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61.
The impact of the Alaskan Stream (AS) eddies on the chlorophyll a (chl-a) distribution in the central subarctic North Pacific was investigated through analysis of chl-a and altimetry data from satellite observations. Altimetry observations provided the locations of mesoscale eddies in time and space within the maps of chlorophyll distributions. The climatological chl-a distributions averaged in the area and time showing presence of AS eddies suggested that AS eddies contributed significantly to the chl-a distribution in the deep-sea region of the subarctic North Pacific. The chl-a distribution was closely related to the AS eddies regardless of whether the eddy was located in or detached from the AS. A combination of two or three AS eddies sometimes formed high chl-a concentration belts that injected chlorophyll and coastal nutrient-rich waters southward from the Aleutian Islands far into the deep-sea region of the subarctic North Pacific. These results indicate that chl-a distribution in the central subarctic North Pacific was strongly impacted by AS eddies.  相似文献   
62.
Reported are the results from a comparison of OH,H2O2CH3OOH, and O3 observationswithmodel predictions based on current HOx–CH4reaction mechanisms. The field observations are thoserecorded during the NASA GTE field program, PEM-Tropics A. The major focus ofthis paper is on thosedata generated on the NASA P-3B aircraft during a mission flown in the marineboundary layer (MBL) nearChristmas Island, a site located in the central equatorial Pacific (i.e.,2° N, 157° W). Taking advantage of thestability of the southeastern trade-winds, an air parcel was sampled in aLagrangian mode over a significantfraction of a solar day. Analyses of these data revealed excellent agreementbetween model simulated andobserved OH. In addition, the model simulations reproduced the major featuresin the observed diurnalprofiles of H2O2 and CH3OOH. In the case ofO3, the model captured the key observational feature whichinvolved an early morning maximum. An examination of the MBL HOxbudget indicated that the O(1D) + H2Oreaction is the major source of HOx while the major sinks involveboth physical and chemical processes involving the peroxide species,H2O2 and CH3OOH. Overall, the generally goodagreement between modeland observations suggests that our current understanding ofHOx–CH4 chemistry in the tropical MBL isquite good; however, there remains a need to critically examine this chemistrywhen both CH2O and HO2are added to the species measured.  相似文献   
63.
Experiments have been performed to study the thermal performance of a backfilled disposal vault in which the waste containers are emplaced in boreholes and surrounded by a bentonitesand buffer.

The near-field thermal regime in a buffer-backfill disposal vault in which the nuclear fuel waste is emplaced in canisters, is studied by one-eight scale experimental models. The thermal performance of the buffer and backfill are examined in a thermal drying environment prior to the ground water recharge of the disposal vault.

The formation of shrinkage cracks in the buffer due to drying and the response of these shrinkage cracks to the rewetting condition and their influence on the near-field thermal regime are assessed.  相似文献   

