Microbial–silica interactions in Icelandic hot spring sinter: possible analogues for some Precambrian siliceous stromatolites     

Kurt O. Konhauser  Vernon R. Phoenix  Simon H. Bottrell  David G. Adams  & Ian M. Head 《Sedimentology》2001,48(2):415-433

Silicified deposits, such as sinters, occur in several modern geothermal environments, but the mechanisms of silicification (and crucially the role of microorganisms in their construction) are still largely unresolved. Detailed examination of siliceous sinter, in particular sections of microstromatolites growing at the Krisuvik hot spring, Iceland, reveals that biomineralization contributes a major component to the overall structure, with approximately half the sinter thickness attributed to silicified microorganisms. Almost all microorganisms observed under the scanning electron microscope (SEM) are mineralized, with epicellular silica ranging in thickness from < 5 μm coatings on individual cells, to regions where entire colonies are cemented together in an amorphous silica matrix tens of micrometres thick. Within the overall profile, there appears to be two very distinct types of laminae that alternate repeatedly throughout the microstromatolite: ‘microbial’ layers are predominantly consisting of filamentous, intact, vertically aligned, biomineralized cyanobacteria, identified as Calothrix and Fischerella sp.; and weakly laminated silica layers which appear to be devoid of any microbial component. The microbial layers commonly have a sharply defined base, overlying the weakly laminated silica, and a gradational upper surface merging into the weakly laminated silica. These cyclic laminations are probably explained by variations in microbial activity. Active growth during spring/summer allows the microorganisms to keep pace with silicification, with the cell surfaces facilitating silicification, while during their natural slow growth phase in the dark autumn/winter months silicification exceeds the bacteria’s ability to compensate (i.e. grow upwards). At this stage, the microbial colony is probably not essential to microstromatolite formation, with silicification presumably occurring abiogenically. When conditions once again become favourable for growth, recolonization of the solid silica surface by free‐living bacteria occurs: cell motility is not responsible for the laminations. We have also observed that microbial populations within the microstromatolite, some several mm in depth, appear viable, i.e. they still have their pigmentation, the trichomes are not collapsed, cell walls are unbroken, cytoplasm is still present and they proved culturable. This suggests that the bulk of silicification occurred rapidly, probably while the cells were still alive. Surprisingly, however, measurements of light transmittance through sections of the microstromatolite revealed that photosynthetically active light (PAL) only transmitted through the uppermost 2 mm. Therefore the ‘deeper’ microbial populations must have either: (i) altered their metabolic pathways; (ii) become metabolically inactive; or (iii) the deeper populations may be dominated by different microbial assemblages from that of the surface. From these collective observations, it now seems unequivocal that microstromatolite formation is intimately linked to microbial activity and that the sinter fabric results from a combination of biomineralization, cell growth and recolonization. Furthermore, the similarities in morphology and microbial component to some Precambrian stromatolites, preserved in primary chert, suggests that we may be witnessing contemporaneous biomineralization processes and growth patterns analogous to those of the early Earth.  相似文献   

Dolomitization of the Waulsortian Limestone (Lower Carboniferous) in the Irish Midlands   总被引：1，自引：0，他引：1  

Jay M. Gregg  Kevin L. Shelton  Aaron W. Johnson  Ian D. Somerville  & Wayne R. Wright 《Sedimentology》2001,48(4):745-766

The Waulsortian Limestone (Lower Carboniferous) of the southern Irish Midlands is dolomitized pervasively over a much larger region than previous studies have documented. This study indicates a complex, multistage, multiple fluid history for regional dolomitization. Partially and completely dolomitized sections of Waulsortian Limestones are characterized by finely crystalline (0·01–0·3 mm) planar dolomite. Planar replacive dolomite is commonly followed by coarse (≥0·5 mm) nonplanar replacive dolomite, and pervasive void‐filling saddle dolomite cement is frequently associated with Zn–Pb mineralization. Planar dolomite has average δ¹⁸O and δ¹³C values (‰ PDB) of –4·8 and 3·9 respectively. These are lower oxygen and slightly higher carbon isotope values than averages for marine limestones in the Waulsortian (δ¹⁸O=–2·2, δ¹³C=3·7). Mean C and O isotope values of planar replacive dolomite are also distinct from those of nonplanar and saddle dolomite cement (–7·0 and 3·3; –7·4 and 2·4 respectively). Fluid inclusions indicate a complex history involving at least three chemically and thermally distinct fluids during dolomite cementation. The petrography and geochemistry of planar dolomites are consistent with an early diagenetic origin, possibly in equilibrium with modified Carboniferous sea water. Where the Waulsortian was exposed to hydrothermal fluids (70–280 °C), planar dolomite underwent a neomorphic recrystallization to a coarser crystalline, planar and nonplanar dolomite characterized by lower δ¹⁸O values. Void‐filling dolomite cement is isotopically similar to nonplanar, replacive dolomite and reflects a similar origin from hydrothermal fluids. This history of multiple stages of dolomitization is significantly more complex than earlier models proposed for the Irish Midlands and provides a framework upon which to test competing models of regional vs. localized fluid flow.  相似文献   

