δ53Cr values of catchment runoff exhibit seasonality regardless of bedrock Cr concentrations: Role of periodically changing chromium export fluxes     

Alexandre V. Andronikov  Martin Novak  Pavel Kram  Ondrej Sebek  Irina E. Andronikova  Marketa Stepanova  Hyacinta Vitkova  Elena Antalova  Arnost Komarek 《水文研究》2021,35(12):e14434

One pre-requisite for the construction of a global chromium isotope mass balance is detailed understanding of Cr isotope systematics in the critical zone where redox-processes can modify the isotope signature of geogenic Cr input into the hydrosphere. A Cr isotope inventory of bedrock, soil, and runoff was performed in a Central European headwater catchment underlain by amphibolite, situated in the vicinity of two previously studied catchments underlain by different bedrock types (serpentinite and leucogranite). Fresh bedrock in the amphibolite catchment NAZ contained ~300 mg/kg Cr, serpentinite at PLB contained ~800 mg/kg Cr, and leucogranite at LYS contained ~2 mg/kg Cr. Monthly hydrochemical monitoring at all three sites revealed higher Cr(VI) export fluxes in winter than in summer. NAZ was characterized by a distinct seasonality in the δ⁵³Cr values, with minima during winter/spring snowmelts (−0.35‰) and maxima during dry summers (0.40‰). Similar seasonality in δ⁵³Cr values had been reported from PLB and LYS. Bedrock at all three sites had similar Cr isotope composition close to −0.10‰, a value indistinguishable from the δ⁵³Cr value of bulk silicate Earth (BSE). Positive mean δ⁵³Cr value of NAZ runoff indicated Cr-isotope fractionations during weathering of geogenic Cr(III), combined with adsorption of the resulting Cr(VI) on soil particles during pedogenesis. However, the mass-weighted mean δ⁵³Cr of NAZ runoff was lower (−0.08‰), indistinguishable from the Cr isotope signature of bedrock. The same pattern of lower mass-weighted mean δ⁵³Cr values of runoff, compared to arithmetic mean δ⁵³Cr values of runoff, were observed also at PLB and LYS. We suggest that elevated Cr runoff fluxes in winter remove some of the residual isotopically light Cr that accumulated in the soil during summer. Seasonality in runoff δ⁵³Cr values appears to be a relatively widespread phenomenon, de-coupled from Cr availability for chemical weathering.  相似文献   

Multi-proxy climate and environmental records from a Holocene eutrophic mire,southern taiga subzone,West Siberia     

Irina V. Kurina  Elena E. Veretennikova  Anna A. Il’ina  Marina L. Egorova  Lyudmila V. Salisch  Vladimir N. Dolgin  Albert V. Udaloi  Evgeniya A. Golovatskaya  Egor A. Dyukarev  Sergei V. Smirnov 《Boreas: An International Journal of Quaternary Research》2023,52(2):223-239

Palaeoenvironmental reconstructions from peat are strongly focused on ombrotrophic mires, but this study demonstrates that eutrophic mires can also be used. A multi-proxy approach was applied to a eutrophic mire on a floodplain terrace in the southern taiga of West Siberia. The results of the reconstruction were considered in the wide geographic context of the surrounding regions, including Siberia and Central Asia. Different palaeoecological proxies (analysis of plant macrofossils, testate amoebae, oribatid mites, molluscs, peat humification, ash content and spectral characteristics of humic acids) were used in this study. The results of different proxies showed a high level of consistency among themselves, which allowed for a robust interpretation of Holocene mire development. Throughout the ~7800 years history of the mire, there was a high level of surface wetness. The presence of mineral matter in the peat between 7800 and 5100 cal. a BP indicates regular flooding caused by the intensive fluvial activity, apparently resulting from increased precipitation. This was followed by a trend towards a gradual decrease in surface wetness from conditions of high surface moisture (stagnant water) between 5100 and 3000 cal. a BP to present day conditions of moderate surface moisture with a water table slightly below the mire surface. This pattern is consistent with the well-documented long-term trend from palaeoecological records throughout the taiga and arctic zones in West Siberia and central arid Asia. Our data further support the idea that the westerlies were the dominant driver of climate for the southern taiga of West Siberia during the Middle to Late Holocene.  相似文献   

