Characteristics of major and trace elements in surface sediments of the Makran Accretionary Prism,Pakistan and their implications for natural gas hydrates     

Jian-ming Gong  Jing Liao  Yu-xi Zhang  Jie Liang  Jian-wen Chen  Nuzhat Khan  Syed Waseem Haider 《China Geology》2021,4(2):299-310

To accurately identify the natural gas hydrates (NGH) in the sea area of the Makran Accretionary Prism, Pakistan, this paper presents the testing and analysis of major and trace elements in sediment samples taken from two stations (S₂ and S₃) in the area by the China Geological Survey. As shown by testing results, all major elements are slightly different in content between the two stations except SiO₂ and CaO. This also applies to the trace elements that include Sr and Ba primarily and Cr, Ni and Zn secondarily. It can be concluded in this study that the tectonic setting of the Makran Accretionary Prism is dominated by oceanic island arc and that provenance of the Makran Accretionary Prism is dominated by felsic igneous provenance, which is at the initial weathering stage and mainly consists of granodiorite. Besides terrigenous detritus, there are sediments possibly originating from Makran-Bela Ophiolite from the northwestern part and Murray Ridge igneous rocks from the southeastern part. The V/Cr, Ni/Co, and V/(V+Ni) ratios indicate that sediments of the two stations are in an oxidation-suboxidation environment. However, the authors infer that the sedimentary environment of the sediments 3.0 m below the seafloor tends to be gradually transformed into a reduction environment by comparison with the Qiongdongnan Basin in the South China Sea where NGH has been discovered. The sediments in the Makran Accretionary Prism are rich in organic matter, with total organic carbon (TOC) content greater than 1%. According to comprehensive research, the organic matter in the sediments mainly originates from marine algae and has high TOC content, which is favorable for the formation of NGH.  相似文献   

Sorptive Potential of Beach Sand to Remove Ni(II) Ions: An Equilibrium Isotherm Study     

Syed Igleem Haider Taqvi  Syed Moosa Hasany  Mohammad Igbal Bhanger 《洁净——土壤、空气、水》2008,36(4):366-372

The potential to remove Ni(II) ions from aqueous solutions using sea beach sand, a carbonate‐quartz mineral, was thoroughly investigated. The effects of relevant parameters such as solution pH, adsorbent dose, metal ions concentration, and temperature on Ni(II) sorption onto beach sand were examined. The sorption data followed the Langmuir, Freundlich and Dubinin‐Radushkevich (D‐R) isotherms. The adsorption was endothermic in nature at ambient temperature and the computation of the parameters, ΔH, ΔS and ΔG indicated the interactions between sorbate and sorbent to be thermodynamically favorable. Equilibrium was achieved very quickly within 30 min of shaking. A pseudo‐first order Lagergren equation was used to test the adsorption kinetics. Other kinetic models, e. g., the Morris‐Weber and Reichenberg equations, were used to calculate the rate constant of intraparticle diffusion and the fate of the diffusion process, respectively. The influence of some of the common cations and anions were also a subject of this study.  相似文献   

Assessing prospects for shrimp culture in the Indian Sundarbans: A combined simulation modelling and choice experiment approach     

D. Knowler  N. Philcox  S. Nathan  W. Delamare  W. Haider  K. Gupta 《Marine Policy》2009

India's Sundarbans region lies within the state of West Bengal and is part of the world's largest mangrove ecosystem. Low-intensity shrimp aquaculture is present, but the potential exists for more intensive development. We argue for avoiding environmental damage and social conflict by adopting appropriate policies now. In this study, we combine ecological simulations and a choice experiment to evaluate several policy scenarios. Such comparative evaluations combining different disciplinary tools are rare. While our ecological modelling supports severe restrictions on shrimp farming activities, local stakeholders prefer a more diverse strategy. Both models indicate that large-scale commercial shrimp aquaculture is least desirable.  相似文献   

