Confirmation of a meteoritic component in impact‐melt rocks of the Chesapeake Bay impact structure,Virginia, USA—Evidence from osmium isotopic and PGE systematics     

Seung Ryeol Lee  J. Wright Horton  Richard J. Walker 《Meteoritics & planetary science》2006,41(6):819-833

Abstract— The osmium isotope ratios and platinum‐group element (PGE) concentrations of impact‐melt rocks in the Chesapeake Bay impact structure were determined. The impact‐melt rocks come from the cored part of a lower‐crater section of suevitic crystalline‐clast breccia in an 823 m scientific test hole over the central uplift at Cape Charles, Virginia. The ¹⁸⁷Os/¹⁸⁸Os ratios of impact‐melt rocks range from 0.151 to 0.518. The rhenium and platinum‐group element (PGE) concentrations of these rocks are 30–270x higher than concentrations in basement gneiss, and together with the osmium isotopes indicate a substantial meteoritic component in some impact‐melt rocks. Because the PGE abundances in the impact‐melt rocks are dominated by the target materials, interelemental ratios of the impact‐melt rocks are highly variable and nonchondritic. The chemical nature of the projectile for the Chesapeake Bay impact structure cannot be constrained at this time. Model mixing calculations between chondritic and crustal components suggest that most impact‐melt rocks include a bulk meteoritic component of 0.01–0.1% by mass. Several impact‐melt rocks with lowest initial ¹⁸⁷Os/¹⁸⁸Os ratios and the highest osmium concentrations could have been produced by additions of 0.1%–0.2% of a meteoritic component. In these samples, as much as 70% of the total Os may be of meteoritic origin. At the calculated proportions of a meteoritic component (0.01–0.1% by mass), no mixtures of the investigated target rocks and sediments can reproduce the observed PGE abundances of the impact‐melt rocks, suggesting that other PGE enrichment processes operated along with the meteoritic contamination. Possible explanations are 1) participation of unsampled target materials with high PGE abundances in the impact‐melt rocks, and 2) variable fractionations of PGE during syn‐ to post‐impact events.  相似文献   

Analysis of a “flickering” Geminid fireball     

Martin BEECH  Alison ILLINGWORTH  Ian S. MURRAY 《Meteoritics & planetary science》2003,38(7):1045-1051

Abstract— In the early morning hours of December 13, 2002, a bright Geminid fireball with an absolute magnitude of ?9.2 ± 0.5 was observed from Southern Saskatchewan, Canada. The fireball displayed distinct small‐scale oscillations in brightness, or flickering, indicative of the parent meteoroid being both non‐spherical and rotating. Using the light curve derived from a calibrated radiometer, we determine a photometric mass of 0.429 ± 0.15 kg for the meteoroid, and we estimate from its initial rotation rate of some 6 Hz that the meteoroid was ejected from the parent body (3200) Phaethon some 2500 ± 500 years ago. We find that 70% of Geminid fireballs brighter than magnitude ?3 display distinct flickering effects, a value that is in stark contrast to the 18% flickering rate exhibited by sporadic fireballs. The high coincidence of flickering and the deep atmospheric penetration of Geminid fireballs are suggestive of Geminid meteoroids having a highly resilient structure, a consequence, we suggest, of their having suffered a high degree of thermal processing. The possibility of Gemind material surviving atmospheric ablation and being sampled is briefly discussed, but the likelihood of collecting and identifying any such material is admittedly very small.  相似文献   

The cluster wind from local massive star clusters     

Ian R. Stevens  Joanna M. Hartwell 《Monthly notices of the Royal Astronomical Society》2003,339(1):280-288

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Dissolved organic carbon dynamics in two streams draining forested catchments at loch ard,Scotland     

