Groundwater contamination with arsenic and other trace elements in an area of the pampa,province of Córdoba,Argentina   总被引：1，自引：0，他引：1  

Hugo B. Nicolli  Jose M. Suriano  Miguel A. Gomez Peral  Luis H. Ferpozzi  Omar A. Baleani 《Environmental Geology》1989,14(1):3-16

A geochemical study of groundwater of the pampa in the province of Córdoba, Argentina, was performed; the area covered approximately 10,000 km².Physical-chemical parameters, dissolved solids, and seven trace elements were determined in 60 selected water samples. Systematic and accurate measurements of arsenic, flourine, and vanadium were performed for the first time. Three trace element contaminants not reported earlier were found: an important one, selenium, and two others of less known effects, uranium and molybdenum.Eighty-four percent of the water analyzed showed arsenic contents over 0.05 mg/L, maximum contaminant level established by the U.S. Environmental Protection Agency (1982). The frequency distribution of trace elements was analyzed, and its fit to the lognormal distribution was proved by means of the Pearson and Kolmogorov-Smirnov test; the geographic distribution of the seven trace elements was mapped and its correlation with the anion-cation composition of the water was studied.The maximum arsenic, fluorine, vanadium, and uranium contents were found in the western part of the area under study, in waters containing dominant alkali metals in the cation composition. Maximum selenium and antimony contents were found in the eastern part of the area, while molybdenum distribution does not show any relationship with the other two groups. In addition, the geographic distribution of the trace elements seems to be related to the subsurface structure, which has been inferred using interactive digital analysis of Landsat imagery. The movements of the subsoil have disturbed surface and subsurface drainage influencing the water salinity and trace element contents.In order to investigate the origin of the contamination, 54 loess samples were collected in wells at depths ranging from the surface down to the water table. This loess, which has a high proportion of volcanic components, mainly rhyolitic glass, exhibits a chemical composition corresponding to that of a dacite.The loess and the volcanic glass show anomalous contents of all contaminant trace elements, mainly arsenic and selenium. For this reason loess is considered the most important contamination source in the groundwater under study.  相似文献   

Space,Place, Population and Census Analysis in Australia     

Graeme Hugo 《The Australian geographer》2007,38(3):335-357

The Australian Census of Population and Housing is a census of people not places. However, where people live and work can be of major relevance in our search for explaining and understanding their behaviour. This paper argues that the place dimension in the Australian census has not been exploited very effectively in this respect. Three dimensions of the issue are addressed. Firstly, the spatial units commonly used for analysis of census data often are not appropriate to the problem being investigated. The spatial units in the Australian Standard Geographical Classification (ASGC) used for census data rarely represent meaningful social, economic and environmental regions. Secondly, the use of a simple urban/rural dichotomy is criticised as being a very blunt instrument to differentiate settlement types. Thirdly, the relationship between people and place in the census is discussed. While for the most part the census relates people to a single location—their place of usual residence—this is only one of the places with which people regularly interact. It is suggested that there is a need to adopt practices in the census which allow a range of population geographies to be defined. In conclusion it is argued that innovation in the Australian census, especially with the introduction of meshblocks and contemporary methodology and technology in Geographical Information Systems, makes it possible to analyse spatially referenced data in ways that can address these three issues.  相似文献   

Pre-eruptive and syn-eruptive conditions in the Black Butte, California dacite: Insight into crystallization kinetics in a silicic magma system     

Molly C. McCanta  Malcolm J. Rutherford  Julia E. Hammer 《Journal of Volcanology and Geothermal Research》2007,160(3-4):263-284

