Lipid distribution in a subtropical southern China stalagmite as a record of soil ecosystem response to paleoclimate change   总被引：3，自引：0，他引：3  

Shucheng Xie  Yi Yi  Junhua Huang  Chaoyong Hu  Yanjun Cai  Matthew Collins  Andy Baker 《Quaternary Research》2003,60(3):340-347

Lipid extracts from a 61.7-cm-long subtropical stalagmite in southern China, spanning the period of ca. 10,000–21,000 yr ago as constrained by U–Th dating, were analyzed using gas chromatography–mass spectrometry. The higher plants and microorganisms in the overlying soils contribute a proportion of n-alkanes identified in the stalagmite. The occurrence of LMW (lower molecular weight) n-alkanols and n-alkan-2-ones in the stalagmite was mainly related to the soil microorganisms. We suggest that HMW (higher molecular weight) n-alkanols and n-alkan-2-ones identified in the stalagmite originate from soil organics and reflect input from contemporary vegetation. Shifts in the ratio of LMW to HMW n-alkanols or n-alkan-2-ones indicative of the variation of soil ecosystems (e.g., microbial degradation of organic matter and/or the relative abundance of soil microorganisms to higher plants) are comparable with the subtropical alkenone-SST (sea surface temperature) record of the same period. The similar trends seen in the δ¹³C data and the lipid parameters in this stalagmite imply that the overlying soil ecosystem response to climate might be responsible for the variation of δ¹³C values.  相似文献   

Historical novels and historical geography     

Alan R H Baker 《Area》1997,29(3):269-273

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Kinetics of the Gas-Phase Reactions of OH Radicals, NO3 Radicals and O3 with Three C7-Carbonyls Formed From The Atmospheric Reactions of Myrcene, Ocimene and Terpinolene     

Jillian Baker  Janet Arey  Roger Atkinson 《Journal of Atmospheric Chemistry》2004,48(3):241-260

Rate constants for the gas-phase reactions of OH radicals, NO₃ radicals and O₃ with the C₇-carbonyl compounds 4-methylenehex-5-enal [CH₂=CHC(=CH₂)CH₂CH₂CHO], (3Z)- and (3E)-4-methylhexa-3,5-dienal [CH₂=CHC(CH₃)=CHCH₂CHO] and 4-methylcyclohex-3-en-1-one, which are products of the atmospheric degradations of myrcene, Z- and E-ocimene and terpinolene, respectively, have been measured at 296 ± 2 K and atmospheric pressure of air using relative rate methods. The rate constants obtained (in cm³ molecule^–1 s^–1 units) were: for 4-methylenehex-5-enal, (1.55 ± 0.15) × 10^–10, (4.75 ± 0.35) × 10^–13 and (1.46 ± 0.12) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; for (3Z)-4-methylhexa-3,5-dienal: (1.61 ± 0.35) × 10^–10, (2.17 ± 0.30) × 10^–12, and (4.13 ± 0.81) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; for (3E)-4-methylhexa-3,5-dienal: (2.52 ± 0.65) × 10^–10, (1.75 ± 0.27) × 10^–12, and (5.36 ± 0.28) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; and for 4-methylcyclohex-3-en-1-one: (1.10 ± 0.19) × 10^–10, (1.81 ± 0.35) × 10^–12, and (6.98 ± 0.40) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively. These carbonyl compounds are all reactive in the troposphere, with daytime reaction with the OH radical and nighttime reaction with the NO₃ radical being predicted to dominate as loss processes and with estimated lifetimes of about an hour or less.  相似文献   

Transfer of Taiwanese ideas and technology to The Gambia, West Africa: a viable approach to rural development?   总被引：1，自引：0，他引：1  

Kathleen M Baker  Richard Louis Edmonds 《The Geographical journal》2004,170(3):189-211