Ian C. Grieve 《水文研究》1994,8(5):457-464

Dissolved organic carbon (DOC) was measured at four or eight hour intervals between mid-1989 and mid-1991 in two catchments in west central Scotland. The experimental catchment had been recently clear-felled and the control remained under forest. The amount of DOC varied during individual storm events following the stream hydro-graph. Maximum variations were found in the summer half-year and in the clear-felled catchment. There was also evidence of the exhaustion of DOC in the later events of a sequence. Differences between the catchments were related to catchment characteristics and to land-use change. The reduced magnitude of variation in DOC with discharge in the control stream was due to the influence of a wetland area through which the stream flowed. The mean DOC concentrations were similar in the two streams and annual exports were 15 g m^?2 from the control and 16g m^?2 from the felled catchment. The stream draining the clear-felled catchment had greater high flow DOC concentrations in the summer half-year, probably due to the effect of greater mean summer temperatures on DOC release and of the greater supply of organic debris in the stream channel.  相似文献   

Reviews     

Ian Alexander  D. S. Houghton  L. D. B. Heenan  Peter Curson  B. R. O'Donnell  D. A. Chisholm 《The Australian geographer》1987,18(1):67-100

OFFICE DEVELOPMENT: A Geographical Analysis by M. Bateman. 14 × 22 cm, xvi and 175 pages. Croom Helm: London 1985 (ISBN 0 7099 0697 8) $A35.95 (cloth).

ATLAS OF YOUTH UNEMPLOYMENT, 1981: The Geographic Distribution of Youth Unemployment in Australian Cities from the 1981 Census According to Birthplace and Gender by P. Matwijiw with E. Bamford and C. Maher. 21 × 29 cm, 127 pages. Australian Institute of Multicultural Affairs: Melbourne 1985 (ISBN 949890 33 2) $A12.00 (limp).

ENVIRONMENT AND HEALTH by A. J. Rowland and P. Cooper. 23 × 16 cm, vi and 205 pages. Edward Arnold: London 1983 (ISBN 0 7131 2855 0) $A27.95 (limp).

FAMINE AS A GEOGRAPHICAL PHENOMENON edited by B. Currey and G. Hugo. 17 × 24 cm, vi and 202 pages. Reidel: Dordrecht 1984 (ISBN 90 277 1762 1) Dfl 95.00, $US37.00 (cloth).

SOUTH AUSTRALIA'S CHANGING POPULATION (South Australian Geographical Papers No. 1) by G. J. Hugo. 25 × 18 cm, 71 pages. Royal Geographical Society of Australasia (SA Branch): Adelaide 1983 (ISBN 0 909112 05 03) $A4.00 (limp).

DEVELOPMENTS IN POLITICAL GEOGRAPHY edited by M. A. Busteed. 23 × 15 cm, 340 pages. Academic Press: London 1983 (ISBN 0 12 148420 3) $US42.00 (cloth).

NEITHER JUSTICE NOR REASON: A Legal and Anthropological Analysis of Aboriginal Land Rights by M. Gumbert. 22 × 14 cm, xv and 215 pages. University of Queensland Press: St Lucia 1984 (ISBN 0 7022 1746 8) $A20.00 (cloth).

RURAL RESOURCE MANAGEMENT by P. J. Cloke and C. C. Park. 14 × 22 cm, xiii and 473 pages. Croom Helm: London 1985 (ISBN 0 7099 2037 7) $A44.95 (cloth).

FARM POLICY IN AUSTRALIA by R. K. Hefford. 14 × 22 cm, xviii and 415 pages. University of Queensland Press: St Lucia 1985 (ISBN 0 7022 1698 4) $A40.00 (cloth).

TRANSPORT AND COMMUNICATIONS FOR PACIFIC MICROSTATES: Issues in Organisation and Management edited by C. C. Kissling. 14 × 21 cm, 192 pages. Institute of Pacific Studies, University of the South Pacific: Suva 1984. $A10.00 (cloth), $A8.00 (limp).

TIMES OF CRISIS: Epidemics in Sydney 1788–1900 by P. H. Curson. 15 × 25 cm, xii and 195 pages. Sydney University Press: Sydney 1985 (ISBN 0 424 00112 8). $A35.00 (cloth).

