Rare Earth Elements in Egyptian Phosphorites     

I.S.ISMAEL 《中国地球化学学报》2002,21(1):19-28

Egyptian phosphorites from Abu Tartur(Western Desert),El Mahamide mine(Nile Valley) and Rabah mne(Eastern Desert)show variable degrees of relative REE enrichment.Black plateau phosphorites of Abu Tartur are substantially enriched in REE as compared to the Red Sea and Nile Valley phosphorites.P-rich organic matter from the Abu Tartur and Rabah mines recorded negative Ce and positive Eu anomalies.Positive Eu anomaly reveals an anoxic event prior to the phase of Late Cretaceous phosphate formation.Ce is a redox indicator.Mixing of sea water and upwelling during the Late Cretaceous was responsible for the recording of positive Eu and negative Ce anomalies in the Egyptian phosphorites.  相似文献   

The interplay between deformation,erosion and sedimentation in the deep‐water Mexican Ridges foldbelt,western Gulf of Mexico basin          下载免费PDF全文

Ismael Yarbuh  Juan Contreras 《Basin Research》2017,29(Z1):446-464

We analyse a regional 2D seismic section of the Mexican Ridges foldbelt (MRFB), western Gulf of Mexico, and construct excess‐area diagrams for each of the structures comprising the foldbelt to estimate shortening, the onset of folding and the degradation of the folded seafloor. From the chronostratigraphy, we derive rates of tectonic and superficial mass transport and illustrate how they change across the MRFB. The resulting tectonic transport in the MRFB is 11.8 km forming a train of twelve buckle folds above a detachment at a depth of ca. 6 s of two‐way travel time, with an average strain of ca. 10%. The fold train grew at a mean uplift rate of ca. 0.21 mm year^?1. Cross‐sectional balancing demonstrates that shortening balances the down‐slip motion of the Quetzalcoatl extensional system (QES), suggesting that horizontal compaction, volume loss and other penetrative deformation mechanisms are negligible. By assuming steady‐state denudation, we are able to distinguish sediments derived locally from sediments transported from distant sources. The constant of mass diffusivity, a parameter controlling the degradation rate, is ca. 0.42 m² year ^?1, which is characteristic of rapid, episodic, superficial mass movements. The combined sedimentation rate from both, local and distal sources is ca. 0.23 mm year ^?1. Those values are not constant; structures proximal to the continental shelf are rising rapidly and are being degraded more intensely than those in the distal part of the MRFB, where sedimentation outweighs tectonic uplift. Our results indicate deformation initiated up to 3 Myr earlier than estimated from stacking patterns. Moreover, we find deformation started synchronously during the Late Miocene throughout the MRFB and not in two episodes as the stacking relations suggest. The discrepancy can be explained by a delay in the sedimentary response to folding. During early fold growth, nearly constant thickness strata are deposited before a progressive unconformity and other converging geometries develop. The development of growth strata is fast in the folds near the QES, which are being uplifted rapidly and degraded vigorously. Under these conditions, the stratigraphic relations give only a broad estimate of the pretectonic/syntectonic limit when compared to the excess‐area method. On the other hand, the development of growth strata took twice as much time for folds near the abyssal plain, which are being uplifted at a slower rate and where degradation is less intense. Consequently, the delay takes more time, and the use of stratigraphic relations introduces an even more pronounced bias towards younger ages in the identification of the onset of folding.  相似文献   

Generation of evenly-spaced pressure-solution seams during (late) diagenesis: A kinetic theory     

Enrique Merino  Peter Ortoleva  Peter Strickholm 《Contributions to Mineralogy and Petrology》1983,82(4):360-370

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Internal consistency of a water analysis and uncertainty of the calculated distribution of aqueous species at 25°C     

Enrique Merino 《Geochimica et cosmochimica acta》1979,43(9):1533-1542

Many water analyses contain more than the minimum number of analytical determinations needed to calculate the distribution of species at ~ 25°C. The speciation of a water that contains $\text{n}$ cations and ligands other than H⁺ and OH^? can be calculated if just $\text{n}$ analytical determinations are available. In the frequent case where $\text{n + 1}$ (or more) determinations are available, one can calculate from the speciation a value for the ($\text{n + 1}$)th variable. The comparison between this computed value and its analytical counterpart (not used in calculating the speciation) constitutes a test for internal consistency among the $\text{n + 1}$ determinations that make up the whole analysis.Application of this test requires knowing the uncertainties of the calculated speciation and of the value computed for the ($\text{n + 1}$)th variable from the speciation. Such uncertainties have been ignored in previous algorithms, but have been determined herein by a Monte Carlo method of error propagation which is very well suited to systems of nonlinear algebraic equations.By comparing the titration alkalinity against the alkalinity calculated from the speciation, several published analyses for which the cation/anion balance is < 3% can be shown to be internally inconsistent. Such analyses may be unsuitable for geochemical calculations (water/rock interaction, estimation of reservoir temperatures, etc.).Several existing speciation algorithms disregard the possibility that the analytical data used as input are internally inconsistent.  相似文献   