西南印度洋中脊49.5°E离轴地壳结构          下载免费PDF全文

王伟  牛雄伟  阮爱国  Syed Waseem Haider  胡昊  王奥星  卫小冬  张洁 《地球物理学报》2018,61(11):4406-4417

超慢速扩张西南印度洋中脊岩浆的集中供给在空间维度上表现为岩浆扩张段（NVR）与相邻的非转换断层不连续带（NTD）地壳结构的差异,而在时间维度上表现为离轴与沿轴地壳结构的差异.为了进一步揭示岩浆集中供给的时空分布特征,本文选取西南印度洋中脊热液区2010年海底地震仪深部探测中平行于洋中脊距轴部偏北约10 km的离轴测线d0d10,使用射线追踪正演和反演的方法,得到了NVR和NTD北侧离轴区域的地壳及上地幔P波速度结构,并与轴部速度结构进行了对比分析.研究结果表明：（1）NTD北侧离轴区域的地壳厚度约5.2 km,其厚度明显大于轴部NTD下方地壳厚度（~3.2 km）,由此推测洋脊轴部NTD区域形成的地壳在不断减薄;（2）NVR北侧离轴区域的地壳厚度约7.0 km,其厚度亦大于轴部NVR地壳厚度（~5.8 km）,表明在洋中脊演化过程中洋脊轴区域的岩浆供给在不断减少,其活动性在不断减弱.  相似文献   

洋中脊扩张速率对洋壳速度结构的约束          下载免费PDF全文

李龑  牛雄伟  阮爱国  刘绍文  Syed Waseem Haider  卫小冬 《地球物理学报》2020,63(5):1913-1926

洋中脊速度结构是揭示大洋岩石圈演化过程的重要约束.为探讨不同扩张速率下洋中脊的洋壳速度结构特征,挑选了全球152处快速(全扩张速率 90mm·a-1)、慢速(全扩张速率20～50mm·a-1)和超慢速(全扩张速率20mm·a-1)扩张洋中脊和非洋中脊的洋壳1-D地震波速度结构剖面,通过筛选统计、求取平均值等方法对分类的洋壳1-D速度结构进行对比研究,获得了不同扩张速率下洋中脊洋壳速度结构差异以及洋中脊与非洋中脊洋壳速度结构差异的新认识:(1)快速、慢速和超慢速扩张洋中脊的平均正常洋壳厚度分别为6.4km、7.2km和5.3km,其中洋壳层2的厚度基本相似,洋壳厚度差异主要源自洋壳层3;其洋壳厚度变化范围分别为4.9～8.1km、4.6～8.7km和4.2～10.2km,随着洋中脊扩张速率减小,洋壳厚度的变化范围逐渐增大;(2)快速扩张洋中脊的洋壳速度大于慢速和超慢速,可能与快速扩张脊洋壳生成过程中深部高密度岩浆上涌比较充足有关;(3)非洋中脊(10Ma)的洋壳比洋中脊(10Ma)的洋壳厚～0.3km,表明洋壳厚度与洋壳年龄有一定的正相关性.  相似文献   

Estimating groundwater discharge to surface waters using heat as a tracer in low flux environments: the role of thermal conductivity          下载免费PDF全文

Carlos Duque  Sascha Müller  Eva Sebok  Kinza Haider  Peter Engesgaard 《水文研究》2016,30(3):383-395

Analytical modelling of heat transport was used to address effects of uncertainty in thermal conductivity on groundwater–surface water exchange. In situ thermal conductivities and temperature profiles were measured in a coastal lagoon bed where groundwater is known to discharge. The field site could be divided into three sediment zones where significant spatial changes in thermal conductivity on metre to centimetre scale show that spatial variability connected to the sediment properties must be considered. The application of a literature‐based bulk thermal conductivity of 1.84 Wm^?1 °C^?1, instead of field data that ranged from 0.62 to 2.19 W m^?1 °C^?1, produced a mean overestimation of 2.33 cm d^?1 that, considering the low fluxes of the study area, represents an 89% increase and up to a factor of 3 in the most extreme cases. Incorporating the uncertainty due to sediment heterogeneities leads to an irregular trend of the flux distribution from the shore towards the lagoon. The natural variability of the thermal conductivity associated with changes in the sediment composition resulted in a mean variation of ±0.66 cm d^?1 in fluxes corresponding to a change of ±25.4%. The presence of organic matter in the sediments, a common situation in the near‐shore areas of surface water bodies, is responsible for the decrease of thermal conductivity. The results show that the natural variability of sediment thermal conductivity is a parameter to be considered for low flux environments, and it contributes to a better understanding of groundwater–surface water interactions in natural environments. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Using multivariate statistical analyses to evaluate groundwater contamination in the northwestern part of Saudi Arabia   总被引：2，自引：1，他引：1  