The beachwatch pollution monitoring programme: Changing priorities to recognize changed circumstances     

Ian Armstrong  Stephen Higham  Grant Hudson  Troy Colley 《Marine pollution bulletin》1996,33(7-12):249-259

Since the commissioning of the three major deepwater outfalls in Sydney, there has been a dramatic improvement in general beach water quality at Sydney's ocean beaches. This has required the NSW Environment Protection Authority's Beachwatch Programme to shift from assessing the impacts of gross sewage pollution due to nearshore outfalls to more diffuse pollution from stormwater and sewer overflows.

The visual indicators of gross sewage pollution originally used by Beachwatch for the daily assessment of bacterial water quality are now of limited value. General linear models (with multiple effects) were constructed to identify the secondary indicators which best describe the levels of bacterial contamination due to stormwater pollution. Data from four representative Sydney beaches were modelled separately due to the site-specific effects of pollution sources and hydrodynamics. Factors which were built into the models and were known on the day of prediction were rain amount, presence of stormwater material, the maximum daily stormwater rating, drain or lagoon flows at the time of sampling, and the drain/lagoon bacterial concentration two days before sampling.

Results indicate that there is a general linear relationship between visual indicators and bacterial density; however, the reliability of the prediction on a daily basis is poor and rainfall alone as a predictor is equivalent to or better than visual assessment alone. The primary source of information for the preparation of Beachwatch daily pollution bulletins now is rainfall reports from a telemetered network of rain gauges along the coast. This is a more cost-effective approach and has allowed the reallocation of resources to address more directly the problem of stormwater pollution at higher risk beaches.  相似文献   

Processing of oxidised nitrogen compounds by passage through winter-time orographic cloud     

R. N. Colvile  T. W. Choularton  J. N. Cape  B. J. Bandy  K. N. Bower  R. A. Burgess  T. J. Davies  G. J. Dollard  M. W. Gallagher  K. J. Hargreaves  B. M. R. Jones  S. A. Penkett  R. L. Storeton-West 《Journal of Atmospheric Chemistry》1996,24(3):211-239

Four case studies are described, from a three-site field experiment in October/November 1991 using the Great Dun Fell flow-through reactor hill cap cloud in rural Northern England. Measurements of total odd-nitrogen nitrogen oxides (NO _y ) made on either side of the hill, before and after the air flowed through the cloud, showed that 10 to 50% of the NO _y , called NO _z , was neither NO nor NO₂. This NO _z failed to exhibit a diurnal variation and was often higher after passage through cloud than before. No evidence of conversion of NO _z to NO₃ ^- in cloud was found. A simple box model of gas-phase chemistry in air before it reached the cloud, including scavenging of NO₃ and N₂O₅ by aerosol of surface area proportional to the NO₂ mixing ratio, shows that NO₃ and N₂O₅ may build up in the boundary layer by night only if stable stratification insulates the air from emissions of NO. This may explain the lack of evidence for N₂O₅ forming NO₃ ^- in cloud under well-mixed conditions in 1991, in contrast with observations under stably stratified conditions during previous experiments when evidence of N₂O₅ was found. Inside the cloud, some variations in the calculated total atmospheric loading of HNO₂ and the cloud liquid water content were related to each other. Also, indications of conversion of NO _x to NO _z were found. To explain these observations, scavenging of NO _x and HNO₂ by cloud droplets and/or aqueous-phase oxidation of NO₂ ^- by nitrate radicals are considered. When cloud acidity was being produced by aqueous-phase oxidation of NO _x or SO₂, NO₃ ^- which had entered the cloud as aerosol particles was liberated as HNO₃ vapour. When no aqueous-phase production of acidity was occurring, the reverse, conversion of scavenged HNO₃ to particulate NO₃ ^-, was observed.  相似文献   