The development of Taiwan's agricultural sector contributed significantly to the country's transformation from virtual poverty after World War II to a modern industrial nation. Success resulted from the use of appropriate technologies, developed through an exceptionally close working relationship between government, research and development institutions, extension services and farmers in Taiwan. As part of their overseas development aid programme, the Republic of China on Taiwan has established Technical Missions in those developing countries where it receives political recognition. Among these is The Gambia, West Africa, where one focus of Taiwan's current Technical Mission is the development of women's market gardens. Although the gardens have proved successful, there is doubt as to whether their achievements will be sustained once Taiwan's Technical Mission in The Gambia has ended. Field research in Taiwan and in The Gambia, based largely on participatory techniques, has revealed that the low-tech methods introduced from Taiwan are appropriate for the Gambian environment. However, much depends on whether women participating in the schemes can commit sufficient time and energy to the gardens, as at present this is a limiting factor. The potential of the gardens may also be constrained by a lack of appropriate institutional infrastructure, particularly the scope for profitable disposal of garden produce. A major conclusion of the article is that successful transfer of appropriate technology to The Gambia is likely to be impeded by poorly developed coordination between groups that proved to be key 'players' in the development of agriculture in Taiwan: government, research and development institutions, extension services and producers.  相似文献   

The geoid EDIN2000 and mean sea surface topography around the British Isles   总被引：2，自引：0，他引：2  

Roger Hipkin  Keith Haines  Ciaran Beggan  Richard Bingley  Fabrice Hernandez  Jason Holt  Trevor Baker 《Geophysical Journal International》2004,157(2):565-577

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Internet‐Based GIS Mapping in Support of K‐12 Education     

Thomas R. Baker 《The Professional geographer》2005,57(1):44-50

Internet‐based mapping provides a powerful alternative for successfully establishing GIS technology in the K‐12 education community, while simultaneously avoiding the traditional barriers associated with desktop GIS. Internet‐based GIS can support standards‐based inquiry methods of teaching and learning while providing basic analysis tools for studying and exploring geographic or scientific data in the classroom.  相似文献   

Comparison of the effects of unidirectional and sign‐alternating temperature gradients on the sintering of ice spheres          下载免费PDF全文

Xuan Wang  Ian Baker 《水文研究》2017,31(4):871-879

To simplify the complex snow structures that occur in nature, polycrystalline ice spheres were produced and arranged vertically to model the sintering process. By controlling the temperatures on both the top and bottom of the ice sphere array, the effect of upward and downward vapor transfers was examined. The evolution of the neck areas between ice spheres was observed using X‐ray computed microtomography. As frequently observed under the basal part of a snow layer and previous experiments of snow temperature gradient metamorphism, depth hoar structures were formed along neck areas and their formation was found to be directly related to the vapor transfer direction. To model the temperature gradient inversion that can be induced in nature by daily cycles of radiative heating and cooling, we also performed sign‐alternating temperature gradient experiments on the ice sphere arrays. The morphological evolution of the neck and the associated vapor transfer were examined through image analysis and 2D modeling. The final microstructures of the neck area turned out to be a symmetrical distribution of ice protrusions bridging neighboring ice spheres.  相似文献   

A 2000‐year lipid biomarker record preserved in a stalagmite from north‐west Scotland     

Alison J. Blyth  Andy Baker  Louise E. Thomas  Peter Van Calsteren 《第四纪科学杂志》2011,26(3):326-334