A series of experiments and petrographic analyses have been run to determine the pre-eruption phase equilibria and ascent dynamics of dacitic lavas composing Black Butte, a dome complex on the flank of Mount Shasta, California. Major and trace element analyses indicate that the Black Butte magma shared a common parent with contemporaneously erupted magmas at the Shasta summit. The Black Butte lava phenocryst phase assemblage (20 v.%) consists of amphibole, plagioclase (core An_77.5), and Fe–Ti oxides in a fine-grained (< 0.5 mm) groundmass of plagioclase, pyroxene, Fe–Ti oxides, amphibole, and cristobalite. The phenocryst assemblage and crystal compositions are reproduced experimentally between 890 °C and 910 °C, ≥ 300 MPa, X_H2O = 1, and oxygen fugacity = NNO + 1. This study has quantified the extent of three crystallization processes occurring in the Black Butte dacite that can be used to discern ascent processes. Magma ascent rate was quantified using the widths of amphibole breakdown rims in natural samples, using an experimental calibration of rim development in a similar magma at relevant conditions. The majority of rims are 34 ± 10 μm thick, suggesting a time-integrated magma ascent rate of 0.004–0.006 m/s among all four dome lobes. This is comparable to values for effusive samples from the 1980 Mount St. Helens eruption and slightly faster than those estimated at Montserrat. A gap between the compositions of plagioclase phenocryst cores and microlites suggests that while phenocryst growth was continuous throughout ascent, microlite formation did not occur until significantly into ascent. The duration of crystallization is estimated using the magma reservoir depth and ascent rate, as determined from phase equilibria and amphibole rim widths, respectively. Textural analysis of the natural plagioclase crystals yields maximum growth rates of plagioclase phenocryst rims and groundmass microlites of 8.7 × 10^− 8 and 2.5 × 10^− 8 mm/s, respectively. These rates are comparable to values determined from time-sequenced samples of dacite erupted effusively from Mount St. Helens during 1980 and indicate that syneruptive crystallization processes were important during the Black Butte eruptive cycle.  相似文献   

Plant water sources in the cold semiarid ecosystem of the upper Kherlen River catchment in Mongolia: A stable isotope approach   总被引：5，自引：0，他引：5  

Sheng-Gong Li  Hugo Romero-Saltos  Atsuko Sugimoto  Gombo Davaa 《Journal of Hydrology》2007,333(1):109-117

  相似文献   

Seismic,petrologic, and geodetic analyses of the 1999 dome-forming eruption of Guagua Pichincha volcano,Ecuador     

Alexander Garcia-Aristizabal  Hiroyuki Kumagai  Pablo Samaniego  Patricia Mothes  Hugo Yepes  Michel Monzier 《Journal of Volcanology and Geothermal Research》2007

Guagua Pichincha, located 14 km west of Quito, Ecuador, is a stratovolcano bisected by a horseshoe-shaped caldera. In 1999, after some months of phreatic activity, Guagua Pichincha entered into an eruptive period characterized by the extrusion of several dacitic domes, vulcanian eruptions, and pyroclastic flows. We estimated the three-dimensional (3-D) P-wave velocity structure beneath Guagua Pichincha using a tomographic inversion method based on finite-difference calculations of first-arrival times. Hypocenters of volcano-tectonic (VT) earthquakes and long-period (LP) events were relocated using the 3-D P-wave velocity model. A low-velocity anomaly exists beneath the caldera and may represent an active volcanic conduit. Petrologic analysis of eruptive products indicates a magma storage region beneath the caldera, having a vertical extent of 7–8 km with the upper boundary at about sea level. This zone coincides with the source region of deeper VT earthquakes, indicating that a primary magma body exists in this region. LP swarms occurred in a cyclic pattern synchronous with ground deformation during magma extrusions. The correlation between seismicity and ground deformation suggests that both respond to pressure changes caused by the cyclic eruptive behavior of lava domes.  相似文献   

Long-term variations in thermal comfort in Vienna     

E. Koch  N. Hammer  E. Rudel 《Theoretical and Applied Climatology》1992,45(4):257-264

Summary A human energy balance model is calculated using the homogeneous data set of Vienna, Austria (48°N and 16° E). Variations in the different stages of comfort since 1873 are discussed. The historical data are then used to generate scenarios of a changing climate and calculate the impact of these variations on thermal comfort.With 5 Figures  相似文献   