PEASANTS, SUBSISTENCE, ECOLOGY AND DEVELOPMENT IN THE HIGHLANDS OF PAPUA NEW GUINEA by L. S. Grossman. 24 × 16 cm, xxi and 302 pages. Princeton University Press: Princeton, NJ 1984 (ISBN 0 691 09406 3) $US45.50.

THE WORLD FOOD PROBLEM 1950–1980 by D. Grigg. 15 × 24 cm, 276 pages. Basil Blackwell: Oxford 1985 (ISBN 0 631 13481 6) $A58.50 (cloth).

POPULATION REDISTRIBUTION AND DEVELOPMENT IN SOUTH ASIA edited by L. A. Kosinski and K. M. Elahi. 17 × 24 cm, 243 pages. Reichel: Dordrecht 1985 (ISBN 90 277 1938 1) Dfl 120.00, $US44.00, £30.50 (cloth).

GEOGRAPHY AND ETHNIC PLURALISM edited by C. Clarke, D. Ley and C. Peach. 15 × 23 cm, xvii and 294 pages. Allen & Unwin: London 1984 (ISBN 0 04 309107 5) $A45.00 (cloth); (ISBN 0 04 309108 3) $A24.95 (limp).

SOCIAL GEOGRAPHY IN INTERNATIONAL PERSPECTIVE edited by J. Eyles. 14 × 22 cm, 295 pages. Croom Helm: London 1986 (ISBN 0 7099 0944 6) $A49.95 (cloth).

THE GENTRIFICATION OF INNER MELBOURNE: A Political Geography of Inner City Housing by W. S. Logan. 14 × 22 cm, xvi and 328 pages. University of Queensland Press: St. Lucia 1985 (ISBN 0 7022 1729 8) $A50.00 (cloth).

YELLOWCAKE AND CROCODILES: Town Planning, Government and Society in Northern Australia by J. Lea and R. Zehner. 14 × 22 cm, xxvi and 200 pages. Allen & Unwin: Sydney 1986 (ISBN 0 86861 875 6) $A24.95 (cloth); (ISBN 0 86861 843 8) $A 14.95 (limp).

THE BUNGALOW: The Production of a Global Culture by A. D. King. 20 × 25 cm, xii and 310 pages. Routledge & Kegan Paul: London 1984 (ISBN 0 7100 9538 4) $A62.50 (cloth).

THE WEST EUROPEAN CITY: A Social Geography by P. White. 15 × 23 cm, xviii and 269 pages. Longman: London 1984 (ISBN 0 582 30047 9) $A22.95 (limp).

THE SHAPING OF AMERICA: A Geographical Perspective on 500 years of History. Volume 1. Atlantic America, 1492–1800 by D. W. Meinig. 18 × 25 cm, xii and 500 pages. Yale University Press: New Haven 1986 (ISBN 0 300 03548 9) $US35.00 (cloth).

CANBERRA: MYTHS AND MODELS. Forces at Work in the Formation of the Australian Capital by K. F. Fischer. 21 × 30 cm, 166 pages. Institute of Asian Studies: Hamburg 1984 (ISBN 3 88910 009 0).

THE GEOGRAPHY OF PEACE AND WAR edited by D. Pepper and A. Jenkins. 15 × 23 cm, vi and 222 pages. Basil Blackwell: Oxford 1985 (ISBN 0 631 13559 6) $A75.00 (cloth); (ISBN 0 631 14069 7) $A23.95 (limp).

POLITICAL GEOGRAPHY: World‐economy, Nation‐state and Locality by P. J. Taylor. 15 × 23 cm, × and 238 pages. Longman: London 1985 (ISBN 0 582 30088 6) $A24.95 (limp).

THE INDUSTRIAL GEOGRAPHY OF CANADA by A. Blackbourn and R. G. Putnam 14 × 22 cm, 201 pages. Croom Helm: London 1984 (ISBN 0 7099 0622 6) $A42.50 (cloth).