Previous studies on lipid biomarkers preserved in Chinese stalagmites have indicated that ratios of low‐molecular‐weight (LMW) to high‐molecular‐weight (HMW) n‐alkanes, n‐alkan‐2‐ones, n‐alkanols and n‐alkanoic acids can be used as an index of vegetation versus microbial organic matter input to the system and, by extension, a marker of climatic changes, with increases in the proportion of LMW compounds coinciding with colder periods. Here we test whether this hypothesis is equally applicable to a different geographical region (north‐west Scotland), by examining a stalagmite record of the past 200 years, and a wider range of lipid markers. We also test the applicability of other lipid proxies in this context, including the use of n‐alkane ratios, to interpret vegetation changes, and unsaturated alkanoic acid ratios as climatic indicators. The results show that lipid proxies preserved in stalagmites, and especially those related to vegetation, are potentially extremely useful in palaeoenvironmental research. Of particular value is the use of C₂₇/C₃₁ n‐alkane ratios as a proxy for vegetation change, clearly indicating variations between herbaceous and arboreal cover. This proxy has now been successfully applied to samples from diverse environments, and can be considered sufficiently robust to be of use in analysing future stalagmite records. It will be of particular value in areas where reliable pollen records are not available, as is often the case with deeper cave deposits. However, the division between LMW and HMW aliphatic compounds is not a clear‐cut case of microbial versus plant activity, with the changes in LMW compounds relating more closely to those in their HMW analogues than in specific bacterial biomarkers. The use of unsaturated alkanoic acid ratios here gives conflicting results, with the observed variation through time depending on the isomer measured. The discrepancies between the findings of this study and previous work are likely to be due to the varying controls on the lipids (original organic matter input, and compound degradation), which in turn will be affected by whether the main climatic limiting factor on the soil is temperature or precipitation. This suggests that lipid proxies preserved in stalagmites must be interpreted with care, particularly in the case of bacterial compounds which may be derived from within the cave or from the soil. However, many of these issues can be resolved by the use of multi‐proxy studies. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Use of cartographic images by expert and novice field geologists in planning fieldwork routes     

Kathleen M. Baker  Andrew C. Johnson  Caitlin N. Callahan  Heather L. Petcovic 《制图学和地理信息科学》2016,43(2):176-187

Topographic maps and aerial photographs are particularly useful when geoscientists are faced with fieldwork tasks such as selecting paths for observation, establishing sampling schemes, or defining field regions. These types of images are crucial in bedrock geologic mapping, a cognitively complex field-based problem-solving task. Geologic mapping requires the geologist to correctly identify rock types and three-dimensional bedrock structures from often partial or poor-quality outcrop data while navigating through unfamiliar terrain. This paper compares the walked routes of novice to expert geologists working in the field (n = 66) with the results of a route planning and navigation survey of a similar population of geologists (n = 77). Results show clearly that those geologists with previous mapping experience make quick and decisive determinations about field areas from available imagery and maps, regardless of whether they are or not physically present in the field area. Recognition of geologic features enabled experts to form and verbalize a specific plan for travel through a landscape based on those features. Novices were less likely to develop specific travel route plans and were less likely to identify critical landscape cues from aerial photographs.  相似文献   

Visualising 30 Years of Population Density Change in Australia’s Major Capital Cities     

Neil T. Coffee  Jarrod Lange  Emma Baker 《The Australian geographer》2016,47(4):511-525

ABSTRACT

This study uses a novel spatial approach to compare population density change across cities and over time. It examines spatio-temporal change in Australia’s five most populated capital cities from 1981 to 2011, and documents the established and emerging patterns of population distribution. The settlement patterns of Australian cities have changed substantially in the last 30 years. From the doughnut cities of the 1980s, programs of consolidation, renewal and densification have changed and concentrated population in our cities. Australian cities in the 1980s were characterised by sparsely populated, low density centres with growth concentrated to the suburban fringes. ‘Smart Growth’ and the ‘New Urbanism’ movements in the 1990s advocated higher dwelling density living and the inner cities re-emerged, inner areas were redeveloped, and the population distribution shifted towards increased inner city population densities. Policies aimed at re-populating the inner city dominated and the resultant changes are now visible in Australia’s five most populated capital cities. While this pattern has been reported in a number of studies, questions remain regarding the extent of these changes and how to analyse and visualise them across urban space. This paper reports on a spatial method which addresses the limitations of changing statistical boundaries to identify the changing patterns in Australian cities over time and space.  相似文献