A system for large volume aerosol sampling in the stratosphere using electrostatic precipitation     

Dr. Leonard R. Solon  Pedro Lilienfeld  Hugo J. DiGiovanni 《Meteorology and Atmospheric Physics》1968,17(2-3):251-289

Summary An instrumental system for securing aerosol samples in the stratosphere by electrostatic precipitation has been developed. The system is designed to be balloon borne to altitudes between 30 km and 45 km and to collect with high efficiency the aerosol content of the stratosphere at these altitudes. Volumetric sampling rates of one meter³ sec^–1 ambient air are obtained with the sampling configuration with collection efficiency in excess of 95 percent for particles between .01 microns (mmd) and 2 microns (mmd).Specially developed associated instrumentation for altitude and air flow measurement points to an important versatility in the application of gas discharges for low-pressure (or high altitude) altimetry and anemometry over a very wide range of air densities and tempertures.The theory, operation, and performance of the aerosol sampling system and associated subsytems are described. Certain new observations of low-density corona physics phenomena are reported and potential applications to other areas of research and technology are indicated.

---

Zusammenfassung Es wurde ein Instrument entwickelt, mit dem man Aerosolproben aus der Stratosphäre durch elektrostatischen Niederschlag erhalten kann. Das System wird von einem Ballon in Höhen zwischen 30 und 45 km getragen und sammelt mit hoher Wirksamkeit Proben des Aerosolgehalts in diesen Höhen. Mit dem Instrument wird eine Sammelgeschwindigkeit von 1 m³/sek erreicht bei einer Sammelwirksamkeit von mehr als 95% für Partikel von Größen zwischen 0,01 und 2 Mikron.Besonders entwickelte angeschlossene Instrumente zur Messung der Höhe und der Luftströmungen zeigen die wesentliche Vielseitigkeit der Anwendung von Gasentladungen für die Höhenmessung und Windmessung bei niedrigem Druck (oder in großen Höhen) in einem großen Bereich der Luftdichte und der Temperatur.Es werden die Theorie, die Arbeitsweise und die Ausführung des Aerosolprobeninstrumentes und der angeschlossenen Hilfssysteme beschrieben. Es wird über einige neue Beobachtungen aus dem Bereich der Phänomene der Gasentladungen bei niedriger Dichte berichtet und neue mögliche Anwendungen in anderen Zweigen der Forschung und Technologie werden angegeben.

---

Résumé On a construit un instrument au moyen duquel on peut obtenir des échantillons d'aérosole stratosphérique par précipitation électrostatique. Le système est emporté par un ballon à des altitudes de 30 à 45 km et rassemble avec efficacité des echantillons du contenu de l'aérosole à ces altitudes. Avec cet appareil, on obtient une vitesse de prise de 1 m³/sec avec une efficacité de plus de 95% pour les particules comprises entre 0,01 et 2 microns.Des appareils spéciaux annexes permettent de mesurer la hauteur et les courants d'air. Ils démontrent les possibilités multiples de l'utilisation de la décharge dans un gaz pour la mesure de l'altitude et des vents par pression très faible (ou à très haute altitude) dans un domaine étendu tant de la densité de l'air que de la température.On décrit dans ce mémoire la théorie, le mode de travail et l'exécution de cet instrument de prise d'échantillons d'aérosoles ainsi que des systèmes auxiliaires annexes. On rapporte sur quelques nouvelles observations faites dans le domaine des phénomènes connexes à la décharge dans un gaz par faible densité. On indique en outre de nouvelles possibilités d'utilisation du système dans d'autres branches de la recherche ou de la technologie.