A critical discussion of numerical models for multiaquifer systems     

Ismael Herrera  Jean Pierre Hennart  Robert Yates 《Advances in water resources》1980,3(4):159-163

Leaky aquifers constitute complicated hydrological structures, whose inclusion in numerical models of hydrological systems is difficult, because of their three-dimensional nature. Methods for treating such systems can be classified as fully three-dimensional and quasi-three-dimensional. The latter have clear numerical advantages when applicable. In this paper a critical discussion of existing quasi-three-dimensional models is presented.  相似文献   

Temporal development of fabric in uniaxially stressed polycrystalline media—A theory     

Enrique Merino  Peter Ortoleva 《Contributions to Mineralogy and Petrology》1980,71(4):429-435

We present a kinetic theory for the development of lattice-preferred orientation in a uniaxiallystressed aggregate consisting of elastically uniaxial crystals. The fabric is brought about by grain-boundary migration alone; other fabric-producing mechanisms, such as plastic deformation, syntectonic recrystallization, and dissolution/reprecipitation, are specifically excluded from the theory. The formulation statistically averages the mass transfer between a typical crystal and its adjacent neighbors over all the possible crystallographic orientations of these neighbors and over all the possible orientations of the interfaces between the neighbors and the crystal of interest. The rate of mass exchange between two adjacent crystals is proportional (1) to the difference between chemical potentials and (2) to the surface area common to them. With these assumptions we find an equation for the massfraction density of crystals that have a given orientation (with respect to the stress) at any given time. The theory predicts that beyond a certain time a gap develops in the distribution of crystal orientations allowed: the only crystals that continue to exist are those for which the c-axis is within a certain, timedependent range about the stress.  相似文献   

Hydrodynamic behaviour of compacted granite sawdust from the dimension stone industry of Pontevedra (Spain): experimental and modelling     

Ismael Falcon-Suarez  Ricardo Juncosa-Rivera  Phil Vardon  Dieter Rammlmair  Thomas Günter  Ulla Noell  Jordi Delgado-Martín 《Environmental Earth Sciences》2016,75(5):421

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Facies,geometry and growth phases of the Valdorria carbonate platform (Pennsylvanian,northern Spain)   总被引：1，自引：0，他引：1       下载免费PDF全文

Valentin Chesnel  Elias Samankassou  Óscar Merino‐Tomé  Luis Pedro Fernández  Elisa Villa 《Sedimentology》2016,63(1):60-104

