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51.
Abstract Fifty calc-schists have been systematically collected from the Piemonte zone of the western Italian Alps and examined in terms of petrology, X-ray powder diffractometer (XRD) analysis of carbonaceous materials, and K-Ar ages of white mica separates. The petrological study and XRD analysis of carbonaceous materials have shown that calc-schists have suffered blueschist-facies metamorphism in the subduction zone of the convergent margin between the Apulian (African) continental and Tethyan oceanic plates. The metamorphic sequence is divided into three mineral zones based on increasing metamorphic temperature: chlorite (lower than 300°C), chloritoid, and rutile (higher than 450°C). The chlorite zone has dispersed ages of white mica separates, ranging from 115 to 44 Ma, whereas the rutile zone has a comparatively uniform age distribution from 60 to 40 Ma. The chloritoid zone has an intermediate age variation. The large variation in the chlorite zone is attributed to mixing of variable amounts of detrital mica derived from older high temperature metamorphic rocks in the separates, which have not been completely reset during Alpine metamorphism. The uniform age (average ca 50 Ma) in the rutile zone is the cooling age of blueschist-facies calc-schists, which have been episodically exhumed at the collision event of the European and Apulian continents in the Paleocene-Eocene.  相似文献   
52.
Abstract Elemental and isotopic compositions of noble gases extracted from the bore hole water in Osaka plain, central Japan were examined. The water samples were collected from four shallow bore holes (180-450 m) and seven deep bore holes (600-1370 m) which have been used for an urban resort hot spring zone. The water temperatures of the deep bore holes were 22-50°C and that of the shallow bore holes, 13-23°C. The elemental abundance patterns show the progressive enrichment of the heavier noble gases compared with the atmospheric noble gas composition except for He, which is heavily enriched in deep bore hole water samples. 3He/4He ratios from the bore holes reaching the Ryoke granitic basement were higher than the atmospheric value (1.4 × 10−6), indicating a release of mantle He through the basement. The highest value of 8.2 × 10−6 is in the range of arc volcanism. On the other hand, the bore holes in sedimentary rocks overlying the basement release He enriched in radiogenic 4He, resulted in a low 3He/4He ratio of 0.5 × 10−6. 4He/20Ne and 40Ar/36Ar ratios indicate that the air contamination is generally larger in shallow bore holes than in deep ones from each site. The helium enriched in mantle He is compatible with the previous work which suggested up-rising magma in 'Kinki Spot', the area of Osaka and western Wakayama, in spite of no volcanic activity in the area. A model to explain an initiation of magma generation beneath this area is presented.  相似文献   
53.
Metamorphic rocks experience change in the mode of deformation from ductile flow to brittle failure during their exhumation. We investigated the spatial variation of phengite K–Ar ages of pelitic schist of the Sambagawa metamorphic rocks (sensu lato) from the Saruta River area, central Shikoku, to evaluate if those ages are disturbed by faults or not. As a result, we found that these ages change by ca 5 my across the two boundaries between the lower‐garnet and albite–biotite, and the albite–biotite and upper‐garnet zones. These spatial changes in phengite K–Ar ages were perhaps caused by truncation of the metamorphic layers by large‐scale normal faulting at D2 phase under the brittle‐ductile transition conditions (ca 300°C) during exhumation, because an actinolite rock was formed along a fault near the former boundary. Assuming that the horizontal metamorphic layers and a previously estimated exhumation rate of 1 km/my before the D2 phase, the change of 5 my in phengite K–Ar ages is converted to a displacement of about 10 km along the north‐dipping, low‐angle normal fault documented in the previous study. Phengite 40Ar–39Ar ages (ca 85 to 78 Ma) in the actinolite rock could be reasonably comparable to the phengite K–Ar ages of the surrounding non‐faulted pelitic schist, because the K–Ar ages of pelitic schist could have been also reset at temperatures close to the brittle–ductile transition conditions far below the closure temperature for thermal retention of argon in phengite (about 500–600°C).  相似文献   
54.
55.
Tetsumaru Itaya 《Lithos》1981,14(3):215-224
Carbonaceous material in pelitic schists of the Sanbagawa metamorphic belt in central Shikoku, Japan, was separated from the host rocks and its X-ray diffraction and chemical composition were studied. Its crystal structure and chemistry change continously with increasing metamorphic grade and approach those of well-ordered graphite near the biotite isograd. As graphitization is a rate process, the temperature of complete graphitization differs from one metamorphic terrain to another as a function of the duration of metamorphism. In an individual metamorphic terraan, however, the degree of graphitization is a useful indicator of relative metamorphic temperature in lower-grade rocks.  相似文献   
56.
The Sanbagawa high-pressure schists from central Shikoku in Southwest Japan have experienced high-strain ductile deformation during exhumation and cooling. This study examines the effects of high-strain ductile deformation on K–Ar ages of phengites on the basis of fabric, chemistry and K–Ar ages of phengites from the pelitic, psammitic and quartzose (or albitic) schists collected from the same outcrop in the albite–biotite zone. Phengites in the pelitic and psammitic schists generally occur forming aggregates consisting of fine-grained phengite crystals and are extremely fine-grained in domains close to relatively rigid garnet and albite porphyroblasts, indicating that deformation-induced grain-size reduction had taken place in phengite during the ductile deformation accompanying the exhumation of host schists. We suggest that the grain-size reduction of phengite is due to strain-induced recrystallization or dynamic recrystallization. The matrix phengites in schists are chemically heterogeneous on the thin-section scale but the phengites from pelitic and psammitic schists from the same outcrop have similar chemical range. Phengite included in garnet has a high Si value and its Na/(Na + K) and Mg/(Mg + Fe) ratios are significantly low in comparison with those in matrix. The phengite included in garnet records the chemistry in equilibrium with other major silicate phases during the higher pressure stage of the P–T–t history of the schists. In contrast, the matrix phengites having low Si values are likely to have been formed during retrograde metamorphism in extremely restricted equilibrium domains. The two or three different types of schists from the same outcrop, which have a similar grain size of phengite, have similar K–Ar ages, suggesting that the closure temperature does not depend on chemistry. However, the hematite-rich quartzose schist with strong grain-size reduction of both phengite and quartz has a significantly younger K–Ar phengite age than the pelitic and quartzose schists in the same outcrop that do not show grain-size reduction. We suggest that the exhumation tectonics of the schists, which have experienced strong ductile deformation at temperatures less than ~350°C, played an important role resulting in the observed variation in age.  相似文献   
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