THE FOODMAKERS by S. Sargent. 13 × 20 cm, 296 pages. Penguin: Ringwood 1985 (ISBN 0 14 007359 0) $A8.95 (limp).

LIMITS TO PREDICTION edited by R. B. McKern and G. C. Lowenthal. 13 × 19 cm, xiii and 163 pages. Australian Professional Publications: Sydney 1985 (ISBN 0 949416 029) $A14.95 (limp).

THE KANGAROO KEEPERS edited by H. J. Lavery. 18 × 25 cm, xxvi and 211 pages. University of Queensland Press: St Lucia 1985 (ISBN 0 7022 1875 8).

PRACTICAL ECOLOGY by D. D. Gilbertson, M. Kent and F. B. Pyatt. 15 × 23 cm, 320 pages, Hutchinson: London 1985 (ISBN 0 09 162651 X) £8.95.

BASIC BIOGEOGRAPHY (Second edition) by N. Pears. 15 × 24 cm, × and 358 pages. Longman: London 1985 (ISBN 0 582 30120 3) $A24.95 (limp).

ENVIRONMENTAL CHANGE (Second edition) by A. Goudie. 23 × 15 cm, xi and 258 pages. Oxford University Press: Oxford 1983 (ISBN 0 19 874135 9) A16.00 (limp).

MEGA‐GEOMORPHOLOGY edited by R. Gardner and H. Scoging. 16 × 24 cm, xiii and 240 pages. Oxford University Press: Oxford (ISBN 0 19 823244 6) $A48.00.

GRANITE LANDFORMS by C. R. Twidale. 25 × 17 cm, xxiii and 372 pages. Elsevier: Amsterdam 1982 (ISBN 0 444 42116 5) $A148.25.  相似文献   

The redox states of basic and silicic magmas: a reflection of their source regions?   总被引：22，自引：1，他引：21  

Ian S. E. Carmichael 《Contributions to Mineralogy and Petrology》1991,106(2):129-141

At present the best estimates of the oxygen fugacity of spinel-lherzolites that could be the source material of basic magmas is about five log units below the Ni–NiO buffer to one above it. However partially glassy basic lavas, ranging from MORBs to minettes, all with olivine on their liquidus, cover a wider range, and may have oxygen fugacities that extend to four log units above NNO. Surprisingly the range of oxygen fugacities observed in silicic lavas and ashflows with quartz phenocrysts is smaller, despite a crustal dominated evolution. The peralkaline silicic lava type pantellerite is the most reduced, equivalent to MORBs, whereas the large volume ashflows with phenocrysts of hornblende and/or sphene are the most oxidised. As the concentration of water in the basic lavas is correlated with increase in their redox state, it would seem that water could be the agent of this increase. That this is unlikely is seen in the behavior of silicic ashflows and lavas, particularly those of Yellowstone. Here the silicic magmas of the last 2Ma contain about 2 wt% FeO_(total), and typically phenocrysts of fayalite, quartz and Fe–Ti oxides. Despite extensive exchange of the ¹⁸O of the magma with meteoric water after caldera collapse (Hildreth et al. 1984), there is no displacement of the redox equilibria. Thus the thermal dissociation of molecular H₂O to H₂, and its subsequent diffusive loss to cause oxidation must have been minimal. This could only be so if the activity of water was small, as it would be if H₂O reacted with the silicate liquid to form OH groups (Stolper 1982). The conclusion is that silicic magmas with small amounts of iron and large amounts of water do not have their redox states reset, which in turn presumably reflect their generation. By analogy basic magmas with large amounts of iron and far less water are even less likely to have their redox equilibria disturbed, so that their oxygen fugacities will also reflect their source regions. The effect of pressure on the ferric-ferrous equilibrium in basic magmas can be calculated from experimental measurements of the partial molar volumes of FeO and Fe₂O₃, and their pressure derivatives V/P, in silicate liquids. The effect of pressure is found to be about the same on the liquid as it is for various solid oxygen buffers. Accordingly there should be mantle source regions covering the same range of oxygen fugacity as that found in basic lavas, but so far samples of spinel-lherzolite of equivalent oxygen fugacity to minettes or other potassic lavas have not been found. Whether or not the redox state of phlogopite-pyroxenites is equivalent to these potassic lavas cannot be established without experiment.  相似文献   