The 14 km wide Valdorria outcrop (Pennsylvanian, northern Spain) is one of the few examples of entirely exposed flat‐topped and high‐relief carbonate platforms reported in the fossil rock record. Laterally and vertically traceable stratal patterns expose three phases of growth. Phase I is a 430 m thick platform to slope succession that prograded over 6 km, and is dated as Early Bashkirian (Akavasian–Askynbashian). Phase II aggraded and prograded, exhibiting 180 m thickness of cyclical platform top deposits, dated as Late Bashkirian (Asatauian). Phase III is a mound‐shape structure that developed over the platform top of Phase II as a new phase of platform nucleation. It is 535 m thick and 2 km wide, and dated as Late Bashkirian (Asatauian–Transition interval). The observed changes of growth styles during platform evolution, from a prograding to an aggrading–prograding system, and a rapid aggradational phase, are inferred to be controlled by flexural subsidence in the active Cantabrian foreland basin, at the Variscan orogenic front. The metre‐scale shallowing‐upward cycles of the platform top are most probably due to glacioeustasy, as evidenced by well‐recorded subaerial exposure surfaces superimposed on subtidal deposits, and by a stratal pattern recurrent in a short interval of about 160 kyr. Observations of outcropping Bashkirian cyclothems in an isolated carbonate system, devoid of siliciclastic input, are relevant for a better understanding of the impact of high‐frequency sea‐level fluctuations on the carbonate factory. Moreover, progradation of the platform margin during Phase I reaches a rate of 2500 m/Myr, and 1810 m/Myr during Phase II; rates that are high when compared to other Pennsylvanian examples. The aggradation rate of 447 m/Myr calculated for the Late Bashkirian–Transition interval (Phases II and III; uncorrected for compaction, missing beats and erosion) is uncommonly high in comparison to coeval Pennsylvanian examples. The platform exhibits a self‐nourishing prograding microbial boundstone‐dominated slope. Thus, the slope‐shedding model applies well to Valdorria. However, Phase II recorded eustatic variations able to inhibit the slope microbial boundstone factory during low sea‐level stands; this is marked by common slope red‐stained breccias synchronous to platform top subaerial exposure phases. Contrarily, periods of relative high sea‐level and rapid subsidence in Phase III registered a greater development of cemented microbial boundstone. These observed, partly opposing relationships of sea‐level stands, shedding modes and slope architecture provide an improvement of the currently used slope‐shedding model. The overall architecture of the Valdorria outcrop compares well with that of other contemporaneous platforms, such as Sierra del Cuera and Bolshoi Karatau. Valdorria shares the high‐relief and flat‐topped, steep slopes, cyclothemic patterns and occurrence of karst features with the Pricaspian Basin platforms (Tengiz, Karachaganak and Kashagan), with minor variations in facies distribution of the internal platform. Furthermore, the continuous seismic‐scale outcrop of Valdorria, together with its isolated setting and asymmetrical growth, makes it a very good candidate for potential subsurface analogues of hydrocarbon‐bearing systems.  相似文献   

Variations in turbulent kinetic energy at a point source submarine groundwater discharge in a reef lagoon     

Sabrina M. Parra  Ismael Mariño-Tapia  Cecilia Enriquez  Arnoldo Valle-Levinson 《Ocean Dynamics》2014,64(11):1601-1614

The influence of sea level variations due to tides and wave setup on turbulent kinetic energy (TKE) was observed at a point source submarine groundwater discharge in a fringing coral reef lagoon. Tidal and wave setup variations modulated speed, TKE, TKE dissipation, and water temperature and salinity at the buoyant jet. The primary driver of jet TKE and speed variations was tides, while wave setup was a minor contributor. An inverse relationship between surface elevation and TKE was explained with an exponential equation based on sea level variations. During low tides, peak jet speeds (up to 0.3 m s^?1) and TKE per unit mass (up to 0.4 m² s^?2) were observed. As high tide approached, the jet produced minimum TKE of ~0.003 m² s^?2 and TKE dissipation ranged from 2 to 8×10^?4 m² s^?3. This demonstrated the sensitivity of the jet discharge to tides despite the small tidal range (<20 cm). Jet temperatures and salinities displayed semidiurnal oscillations with minimum salinity and temperature values during maximum discharge. Jet salinities increased throughout low tides while temperatures decreased. This pattern suggested the jet conduit was connected to a stratified cavity within the aquifer containing cool fresh water over cool salty water. As low tides progressed, jet outflow increased in salinity because of the mixing within the conduit, while lower jet temperatures suggested water coming from further or deeper in the aquifer. The presence of such a cavity has been recently confirmed by divers.  相似文献   

Towards the implementation of an integrated ecosystem fleet-based management of European fisheries     

D. Gascuel  G. Merino  R. Döring  J.N. Druon  L. Goti  S. Guénette  C. Macher  K. Soma  M. Travers-Trolet  S. Mackinson 《Marine Policy》2012

Using the Celtic Sea and the North Sea as case studies, the fleet-based approach is shown to be the pathway to implement an effective ecosystem approach to fisheries management (EAFM) in European seas. First, a diagnostic on the health of each ecosystem is proposed based on the reconstruction of long time-series of catch, the analysis of mean indicators or stocks trajectories derived from ICES stock assessment results, and the analysis of ecosystem indicators. Then, a fleet-based synthesis is presented using indicators of both the ecological impact and the economic performances of the major fleets operating within each ecosystem. In particular, assessment diagrams show whether each fleet segment, on average, sustainably exploits the stocks. Although results are preliminary due to the poor quality of available data, the analysis shows that simple indicators can be estimated and clearly highlight contrasts between fleet segments. Such an approach contributes to the evolution from a stock-based to a fleet-based management, which reflects the ecological, economical and social pillars of the sustainable development of fisheries.  相似文献