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41.
The extreme depletion of the Earth’s mantle in sulfur is commonly seen as a signature of metal segregation from Earth’s mantle to Earth’s core. However, in addition to S, the mantle contains other elements as volatile as S that are hardly depleted relative to the lithophile volatility trend although they are potentially as siderophile as sulfur. We report experiments in metal-sulfide–silicate systems to show that the CI normalized abundances of S, Pb, and Sn in Earth’s mantle cannot be reproduced by element partitioning in Fe ± S–silicate systems, neither at low nor at high pressure. Much of the volatile inventory of the Earth’s mantle must have been added late in the accretion history, when metal melt segregation to the core had become largely inactive. The great depletion in S is attributed to the selective segregation of a late sulfide matte from an oxidized and largely crystalline mantle. Apparently, the volatile abundances of Earth’s mantle are not in redox equilibrium with Earth’s core.  相似文献   
42.
43.
A reversed‐phase fractionation method with subsequent biological and chemical analysis has been developed to estimate the contributions of the most potent estrogens to observed estrogenic effect potentials. Surface water samples were taken in the German Baltic Sea (Inner Wismar Bay and Darss Peninsula, sampling campaign July 2003) and were separated into seven individual fractions. Three fractions showed significant estrogenic activities and clear dose‐dependant responses were obtained in the yeast estrogen screen (YES). In the 2nd fractions liquid chromatographic‐electrospray‐tandem mass spectrometric (LC‐ESI‐MS‐MS) analyses showed the presence of bisphenol A (Inner Wismar Bay: 4.8 ng L–1 and 6 ng L–1; Darss Peninsula: 0.91 ng L–1 and 1.7 ng L–1) and ethinylestradiol (Inner Wismar Bay: 2.0 ng L–1 and 6.0 ng L–1; Darss Peninsula: < MDL and 1.7 ng L–1), whereas estrogenic activities in the YES were only around 10% of the positive control E2. Although not identified prior in the total extract the natural hormones estradiol (Inner Wismar Bay: 0.13 ng L–1 and 0.19 ng L–1; Darss Peninsula: 0.12 ng L–1 and 0.16 ng L–1) and estriol (Inner Wismar Bay: < MDL and 0.33 ng L–1; Darss Peninsula: < MDL) could be detected in the 3rd fractions, where high estrogenic potentials could be observed. The 4th fractions showed high responses as well and estrone were herein quantified with concentrations of 0.16 ng L–1 and 0.18 ng L–1 (Darss Peninsula) up to 0.37 ng L–1 (Inner Wismar Bay). Measured and calculated estradiol equivalents for individual fractions correlated very well (R2 = 0.78), when disregarding results of the 2nd fraction, where high deviations occurred.  相似文献   
44.
This paper unravels a variety of perspectives about the concept of social mix, drawing on a case study of the implementation of a redevelopment project in Melbourne. The first part provides a theoretical overview of two internationally predominant academic debates around policy interpretations of this concept, namely social mix as a means for promotion of social inclusion; and as a state-led form of gentrification. These two arguments are usually presented as one, with social inclusion and reductions of concentrations of disadvantage one side of the ‘social mix policy’ coin, and state-led gentrification the other. This paper contributes to the national and international literature on public housing estate regeneration and social mix policies through exploring the question of whether these two ideas about social mix were shared by different stakeholders as the ‘messy’ process of redevelopment unfurled. Interviews were conducted with public tenants, homeowners and homebuyers, private renters and local service providers at the Carlton Housing Estate to explore the diverse perspectives of various stakeholder groups as estate design and implementation shifted. The study identified that as a result of the global financial crisis and the developers exerting pressure on government there was a gradual move away from perceiving social mix as a policy tool for encouraging social inclusion at Carlton, between public housing tenants and private residents, towards a different form of social mix and inclusion. Contrary to intentions, the revised form of social mix at Carlton was perceived as a means to harness market capital and attract higher income residents to the inner city.  相似文献   
45.
In this study male largemouth bass (LMB) were exposed to the naturally occurring androgens, dihydrotestosterone (DHT) or 11-ketotestosterone (11-KT) in order to identify genes that are differentially regulated by these steroid hormones. Using subtractive hybridization on livers of fish treated with DHT against vehicle control, many novel LMB genes were cloned. These genes were added to our gene library and arrayed. Six genes were up-regulated and five were down-regulated by both androgens. But, each androgen also regulated specific genes. One gene that was identified as a potential androgen marker was spermidine-spermine-N1-acetyltransferase that was up-regulated by both androgens. Determining which genes are responsive to natural androgens will help to identify biochemical pathways that are impacted.  相似文献   
46.
In Europe the process of agricultural engagement or disengagement is attributed to the economic factor and mainly on the level of alternative employment source development. It is the relational quality of economic, social and environmental factors that determine sustainability of agricultural holdings and, hence, households. In regions of poor agricultural structures and of many employment opportunities as well as in regions suffering from agricultural depression, households exhibit stronger tendencies towards agricultural disengagement. Remarkably in southern Europe a stable agricultural engagement and not disengagement is observed, even though in recent years there are limited possibilities of alternative income sources and prevailing agricultural depression. This article highlights the factors which lead households to stable engagement with agriculture in a region of southern Europe, the island of Lesvos. The island is characterised by traditional olive grove mono-culture, poor agricultural structures and limited employment opportunities. The investigation of the economic, social and environmental farm household characteristics concluded that in regions where poor agricultural infrastructure and lack of employment prevail, all three factors of sustainability contribute to stability and/or low agricultural disengagement. Among these, the economic factor is the most sensitive and hence highly influential. The social factor is highlighted as a quality and consistent factor due to the respect for tradition. The environmental factor, finally, is characterised by mild cultivation practices, contributing to environment conservation.  相似文献   
47.
