UV Laser Ablation ICP-MS: Some Applications in the Earth Sciences   总被引：4，自引：0，他引：4  

Robert W. Nesbitt  Takafumi Hirata  Ian B. Butler  James A. Milton 《Geostandards and Geoanalytical Research》1997,21(2):231-243

This study reports a series of applications of UV laser ablation ICP-MS in the geological sciences. The advantages and disadvantages of the PQ "S" option and the use of nitrogen in the carrier gas are discussed. A general problem common to all ablation techniques is the calibration technique and experiments involving synthetic calibration samples are covered. Zircon geochemistry and geochronology by LA-ICP-MS are discussed and data are presented for REE, Hf and U for a standard zircon (91500) as well as a series of zircons from Zimbabwe. The potential of using Ce and Eu anomalies in petrologic studies is illustrated by zircons from a fractionated gabbroic-granite in the Urals. The potential of the LA-ICP-MS method to utilise standard X-ray fluorescence glass discs is demonstrated as a useful semi-quantitative tool in determining REE patterns. LA-ICP-MS is a powerful tool in the analysis of the platinum group elements (and Re) and some examples are given in the successful application of the technique to partitioning in iron meteorites.  相似文献   

Some reflections on World Heritage   总被引：1，自引：0，他引：1  

Douglas Pocock 《Area》1997,29(3):260-268

Summary This paper presents some initial reflections on the emergence of the World Heritage Convention in 1972, the significance of the appellation 'world' and the interpretation of 'heritage'. The dichotomous definition of heritage has found decreasing support in practice and occasioned changes in the original Operational Guidelines for implementing the Convention .  相似文献   

Recovering magnetic susceptibility from electromagnetic data over a one-dimensional earth   总被引：1，自引：0，他引：1  

Zhiyi Zhang  Douglas W. Oldenburg 《Geophysical Journal International》1997,130(2):422-434

While the inversion of electromagnetic data to recover electrical conductivity has received much attention, the inversion of those data to recover magnetic susceptibility has not been fully studied. In this paper we invert frequency-domain electromagnetic (EM) data from a horizontal coplanar system to recover a 1-D distribution of magnetic susceptibility under the assumption that the electrical conductivity is known. The inversion is carried out by dividing the earth into layers of constant susceptibility and minimizing an objective function of the susceptibility subject to fitting the data. An adjoint Green's function solution is used in the calculation of sensitivities, and it is apparent that the sensitivity problem is driven by three sources. One of the sources is the scaled electric field in the layer of interest, and the other two, related to effective magnetic charges, are located at the upper and lower boundaries of the layer. These charges give rise to a frequency-independent term in the sensitivities. Because different frequencies penetrate to different depths in the earth, the EM data contain inherent information about the depth distribution of susceptibility. This contrasts with static field measurements, which can be reproduced by a surface layer of magnetization. We illustrate the effectiveness of the inversion algorithm on synthetic and field data and show also the importance of knowing the background conductivity. In practical circumstances, where there is no a priori information about conductivity distribution, a simultaneous inversion of EM data to recover both electrical conductivity and susceptibility will be required.  相似文献   

Shear-wave anisotropy: spatial and temporal variations in time delays at Parkfield, Central California   总被引：4，自引：0，他引：4  

Yun Liu  Stuart Crampin  Ian Main 《Geophysical Journal International》1997,130(3):771-785

Shear-wave splitting is analysed on data recorded by the High Resolution Seismic Network (HRSN) at Parkfield on the San Andreas fault, Central California, during the three-year period 1988-1990. Shear-wave polarizations either side of the fault are generally aligned in directions consistent with the regional horizontal maximum compressive stress, at some 70° to the fault strike, whereas at station MM in the immediate fault zone, shear-wave polarizations are aligned approximately parallel to the fault. Normalized time delays at this station are found to be about twice as large as those in the rock mass either side. This suggests that fluid-filled cracks and fractures within the fault zone are elastically or seismically different from those in the surrounding rocks, and that the alignment of fault-parallel shear-wave polarizations are associated with some fault-specific phenomenon.
Temporal variations in time delays between the two split shear-waves before and after a M_L = 4 earthquake can be identified at two stations with sufficient data: MM within the fault zone and VC outside the immediate fault zone. Time delays between faster and slower split shear waves increase before the M_L = 4 earthquake and decrease near the time of the event. The temporal variations are statistically significant at 68 per cent confidence levels. Earthquake doublets and multiplets also show similar temporal variations, consistent with those predicted by anisotropic poroelasticity theory for stress modifications to the microcrack geometry pervading the rock mass. This study is broadly consistent with the behaviour observed before three other earthquakes, suggesting that the build-up of stress before earthquakes may be monitored and interpreted by the analysis of shear-wave splitting.  相似文献   

Leucoxene fish as a micro-kinematic indicator     

Douglas H. Oliver  John W. Goodge 《Journal of Structural Geology》1996,18(12):1493-1495

Asymmetric aggregates of fine-grained leucoxene and quartz are reported from siliceous L-S tectonites deformed by progressive simple shear. The leucoxene fish, morphologically similar to mica fish, consistently yield shear senses in agreement with other kinematic criteria. We interpret the leucoxene as a pre- or early syntectonic alteration product of detrital heavy-minerals in a siliciclastic protolith. The leucoxene fish behave as passive markers, and they record kinematics by modification of pre-existing aggregates rather than syndeformational mineral growth. For siliceous metasedimentary rocks otherwise lacking in micro-kinematic indicators, leucoxene fish may provide an alternative to quartz c-axis analysis.  相似文献   