Validation of a limited area model over Dome C, Antarctic Plateau, during winter     

Hubert Gallée  Irina V. Gorodetskaya 《Climate Dynamics》2010,34(1):61-72

The limited area model MAR (Modèle Atmosphérique Régional) is validated over the Antarctic Plateau for the period 2004–2006, focussing on Dome C during the cold season. MAR simulations are made by initializing the model once and by forcing it through its lateral and top boundaries by the ECMWF operational analyses. Model outputs compare favourably with observations from automatic weather station (AWS), radiometers and atmospheric soundings. MAR is able to simulate the succession of cold and warm events which occur at Dome C during winter. Larger longwave downwelling fluxes (LWD) are responsible for higher surface air temperatures and weaker surface inversions during winter. Warm events are better simulated when the small Antarctic precipitating snow particles are taken into account in radiative transfer computations. MAR stratosphere cools during the cold season, with the coldest temperatures occurring in conjunction with warm events at the surface. The decrease of saturation specific humidity associated with these coldest temperatures is responsible for the formation of polar stratospheric clouds (PSCs) especially in August-September. PSCs then contribute to the surface warming by increasing the surface downwelling longwave flux.  相似文献   

Dynamic topography of the East European craton: Shedding light upon lithospheric structure, composition and mantle dynamics     

Irina M. Artemieva   《Global and Planetary Change》2007,58(1-4):411

Most of the East European Craton lacks surface relief; however, the amplitude of topography at the top of the basement exceeds 20 km, the amplitude of topography undulations at the crustal base reaches almost 30 km with an amazing amplitude of ca. 50 km in variation in the thickness of the crystalline crust, and the amplitude of topography variations at the lithosphere–asthenosphere boundary exceeds 200 km. This paper examines the relative contributions of the crust, the subcrustal lithosphere, and the dynamic support of the sublithospheric mantle to maintain surface topography, using regional seismic data on the structure of the crystalline crust and the sedimentary cover, and thermal and large-scale P- and S-wave seismic tomography data on the structure of the lithospheric mantle. For the Precambrian lithosphere, an analysis of Vp/Vs ratio at 100, 150, 200, and 250 km depths does not show any age-dependence, suggesting that while Vp/Vs ratio can be effectively used to outline the cratonic margins, it is not sensitive to compositional variations within the cratonic lithosphere.Statistical analysis of age-dependence of velocity, density, and thermal structure of the continental crust and subcrustal lithosphere in the study area (0–62E, 45–72N) allows to link lithospheric structure with the tectonic evolution of the region since the Archean. Crustal thickness decreases systematically with age from 42–44 km in regions older than 1.6 Ga to 37–40 km in the Paleozoic–Mesoproterozoic structures, and to ca. 31 km in the Meso-Cenozoic regions. However, the isostatic contribution of the crust to the surface topography of the East European Craton is almost independent of age (ca. 4.5 km) due to an interplay of age-dependent crustal and sedimentary thicknesses and lithospheric temperatures.On the contrary, the contribution of the subcrustal lithosphere to the surface topography strongly depends on the age, being slightly positive (+ 0.3 + 0.7 km) for the regions older than 1.6 Ga and negative (− 0.5–1 km) for younger structures. This leads to age-dependent variations in the residual topography, i.e. the topography which cannot be explained by the assumed thermal and density structure of the lithosphere, and which can (at least partly) originate from the dynamic component caused by the mantle flow. Positive dynamic topography at the cratonic margins, which exceeds 2 km in the Norwegian Caledonides and in the Urals, clearly links their on-going uplift with deep mantle processes. Negative residual topography beneath the Archean-Paleoproterozoic cratons (− 1–2 km) indicates either a smaller density deficit (ca. 0.9%) in their subcrustal lithosphere than predicted by global petrologic data on mantle-derived xenoliths or the presence of a strong convective downwelling in the mantle. Such mantle downflows can effectively divert heat from the lithospheric base, leading to a long-term survival of the Archean-Paleoproterozoic lithosphere.  相似文献   

Limitations and innovations in the control of environmental impacts from petroleum industry activities in the Arctic     

F.R. Engelhardt 《Marine pollution bulletin》1994,29(6-12):334-341

Exploitation of petroleum reserves in polar regions involves exploration, field development, production and transportation, all of which have a potential for impact on the arctic environment and its people. The magnitude of such impact depends greatly on specific geographic circumstances, and also on the application of innovative approaches to create an operating environment that maximizes both safety and environmental mitigation. The overall issues are complex from industrial, environmental and societal perspectives.