Morphological characteristics of the earthquake surface ruptures on Awaji Island, associated with the 1995 Southern Hyogo Prefecture Earthquake   总被引：1，自引：0，他引：1  

Aiming  Ian Shinichi  Uda 《Island Arc》1996,5(1):1-15

Abstract The earthquake surface ruptures on the northern side of Awaji Island accompanying the 1995 Southern Hyogo Prefecture Earthquake in Japan consist of three earthquake surface rupture zones called the Nojima, Matsuho, and Kusumoto Earthquake Surface Rupture Zones. The Nojima Earthquake Surface Rupture Zone is - 18 km long and was formed from Awaji-cho at the northern end of Awaji Island to Ichinomiya-cho. It occurred along the pre-existing Nojima geological fault in the northern segment and as a new fault in the southern segment. The northern segment of the Nojima Earthquake Surface Rupture Zone is composed of some subparallel shear faults showing a right-step en echelon form and many extensional cracks showing a left-step en echelon form. The southern segment consists of some discontinuous surface ruptures which are concentrated in a narrow zone a few tens of meters in width. This surface rupture zone shows a general trend striking north 30°-60° east, and dipping 75°-85° east. The deformational topographies and striations on the fault plane generated during the co-seismic displacement show that the Nojima Earthquake Surface Rupture Zone is a right-lateral strike-slip fault with some reverse component. Displacements measured at many of the outcrops are generally 100-200 em horizontally and 50-100 em vertically in the northern segment and a few em to 20 em both horizontally and vertically in the southern segment. The largest displacements are 180 em horizontally, 130 em vertically, and 215 em in netslip measured at the Hirabayashi fault scarp. The Matsuho Earthquake Surface Rupture Zone striking north 40°-60° west was also found along the coastline trending northwest-southeast in Awaji-cho for ～1 km at the northern end of Awaji Island. The Kusumoto Earthquake Surface Rupture Zone occurred along the pre-existing Kusumoto geological fault for ～ 1.5 km near the northeastern coastline, generally striking north 35°-60° east, dipping 60°-70° west. From the morphological and geomorphological characteristics, the Nojima Earthquake Surface Rupture Zone can be divided into four segments which form a right-step en echelon formation. The geological and geomorphological evidence and the aftershock epicenter distributions show clearly that the distributions and geometry of these four segments are controlled by the pre-existing geological structures.  相似文献   

Deuterium tracing for the estimation of transpiration from trees Part 1. Field calibration     

Ian R. Calder  G.S. Kariyappa  N.V. Srinivasalu  K.V. Srinivasa Murty 《Journal of Hydrology》1992,130(1-4):17-25

Flow rates calculated using the deuterium tracing method were compared with measurements of direct water uptake of excavated trees which had been inserted into water containers. Taking into account that the tracing method provides an estimate of the weighted mean flow rate over the period that the tracer pulse is present (the weighting factor is the relative concentration of the tracer as measured at the sampling point) agreement was obtained within the experimental error (about 10%) associated with the tracing method.  相似文献   

Geodetic determination of crustal deformation across the Strait of Gibraltar     

W. Ian Reilly  Gabriele Fredrich  Günter W Hein  Herbert Landau  J. L. Almazán  J. L. Caturla 《Geophysical Journal International》1992,111(2):391-398

  相似文献   

Evidence for the trapped liquid shift effect in the Mount Ayliff Intrusion,South Africa   总被引：1，自引：2，他引：1  

R. Grant Cawthorn  Bernhard K. Sander  Ian M. Jones 《Contributions to Mineralogy and Petrology》1992,111(2):194-202

Postcumulus trapped liquid shift in layered complexes produces cumulate minerals with more fractionated compositions than the original primary phases. This effect is shown by olivine compositions from the base of the Mount Ayliff Intrusion, where varying proportions of olivine to interstitial liquid produce a suite of rocks which define a tight linear trend on a binary whole-rock plot of MgO versus FeO. Extrapolation of this trend constrains the composition of the primary cumulus olivine to the range Fo_84–86, whereas olivine actually present have compositions Fo_77–83. The magnitude of the discrepancy between the theoretical and observed olivine compositions correlates directly with the weight fraction of interstitial liquid. These observations are quantitatively predicted by the trapped liquid shift model. They also argue against significant migration of residual liquid. Trapped liquid shift is documented over a vertical interval of 60 m. It occurred in rocks lying only 1 m above the basal contact of the intrusion and hence must be a comparatively rapid process.  相似文献   

Estimates of total radiation and albedo in Sub-Arctic Canada     

C. Ian Jackson 《Theoretical and Applied Climatology》1960,10(2):193-199

Summary Maps have recently been prepared of the physiography and plant cover of Labrador-Ungava, in the Canadian Sub-Arctic. These enable detailed studies of representative localities to be extended over wider areas. Methods of estimating the average total insolation from sun and sky received at the surface are discussed, together with aerial measurements of albedo and thus a method of calculating the insolation absorbed by the surface is demonstrated. The limitations of the technique are stressed.