Arrays of Unpumped Wells for Plume Migration Control by Semi-Passive In Situ Remediation     

Ryan D. Wilson  Douglas M. Mackay  John A. Cherry 《Ground Water Monitoring & Remediation》1997,17(3):185-193

Arrays of unpumped wells can be used as discontinuous permeable walls in which each well serves both as a means to focus ground water flow into the well for treatment and as a container either for permeable reactive media which directly destroy dissolved ground water contaminants or for devices or materials which release amendments that support in situ degradation of contaminants within the aquifer downgradient of the wells. This paper addresses the use of wells for amendment delivery, recognizing the potential utility of amendments such as electron acceptors (e.g., oxygen nitrate), electron donors (primary substrates), and microbial nutrients for stimulating bioremediation, and the potential utility of oxidizers, reducers, etc., for controlled abiotic degradation. Depending on its rate and constraints, the remedial reaction may occur within the well and/or downgradient. For complete remediation of ground water passing through the well array, the total flux of amendment released must meet or exceed the total flux demand imposed by the plume. When there are constraints on the released concentration of amendment (relative to the demand), close spacing of the wells may be required. If the flux balance allows wider spacing, it is likely that limited downgradient spreading of the released amendment will then be the primary constraint on interwell spacing. Divergent flow from the wells, roughly two times the well diameter, provides the bulk of downgradient spreading and constrains maximum well spacing in the absence of significant lateral dispersion. Stronger lateral dispersion enhances the spreading of amendment, thereby increasing the lateral impact of each well, which allows for wider well spacing.  相似文献   

Cold anticyclonic eddies formed from cold pool water in the southern Middle Atlantic Bight     

Charles N. Flagg  Douglas Wallace  Zbigniew Kolber 《Continental Shelf Research》1997,17(15):1839-1867

AVHRR satellite imagery of the southern Mid-Atlantic Bight during May 1993 revealed a large area of cold water over the shelf break and slope that appeared to spin up into a series of southward propagating anticyclonic eddies. The eddies had diameters of 35–45 km at the surface and moved southward at about 20 cm/sec. A radial TOYO CTD (to 50m) and ADCP velocity (to 400m) transect was conducted across the southern-most of these eddies. The upper 50 meters had minimum temperatures of less than 7°C and salinities of about 33 pss, characteristics similar to cold pool waters usually found over the continental shelf. ADCP velocity data from one of the eddies revealed anticyclonic flow extending to a depth of about 250m. The transport of cold pool water by the eddies was estimated to be 0.1 to 0.2 Sv which is of the same order as the annual mean alongshore transport of shelf water in this region. The origin of the deeper water within the eddy is unlikely to be the continental shelf because the shelf break is less than 100 m. The depth and velocity profiles along the TOYO transect were consistent with the constant potential vorticity eddy model of Flierl (1979) although the source of the eddy kinetic energy is uncertain. The cause for the exodus of cold pool water from the shelf, which extended northward to at least 38°N, is unclear but must involve the establishment of an alongshore baroclinic pressure gradient against the usual southwestward shelf flow. It is possible that the intrusion of Gulf Stream waters onto the shelf near Cape Hatteras was a precursor of this off shelf transport. The southern-most eddy was marked by high biological productivity and very high oxygen supersaturation. The phytoplankton bloom detected within the exported cold pool water, located over the continental slope, suggests a mechanism whereby production fueled by nutrients derived from the shelf can be locally exported into deep water.  相似文献   

Radiative Exchange in an Urban Street Canyon   总被引：1，自引：4，他引：1  

Ian N. Harman  Martin J. Best  Stephen E. Belcher 《Boundary-Layer Meteorology》2004,110(2):301-316

The influence of building geometry on the radiation terms ofthe surface energy balance is a principal reason for surfacetemperature differences between rural and urban areas.Methods exist to calculate the radiation balance in an urban area,but their validity across the range of urban geometries andmaterials has not been carefully considered.Here the exchange of diffuse radiation in an urban street canyon isinvestigated using a method incorporating all reflections of radiation.This exact solution is compared to two commonly used approximationsthat retain either no reflections, or just one reflection of radiation.The area-averaged net radiative flux density from the facets of the canyondecreases in magnitude monotonically as the canyon aspect ratio increases.The two approximate solutions possess unphysical differences from thismonotonic decrease for high canyon aspect ratios or low materialemissivities/high material albedos.The errors of the two approximate solutions are small for near blackbodymaterials and small canyon aspect ratios but can be an order ofmagnitude for intermediate material properties and deep street canyons.Urban street canyon models need to consider at least one reflectionof radiation and multiple reflections are desirable for full applicability.  相似文献   

International and National Aspects of a Legislative Framework to Manage Soil Carbon Sequestration   总被引：1，自引：0，他引：1  

Ian Hannam 《Climatic change》2004,65(3):365-387

This article discusses the international and national environmental law framework for the management of soil carbon sequestration. Aspects of the legislative framework important to this process include its ability to recognise carbon sinks, expand existing sinks, and the procedures available to return and store carbon in soil reservoirs. International law provides global standards and guidelines and national legislative systems provide the substantive and procedural legal mechanisms to manage soil carbon. The United Nations Framework Convention on Climate Change and the Kyoto Protocol are the primary international legislative instruments but other international instruments and strategies have a significant synergistic role. Various approaches are presented for framing new legislation or to reform existing legislative frameworks to improve the procedures to manage soil carbon.  相似文献   

Human exploration of the Moon and Mars: implications for Aurora   总被引：1，自引：0，他引：1  

Ian A Crawford 《Astronomy& Geophysics》2004,45(2):2.28-2.29

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