Taisser Zumlot  Awni Batayneh  Yousef Nazal  Habes Ghrefat  Saad Mogren  Haider Zaman  Eslam Elawadi  Abdalaziz Laboun  Saleh Qaisy 《Environmental Earth Sciences》2013,70(7):3277-3287

Chemical characteristics of groundwater in the Midyan Basin (northwestern Saudi Arabia) were investigated and evaluated. A total of 72 water samples were collected from existing shallow wells and analyzed for different elements. Two multivariate statistical methods, hierarchical cluster analysis (HCA) and principal components analysis (PCA), were applied to a subgroup of the data set in terms of their usefulness for groundwater classification, and to identify the processes controlling groundwater geochemistry. The subgroup consisted of 46 water samples out of 72 samples and 24 variables included major elements (Ca²⁺, Na⁺, Mg²⁺, K⁺, Cl^?, HCO₃ ^?, NO₃ ^?, SO₄ ^2?), minor and trace element (SiO₂, Al, As, B, Ba, Cd, Cr, F, Fe, Mo, P, Pb, Sb, Sn, Ti, and V). For water samples, four geochemically distinct clusters (i.e., C1, C2, C3 and C4) have been observed by hierarchical cluster analysis. Cr, F and Pb are the dominant ions in cluster C2. Al, As, Cd, Mo, Sb and Ti are the dominant ions in cluster C3, while B, Ca, Cl, HCO₃, K, Mg, Na, SO₄ and V are identified as dominant ions in the cluster C4. In the PCA, a total of five components are extracted form the data set, which explained 73.37 % of the total data variability. Among them the first component reveals strong associations between As, B, Cd, Cr, F, Mo, Pb, Sb and Ti. The second component reveals the associations between Ca, Cl, HCO₃, Mg, Na, SO₄ and V.  相似文献   

Radial distribution of production rates, loss rates and densities corresponding to ion masses ?40 amu in the inner coma of Comet Halley: Composition and chemistry     

S.A. Haider 《Icarus》2005,177(1):196-216

In this paper we have studied the chemistry of C, H, N, O, and S compounds corresponding to ions of masses ?40 amu in the inner coma of the Comet 1P/Halley. The production rates, loss rates, and ion mass densities are calculated using the Analytical Yield Spectrum approach and solving coupled continuity equation controlled by the steady state photochemical equilibrium condition. The primary ionization sources in the model are solar EUV photons, photoelectrons, and auroral electrons of the solar wind origin. The chemical model couples ion-neutral, electron-neutral, photon-neutral and electron-ion reactions among ions, neutrals, electrons, and photons through over 600 chemical reactions. Of the 46 ions considered in the model the chemistry of 24 important ions (viz., CH₃OH⁺₂, H₃CO⁺, NH⁺₄, H₃S⁺, H₂CN⁺, H₂O⁺, NH⁺₃, CO⁺, C₃H⁺₃, OH⁺, H₃O⁺, CH₃OH⁺, C₃H⁺₄, C₂H⁺₂, C₂H⁺, HCO⁺, S⁺, CH⁺₃, H₂S⁺, O⁺, C⁺, CH⁺₄, C⁺₂, and O⁺₂) are discussed in this paper. At radial distances <1000 km, the electron density is mainly controlled by 6 ions, viz., NH⁺₄, H₃O⁺, CH₃OH⁺₂, H₃S⁺, H₂CN⁺, and H₂O⁺, in the decreasing order of their relative contribution. However, at distances >1000 km, the 6 major ions are H₃O⁺, CH₃OH⁺₂, H₂O⁺, H₃CO⁺, C₂H⁺₂, and NH⁺₄; along with ions CO⁺, OH⁺, and HCO⁺, whose importance increases with further increase in the radial distance. It is found that at radial distances greater than ∼1000 km (±500 km) the major chemical processes that govern the production and loss of several of the important ions in the inner coma are different from those that dominate at distances below this value. The importance of photoelectron impact ionization, and the relative contributions of solar EUV, and auroral and photoelectron ionization sources in the inner coma are clearly revealed by the present study. The calculated ion mass densities are compared with the Giotto Ion Mass Spectrometer (IMS) and Neutral Mass Spectrometer (NMS) data at radial distances 1500, 3500, and 6000 km. There is a reasonable agreement between the model calculation and the Giotto measurements. The nine major peaks in the IMS spectra between masses 10 and 40 amu are reproduced fairly well by the model within a factor of two inside the ionopause. We have presented simple formulae for calculating densities of the nine major ions, which contribute to the nine major peaks in the IMS spectra, throughout the inner coma that will be useful in estimating their densities without running the complex chemical models.  相似文献   