An analysis of the hydrological effects of vegetation changes in the Columbia River basin over the last century was performed using two land cover scenarios. The first was a reconstruction of historical land cover vegetation, c. 1900, as estimated by the federal Interior Columbia Basin Ecosystem Management Project (ICBEMP). The second was current land cover as estimated from remote sensing data for 1990. Simulations were performed using the variable infiltration capacity (VIC) hydrological model, applied at one‐quarter degree spatial resolution (approximately 500 km2 grid cell area) using hydrometeorological data for a 10 year period starting in 1979, and the 1900 and current vegetation scenarios. The model represents surface hydrological fluxes and state variables, including snow accumulation and ablation, evapotranspiration, soil moisture and runoff production. Simulated daily hydrographs of naturalized streamflow (reservoir effects removed) were aggregated to monthly totals and compared for nine selected sub‐basins. The results show that, hydrologically, the most important vegetation‐related change has been a general tendency towards decreased vegetation maturity in the forested areas of the basin. This general trend represents a balance between the effects of logging and fire suppression. In those areas where forest maturity has been reduced as a result of logging, wintertime maximum snow accumulations, and hence snow available for runoff during the spring melt season, have tended to increase, and evapotranspiration has decreased. The reverse has occurred in areas where fire suppression has tended to increase vegetation maturity, although the logging effect appears to dominate for most of the sub‐basins evaluated. Predicted streamflow changes were largest in the Mica and Corralin sub‐basins in the northern and eastern headwaters region; in the Priest Rapids sub‐basin, which drains the east slopes of the Cascade Mountains; and in the Ice Harbor sub‐basin, which receives flows primarily from the Salmon and Clearwater Rivers of Idaho and western Montana. For these sub‐basins, annual average increases in runoff ranged from 4·2 to 10·7% and decreases in evapotranspiration ranged from 3·1 to 12·1%. In comparison with previous studies of individual, smaller sized watersheds, the modelling approach used in this study provides predictions of hydrological fluxes that are spatially continuous throughout the interior Columbia River basin. It thus provides a broad‐scale framework for assessing the vulnerability of watersheds to altered streamflow regimes attributable to changes in land cover that occur over large geographical areas and long time‐frames. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   
48.
Ten years (1985–1994) of data were analyzed to investigate general patterns of phytoplankton and nutrient dynamics, and to identify major factors controlling those dynamics in the York River Estuary, Virginia. Algal blooms were observed during winter-spring followed by smaller summer blooms. Peak phytoplankton biomass during the winter-spring blooms occurred in the mid reach of the mesohaline zone whereas peak phytoplankton biomass during the summer bloom occurred in the tidal fresh-mesohaline transition zone. River discharge appears to be the major factor controlling the location and timing of the winter-spring blooms and the relative degree of potential N and P limitation. Phytoplankton biomass in tidal fresh water regions was limited by high flushing rates. Water residence time was less than cell doubling time during high flow seasons. Positive correlations between PAR at 1 m depth and chlorophylla suggested light limitation of phytoplankton in the tidal fresh-mesohaline transition zone. Relationships of salinity difference between surface and bottom water with chlorophylla distribution suggested the importance of tidal mixing for phytoplankton dynamics in the mesohaline zone. Accumulation of phytoplankton biomass in the mesohaline zone was generally controlled by N with the nutrient supply provided by benthic or bottom water remineralization.  相似文献   
49.
The degree to which the climate change signal can be seen in the increasing frequency and/or magnitude of extreme events forms a key part of the global environmental change agenda. Geomorphology engages with this debate through extending the instrumental record with palaeogeomorphological research; studying resilience and recovery of geomorphic systems under extreme disturbance; documenting the mediation by catchment organisation of transport processes during extreme events; applying new monitoring methods to better understand process‐response systems; and illustrating how process, experimental and modelling insights can be used to define the buffering of geomorphic systems and human assets from the effects of extremes, providing practical outcomes for practitioners. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
50.
Planning and design of coastal protection rely on information about the probabilities of very severe storm tides and the possible changes that may occur in the course of climate change. So far, this information is mostly provided in the form of high percentiles obtained from frequency distributions or return values. More detailed information and assessments of events that may cause extreme damages or have extreme consequences at the coast are so far still unavailable. We describe and compare two different approaches that may be used to identify highly unlikely but still physically possible and plausible events from model simulations. Firstly, in the case when consistent wind and tide-surge data are available, different metrics such as the height of the storm surge can be derived directly from the simulated water levels. Secondly, in cases where only atmospheric data are available, the so called effective wind may be used. The latter is the projection of the horizontal wind vector on that direction which is most effective in producing surges at the coast. Comparison of events identified by both methods show that they can identify extreme events but that knowledge of the effective wind alone does not provide sufficient information to identify the highest storm surges. Tracks of the low-pressure systems over the North Sea need to be investigated to find those cases, where the duration of the high wind is too short to induce extreme storm tides. On the other hand, factors such as external surges or variability in mean sea level may enhance surge heights and are not accounted for in estimates based on effective winds only. Results from the analysis of an extended data set suggest that unprecedented storm surges at the German North Sea coast are possible even without taking effects from rising mean sea level into account. The work presented is part of the ongoing project “Extreme North Sea Storm Surges and Their Consequences” (EXTREMENESS) and represents the first step towards an impact assessment for very severe storm surges which will serve as a basis for development of adaptation options and evaluation criteria.  相似文献   
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