---

---

With 16 Figures

---

This work has been supported by the Division of Biology and Medicine, U. S. Atomic Energy Commission, under contract at (30-1)-2363 with Del Electronics.  相似文献   

On solution of the inverse problem for confined aquifer flow via maximum likelihood     

Hugo A. Loaiciga  Miguel A. Mariño 《Mathematical Geology》1986,18(7):677-692

Joint estimation of transmissivity (T) and storativity (S) in a confined aquifer is done via maximum likelihood (ML). The differential equation of groundwater flow is discretized by the finite-element method, leading to equation _t+x _t=u _t. Elements of matrices and , as well as estimated covariance matrix of noise termu _t, are functions of T and S. By minimizing the negative loglikelihood function corresponding to discretized groundwater flow equation with respect to T and S, ML estimators are obtained. The ML approach is found to yield accurate estimates of T and S (within 9 and 10% of their actual values, respectively) and showed quadratic convergence in Newton's search technique. Prediction of aquifer response, using ML estimators, results in estimated piezometric heads accurate to ±0.5 m from their actual, exact values. Statistical properties of ML estimators are derived and some basic results for statistical inference are given.  相似文献   

Precipitate flotation of copper as the sulfide,using recyclable amphoteric surfactants     

Carl P. Beitelshees  C.Judson King  Hugo H. Sephton 《International Journal of Mineral Processing》1981,8(2):97-110

An experimental study was made to identify surfactants which are effective for removal of copper from dilute aqueous solution (100–500 ppm) by precipitate flotation as the sulfide, and which at the same time can be recovered from the CuS product for recycle. Batch flotation experiments confirmed that a cationic surfactant was necessary for flotation of CuS from such dilute suspensions; however, no satisfactory way could be found for recovering cationic surfactants from the CuS. This led to consideration of amphoteric surfactants, which are cationic at low pH and anionic at high pH. It was found that a change to negative, rather than simply neutral, charge was required for efficient surfactant recovery. It was further found, through the assistance of experiments in which the CuS suspension was agitated with solvents, that certain functional groups which interact chemically with the CuS surface should also be absent from the surfactant molecule. Following this logic, Amphoterge K-2 (Lonza Chemical Co.) was identified as a suitable surfactant, provided CuS was precipitated with S^2? in excess. Tests established that 95% of adsorbed Amphoterge K-2 could be recovered by raising the pH to 11 and boiling the suspension for one hour, followed by decanting. Surfactant thus recovered was effective in a second flotation test. Foamate solids settled rapidly; such behavior would help reduce the consumption of chemicals for the pH change.Column flotation studies were made using Amphoterge K-2 for removal of Cu²⁺ present at 100 ppm and pH = 2. High removals of CuS could be obtained at concentrations of surfactant above about 25 ppm, for which conditions a substantial fraction of the surfactant remains in solution rather than being adsorbed onto the CuS. The recovery of CuS would be improved by introducing the surfactant in a separate feed, below the feed of CuS suspension. Adding some surfactant in the CuS feed, as well as in a lower feed, gave an even better recovery of CuS (99.8%) at sufficiently high surfactant loadings.  相似文献   

The origin of cutoff frequencies for torsional tube waves propagating in the solar atmosphere     

R. Hammer  Z.E. Musielak  S. Routh 《Astronomische Nachrichten》2010,331(6):593-595

Torsional waves supported by magnetic flux tubes have long been thought to bear a high potential for supplying energy and momentum to the upper solar atmosphere, thereby contributing to its heating and to the driving of dynamic events like spicules. This hope rested on the belief that their propagation is not impeded by cutoff restrictions, unlike longitudinal and kink waves. We point out that this applies only to thin, isothermal tubes. When they widen in the chromosphere, and as a result of temperature gradients, cutoff restrictions arise. We compare them to recent observational reports of such waves and of vortex motions and find that their long period components are already affected by cutoff restrictions. An observational strategy is proposed that should permit the derivation of better information on vortex flows from off‐center observations with next generation telescopes (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献