The impact of the petroleum industry in Arctic environments is discussed in relation to a number of different activities. In general, the issues are categorized as those associated with routine activities (for example, seismic surveys, transportation, drilling and production discharges) and accidental events, in particular oil spills. While it is possible to state that the severity of impact is generally related to the size of a spill, it is not possible to be categorical about this in that site-specific variables are of great importance.  相似文献   

Inorganic matter in coal: Yakov E. Yudovich and Marina P. Ketris, Russian Academy of Science, Ural Division, Ekaterinburg, 2002, 422 pp. (in Russian).     

Irina Galuskina 《International Journal of Coal Geology》2004,58(4):269-270

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Impact of Air Transport on Seasonal Variations and Trends of Surface Ozone at Kislovodsk High Mountain Station     

Oksana A. Tarasova  Nicolai F. Elansky  Gennady I. Kuznetsov  Irina N. Kuznetsova  Irina A. Senik 《Journal of Atmospheric Chemistry》2003,45(3):245-259

The impact of air transport on the surface ozone variations is analyzed at Kislovodsk High Mountain Station for the period 1989–1996 on the basis of 2D back trajectories. It was shown that the contribution of photochemical and dynamical processes is different for the different seasons. In summer months the surface ozone concentration is governed by photochemical ozone production in semi polluted air from the regions of Northern Caspian, Southern Ural and Volga region. Time of the seasonal ozone maximum appearance is defined by joint influence of the processes of photochemical production and destruction in the eastern sectors and advection from Ukraine and Central Europe. The value of the seasonal minimum is determined by the processes of ozone destruction in the air coming from northeastern direction in the stable frontal zone. Distribution of sectors of the air transport changes from year to year and it can partly explain strong negative trend of the surface ozone concentration at the site.  相似文献   

Seismic anisotropy and mantle creep in young orogens   总被引：9，自引：0，他引：9  

Rolf Meissner  Walter D. Mooney  Irina Artemieva 《Geophysical Journal International》2002,149(1):1-14

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Combination of long time-series of troposphere zenith delays observed by VLBI   总被引：1，自引：0，他引：1  

R. Heinkelmann  J. Boehm  H. Schuh  S. Bolotin  G. Engelhardt  D. S. MacMillan  M. Negusini  E. Skurikhina  V. Tesmer  O. Titov 《Journal of Geodesy》2007,81(6-8):483-501

Within the International Very Long Baseline Interferometry (VLBI) Service for Geodesy and Astrometry (IVS), long time-series of zenith wet and total troposphere delays have been combined at the level of parameter estimates. The data sets were submitted by eight IVS Analysis Centers (ACs) and cover January 1984 to December 2004. In this paper, the combination method is presented and the time-series submitted by the eight IVS ACs are compared with each other. The combined zenith delays are compared with time-series provided by the International Global Navigation Satellite System (GNSS) Service (IGS), and with zenith delays derived from the European Centre for Medium-Range Weather Forecasts (ECMWF). Before the combination, outliers are eliminated from the individual time-series using the robust BIBER (bounded influence by standardized residuals) estimator. For each station and AC, relative weight factors are obtained by variance component estimation. The mean bias of the IVS ACs’ time-series with respect to the IVS combined time-series is 0.89 mm and the mean root mean square is 7.67 mm. Small differences between stations and ACs can be found, which are due to the inhomogeneous analysis options, different parameterizations, and different treatment of missing in-situ pressure records. Compared to the IGS zenith total delays, the combined IVS series show small positive mean biases and different long-term trends. Zenith wet delays from the ECMWF are used to validate the IVS combined series. Inconsistencies, e.g., long-term inhomogeneity of the in-situ pressure data used for the determination of VLBI zenith delays, are identified.  相似文献   

Coastal cooling/heating events: Laboratory experiments     

Natalia Demchenko  Irina Chubarenko 《Acta Geophysica》2007,55(1):56-64

We report the results of laboratory experiments on water heating/cooling, performed in 5 m long water channel with a slope. About 63 series of photos were analyzed: for 3 locations, for 3 bottom slopes (3.7, 6.7 and 12 degrees) and for different Ra numbers. It was pointed out that there exist two types of mixing characterizing different circulations in the presence of slope: gravity current and undersurface jet; the thermal bar is the region where one type of mixing is replaced by another; the highest speed and flowrate are at the break point; the flow is three-dimensional.  相似文献