Estimating proximate populations for an extensive set of locations in Australia     

Cocks KD  Walker PA 《The Australian geographer》1985,16(4):295-300

"The paper reports the use of Australian Resources Information System to calculate two proximate populations (people living within (i) 150 and (ii) 500 km) for the centroids of each of 3,000 half by half degree geodetic grid cells covering Australia. The use of proximate population data is exemplified by computing a map of the eighteen regions collectively containing a maximum fraction of the Australian population." The data used are from the 1981 census.  相似文献   

Advances in our understanding of the gem corundum deposits of the West Pacific continental margins intraplate basaltic fields   总被引：2，自引：1，他引：1  

Ian Graham  Lin Sutherland  Khin Zaw  Victor Nechaev  Alexander Khanchuk 《Ore Geology Reviews》2008,34(1-2):200

Recent discoveries over the last decade of new gemfields, exploitation of new and existing deposits, and application of relatively new techniques have greatly increased our knowledge of the basalt-derived gem sapphire–ruby–zircon deposits. In this paper we focus on the Late Mesozoic to Cenozoic intraplate basaltic fields of the West Pacific continental margins. We review advances made in understanding the genesis of these deposits, based on the application of newer techniques. We also critically review existing data on the gem corundum deposits, in order to further refine a model for their origin.In some of the intraplate basaltic fields, corundum-bearing xenoliths have been found showing a range of PT formation conditions from 790 °C at 0.85 GPa to as much as 1100 to 1200 °C at 1.0 to 2.5 GPa. Although most magmatic sapphires contain syngenetic inclusions of columbite-group phases, zircon, spinel and rutile, some contain additional nepheline and K-feldspar, suggesting crystallization from more undersaturated alkaline magma while the Weldborough field of NE Tasmania also contains molybdenite and beryl, suggesting at least some interaction with more fractionated ‘granitic-type’ magmas. There is a large range in PT conditions calculated for the metamorphic rubies (from 780 to 940 °C, through 800 to 1150 °C up to 1000 to 1300 °C). Fluid/melt inclusion studies on magmatic corundums generally suggest that they formed in a CO₂-rich environment from a ‘syenitic’ melt under a range of T conditions from 720 to 880 °C up to 1000 to 1200 °C. Oxygen isotope studies reveal that typical magmatic corundums have values of + 4.4 to 6.9‰, whereas metamorphic corundums from the same basaltic host have lower values of + 1.3 to 4.2‰.Geochronological studies have shown that some fields produced a simple eruptive and zircon/corundum crystallization event while others had multiple eruptive events but only one or two zircon crystallization events. For a few fields, some corundums/zircons crystallized in storage regions and then remained relatively inert for periods of 200 to 400 Ma without significant change before transport to the surface in the Cenozoic. Tectonic studies of the Australian region suggest that many of the corundums crystallized from magmas related to episodic basaltic volcanism in a tectonic regime of extension, associated with the opening of the Tasman and Coral Seas. For the Asian region, the magmatic–polygenetic corundums within the basaltic fields largely crystallized in a tectonic regime of distributed E–W extension, whereas the metamorphic-metasomatic corundums crystallised in a transpressional regime associated with the collision of the Indian Plate with the Eurasian Plate (e.g., [Garnier, V., Giuliani, G., Maluski, H., Ohnenstetter, D., Deloule, E., 2003. Ar–Ar and U–Pb ages of marble-hosted ruby deposits from Central and South-east Asia. Geophysical Research Abstracts 5, 03751; Garnier, V., Giuliani, G., Ohnenstetter, D., and Schwarz, D., 2004. Les gisements de corindon: classification et genese. Les placers a corindon gemme. Le Regne Mineral 55, 7-47; Garnier, V., Ohnenstetter, D., Giuliani, G., Maluski, H., Deloule, E., Phan Trong, T., Pham Van, L., Hoang Quang, V., 2005a. Age and significance of ruby-bearing marble from the Red River Shear Zone, Northern Vietnam. Canadian Mineralogist 43, 1315–1329]).  相似文献   

