. It was further found, through the assistance of experiments in which the CuS suspension was agitated with solvents, that certain functional groups which interact chemically with the CuS surface should also be absent from the surfactant molecule. Following this logic, Amphoterge K-2 (Lonza Chemical Co.) was identified as a suitable surfactant, provided CuS was precipitated with S2? in excess. Tests established that 95% of adsorbed Amphoterge K-2 could be recovered by raising the pH to 11 and boiling the suspension for one hour, followed by decanting. Surfactant thus recovered was effective in a second flotation test. Foamate solids settled rapidly; such behavior would help reduce the consumption of chemicals for the pH change.Column flotation studies were made using Amphoterge K-2 for removal of Cu2+ present at 100 ppm and pH = 2. High removals of CuS could be obtained at concentrations of surfactant above about 25 ppm, for which conditions a substantial fraction of the surfactant remains in solution rather than being adsorbed onto the CuS. The recovery of CuS would be improved by introducing the surfactant in a separate feed, below the feed of CuS suspension. Adding some surfactant in the CuS feed, as well as in a lower feed, gave an even better recovery of CuS (99.8%) at sufficiently high surfactant loadings. 相似文献
19.
Young Nathan L. Lemieux Jean-Michel Locat Pascal Demers Denis Delottier Hugo Mony Laura 《Hydrogeology Journal》2022,30(4):1337-1344
Hydrogeology Journal - An extensive network of multilevel vibrating-wire piezometers (VWP) was recently created to monitor the spatial and temporal variation of pore pressure (and hydraulic head)... 相似文献
20.
Chaulagain Hemchandra Rodrigues Hugo Silva Vitor Spacone Enrico Varum Humberto 《Natural Hazards》2015,78(1):583-602
Natural Hazards - Seismic risk in the form of impending disaster has been seen from past records that moderate-to-large earthquakes have caused the loss of life and property in all parts of Nepal.... 相似文献