Petrology and geochemistry of the Juzzak Sill,western Chagai arc (Pakistan): implications for petrogenesis and emplacement     

Rehanul?Haq?Siddiqui  M.?Qasim?Jan  M.?Ishaq?KakarEmail author  Ehsanullah?Kakar  Naghma?Haider 《Arabian Journal of Geosciences》2016,9(13):626

The Juzzak Sill occurs in the western part of the east-west trending, subduction-related magmatic belt known as the Chagai arc. The sill is concordantly emplaced in the Paleocene Juzzak Formation and locally cross-cuts the Early to Middle Eocene Robat Limestone and Eocene Saindak Formation. The sill is a porphyritic pyroxene diorite that grades into a porphyritic andesite (60.12–61.57 wt% SiO₂) along the chilled margins. It comprises phenocrysts of hypersthene and plagioclase (An_32–45) in a medium- to fine-grained groundmass of these minerals, opaque oxide, and apatite. The rocks are high-K (2.37–2.86 wt% K₂O) calc-alkaline with low Mg# (42–55), Cr (51–80 ppm), and Ni (22–30 ppm) contents. Mantle-normalized trace element patterns, exhibited by marked negative Nb anomalies and positive spikes for Sr, Rb, and Zr and are akin to island arc signatures. The relatively higher ratios of Zr/Y (3.57–6.58), Ti/V (46.05–54.36), Ta/Yb (0.14–0.15), and Th/Yb (2.56–2.65) and high ⁸⁷Sr/⁸⁶Sr ratio (0.70524) suggest the role of continental crust materials, thus implying continental margin-type arc affinity. The source diagnostic ratios including K/Ba, P/Zr, and La/Ce of Juzzak Sill andesite and Eocene andesite from the Chagai arc are more or less similar, but the former has a much higher K/Y and Ba/Y ratios, which suggests assimilations of the host sediments during intrusion.  相似文献   

Amateur decision-making in avalanche terrain with and without a decision aid: a stated choice survey     

Pascal Haegeli  Wolfgang Haider  Margo Longland  Ben Beardmore 《Natural Hazards》2010,52(1):185-209

Avalanches pose a serious threat to recreational backcountry travelers in mountainous terrain. This study explores how the three main amateur user groups of avalanche terrain in western Canada (backcountry skiers, out-of-bound skiers, and snowmobile riders) balance recreational goals with safety concerns when choosing backcountry destinations under varying avalanche conditions. Using a discrete choice experiment (DCE), a stated preference technique, the study first examines the strengths and weaknesses in the decision process of the three amateur groups by comparing their responses with the choice patterns of professional mountain guides. The results show that the decision-making strategies employed by the respective amateur groups vary considerably in their level of complexity and the degree to which avalanche safety considerations are incorporated. Second, we examine the effects of a decision aid that preprocesses the most crucial pieces of avalanche hazard information on the decision preferences of the amateur groups in the DCE. The results show that a relatively simple decision aid can influence the decision-making process considerably and steer users towards more avalanche hazard sensitive behaviour.  相似文献