---

Zusammenfassung Es wurden Karten der Physiographie und Pflanzenbedeckung von Labrador-Ungava im sub-arktischen Klimagebiet Kanadas bearbeitet; an Hand dieser Karten kann von einzelnen, repräsentativen Orten auf die Verhältnisse in größeren Gebieten geschlossen werden. Die Methoden zur Abschätzung der Globalstrahlung an der Erdoberfläche werden diskutiert. Zusammen mit Messungen der Albedo vom Flugzeug aus ergibt sich eine Möglichkeit, die vom Erdboden absorbierte Strahlungsenergie zu berechnen. Die Grenzen der Leistungsfähigkeit dieser Methode werden betont.

---

Résumé On a dressé des cartes de la physiographie et de la couverture végétale du Labrador-Ungava soumis au climat subarctique du Canada. Elles permettent d'étendre les conclusions relatives à certains lieux représentatifs à de plus grands territoires. Discussion des méthodes d'estimation du rayonnement global à la surface du sol. En tentant compte de mesures de l'albédo faites depuis l'avion, on peut calculer l'énergie de rayonnement absorbée par le sol. Les limites d'application de la méthode sont discutées.

---

---

The research described in this paper was sponsored jointly by the Carnegie Arctic Programme of McGill University and the Defence Research Board of Canada.  相似文献   

The petrology of the Las Canadas volcanoes,Tenerife, Canary islands     

William Ian Ridley 《Contributions to Mineralogy and Petrology》1970,26(2):124-160

Tenerife is the largest of the seven Tertiary to Recent volcanic islands that make up the Canary Archipelago. The island is composed of volcanics belonging to the basanitetrachyte-phonolite assemblage that characterises many Atlantic islands. The most voluminous development of intermediate and salic volcanics has been in the centre of the island where the Las Canadas volcanoes arose upon a basement shield composed mainly of basanite and ankaramite flows, tuffs and agglomerates. The initial post-shield activity built the Vilaflor volcanic complex (Lower and Upper Canadas Series) that originally covered much of the underlying shield volcanics. A vast collapse of the complex, probably during post-Pleistocene times, in the centre of the island has left a large semi-circular wall, and provides an excellent vertical section through the complex. Quaternary volcanism within the collapsed area has built the twin, central-type volcanoes, Viejo and Teide, both of which have attendant satellite vents. That part of the Vilaflor Complex exposed in Las Canadas, together with the Viejo and Teide volcanoes, comprise the Las Canadas volcanoes.Four distinct rock types can be recognised in these volcanoes, basanite, trachybasanite, plagioclase phonolite, and phonolite. Each rock type can be recognised chemically and mineralogically, but there is essentially a gradational series from basanite to phonolite that includes both aphyric and glomerophyric rocks. The volcanics are strongly undersaturated and sodic, and some of the phonolites are mildly peralkaline. Variations in degree of undersaturation, and trace element abundances indicate a number of cycles of activity which would be consistent with the known field relations.Forsteritic olivine occurs in the basanites and trachybasanites but is not a stable phase in the more salic volcanics. Clinopyroxene is ubiquitous, varying in composition from titanaugite in the basanites to slightly sodic augite in the phonolites. Strongly sodic pyroxene is restricted to the groundmass of the microcrystalline phonolites along with aenigmatite and a kataphoritic amphibole. Plagioclase is found only in the groundmass of the basanites, but andesine and potash-oligoclase are common phenocryst minerals in the trachybasanites and plagioclase phonolites respectively, whereas the characteristic feldspar of the phonolites is anorthoclase.The relatively smooth curves of major and trace element variation, the presence of accumulative volcanics at all stages of differentiation, zoning of the mineral phases, and the clustering of the phonolites around the low temperature trough in Petrogeny's Residua System, all indicate that the descent from basanite to phonolite has resulted from fractional crystallisation of a basanite parent magma. The trend of pyroxene crystallisation, and the fairly constant FeO/Fe₂O₃ ratio during fractionation indicate crystallisation under low PO₂ conditions.  相似文献