Geotechnical properties of evaporite soils of the Dead Sea area     

Sam Frydman  Josef Charrach  Ian Goretsky 《Engineering Geology》2008,101(3-4):236-244

The Dead Sea Basin is the lowest point on earth and is tectonically subsiding. During the Holocene Period the climate became much drier with increasing evaporation whereby initially lacustrine sediments were deposited from the non-marine brines, giving a multi-layered stratigraphy of lime carbonate and halite sediments. The lime carbonate sediments are comprised of laminated, clay to silt sized, clastic sediments (calcite) and authigenic aragonite and gypsum. The halite commonly appears as rock salt. Chemical industries, based on harvesting the salts from the Dead Sea, have developed on both the Israeli and the Jordanian sides of the basin. The lime carbonate soils are used for dike construction, and these soils, together with significant salt layers, are encountered in the foundations of structures, dikes, and tailings dams, requiring definition of their geotechnical properties. Use of standard soil mechanics definitions and testing approaches for the lime carbonates have been found inapplicable, particularly in view of their exceptionally high saline content, and it has been necessary to develop new concepts. The rock salt is encountered at shallow depths, with unit weights considerably lower than those usually discussed in the literature, and with correspondingly different mechanical properties. The geotechnical properties of these soils, and approaches used to define them, are discussed in the paper.  相似文献   

Fractionation of Cu and Zn isotopes during adsorption onto amorphous Fe(III) oxyhydroxide: Experimental mixing of acid rock drainage and ambient river water     

Laurie S. Balistrieri  David M. Borrok  W. Ian Ridley 《Geochimica et cosmochimica acta》2008,72(2):311-328

Fractionation of Cu and Zn isotopes during adsorption onto amorphous ferric oxyhydroxide is examined in experimental mixtures of metal-rich acid rock drainage and relatively pure river water and during batch adsorption experiments using synthetic ferrihydrite. A diverse set of Cu- and Zn-bearing solutions was examined, including natural waters, complex synthetic acid rock drainage, and simple NaNO₃ electrolyte. Metal adsorption data are combined with isotopic measurements of dissolved Cu (⁶⁵Cu/⁶³Cu) and Zn (⁶⁶Zn/⁶⁴Zn) in each of the experiments. Fractionation of Cu and Zn isotopes occurs during adsorption of the metal onto amorphous ferric oxyhydroxide. The adsorption data are modeled successfully using the diffuse double layer model in PHREEQC. The isotopic data are best described by a closed system, equilibrium exchange model. The fractionation factors (α_soln-solid) are 0.99927 ± 0.00008 for Cu and 0.99948 ± 0.00004 for Zn or, alternately, the separation factors (Δ_soln-solid) are −0.73 ± 0.08‰ for Cu and −0.52 ± 0.04‰ for Zn. These factors indicate that the heavier isotope preferentially adsorbs onto the oxyhydroxide surface, which is consistent with shorter metal-oxygen bonds and lower coordination number for the metal at the surface relative to the aqueous ion. Fractionation of Cu isotopes also is greater than that for Zn isotopes. Limited isotopic data for adsorption of Cu, Fe(II), and Zn onto amorphous ferric oxyhydroxide suggest that isotopic fractionation is related to the intrinsic equilibrium constants that define aqueous metal interactions with oxyhydroxide surface sites. Greater isotopic fractionation occurs with stronger metal binding by the oxyhydroxide with Cu > Zn > Fe(II).  相似文献