64.
Al-spinels in primitive arc volcanics   总被引:1,自引:0,他引:1  
Summary Al-rich spinels (100Cr/(Cr + Al) < 5, Al2O3 > 50 wt%) are common in alpine peridotites, both terrestrial and lunar mafic and ultramafic cumulates, and in certain metamorphic rocks, but they are apparently rare in terrestrial volcanic rocks. Here we describe the occurrence of Al-rich spinel inclusions in olivine phenocrysts in island arc volcanic rocks from five new localities: Bukit Mapas (Sumatra) and eastern Bali in the Sunda arc, and Epi, Merelava, and Ambrym islands in the Vanuatu arc. More commonly, relatively Cr-rich spinels also occur as inclusions in the saine olivine phenocrysts, and it appears that the Cr-poor aluminous spinels must be in disequilibrium with the host basaltic melts. In the rocks studied, Al-rich spinels also coexist with trapped silicate glasses and highly aluminous clinopyroxene in melt inclusions in olivine. This paragenesis suggests an origin involving contamination by localized Al-rich melt pockets as opposed to a xenocrystic origin. Two mechanisms to produce this high-Al melt in basaltic magma chambers are suggested: (1) localized high-Al melt production by complete breakdown of assimilated lower crustal gabbroic rocks. In this model the high-Al melt may crystallise Al-rich spinels which are subsequently trapped as solid inclusions by phenocryst phases of the host basaltic melt or may be trapped as melt inclusions in which Al-rich spinels and Al-rich clinopyroxene crystallise as daughter phases, and (2) in congruent breakdown of amphibole in amphibole-rich cumulates in sub-arc, or sub-OIB volcano magma chambers. The latter reaction produces a melt with 20–22% of Al2O3, aluminous clinopyroxene, Al-rich spinel and olivine. Mixing between these amphibole breakdown products and host basaltic melt may occur throughout the evolution of a magmatic system, but particularly during recharge with hot magnesian basalt batches. Aluminous spinels and aluminous clinopyroxene produced during amphibole breakdown, or perhaps crystallised from aluminous melt produced in the saine reaction, are incorporated into the magma during recharge, and subsequently trapped, together with the coexisting Cr-spinels, by crystallising olivine and clinopyroxene.
Al-Spinelle in primitiven Inselbogen-Vulkaniten
Zusammenfassung Al-reiche Spinelle (100Cr/(Cr + Al) < 5, Al2O3 > 50 Gew.%) sind in alpinen Peridotiten, in terrestrischen und lunaren mafischen und ultramafischen Kumulaten und in manchen metamorphen Gesteinen weit verbreitet, aber sie scheinen in terrestrischen, vulkanischen Gesteinen selten zu sein. Wir beschreiben hier das Vorkommen von Al-reichen Spinell-Inklusionen in Olivinkristallen von Inselbogen-Vulkaniten von 5 neuen Lokalitäten: Bukit Mapas (Sumatra) und Ost-Bali im Sunda-Bogen und die Inseln Epi, Merelava und Ambrym im Vanuatu-Bogen. Relativ Cr-reiche Spinelle kommen häufiger auch als Einschlüsse in denselben Olivin-Kristallen vor, und es scheint, daß Chrom-arme Aluminiumspinelle im Ungleichgewicht mit ihren basaltischen Mutterschmelzen stehen. In den untersuchten Gesteinen kommen Al-reiche Spinelle zusammen mit Silikatgläsern und Aluminium-reichen Klinopyroxenen in Schmelzeinschlüssen in Olivinen vor. Diese Assoziation weist auf einen Ursprung hin, der Kontamination durch lokalisierte Al-reiche pockets von Schmelze involviert; dies steht im Gegensatz zu einem Ursprung als Xenokristalle. Wir schlagen zwei Mechanismen vor, die diese Aluminium-reiche Schmelze in basaltischen Magmakammern erzeugen können: (1) lokalisierte Produktion von Aluminium-reicher Schmelze durch vollkommene Auflösung von assimilierten gabbroischen Gesteinen aus der unteren Kruste. In diesem Modell kann die Aluminium-reiche Schmelze Al-reiche Spinelle kristallisieren, die dann anschließend als feste Einschlüsse von Phenokristallen in der basaltischen Mutterschmelze eingefangen werden oder als Schmelzeinschlüsse, in denen Al-reiche Spinelle und Al-reiche Klinopyroxene als Tochterphasen kristallisieren. (2) Inkongruenter Zerfall von Amphibol in Amphibol-reichen Kumulaten in Magmakammern unter Inselbögen oder unter OIB-Vulkanen. Die letztgenannte Reaktion erzeugt eine Schmelze mit ungefähr 20–22% Al2O3, Aluminium-haltigen Klinopyroxen, Al-reichen Spinell und Olivin. Mischung zwischen diesen Produkten des Zerfalls von Amphibol und basaltischer Mutterschmelze kann während der ganzen Evolution eines magmatischen Systems stattfinden, aber besonders während der Zufuhr neuer heißer Magnesium-reicher Basalte. Aluminium-haltige Spinelle und Klinopyroxene, die während des Zerfalls von Amphibol entstanden sind oder vielleicht aus einer Aluminium-haltigen Schmelze in derselben Reaktion produziert wurden, werden während der Neuzufuhr in das Magma inkorporiert und im Anschluß daran, zusammen mit den koexistierenden Cr-Spinellen, von kristallisierendem Olivin und Klinopyroxen eingefangen.


With 6 Figures  相似文献   
65.
Numbers of Cape cormorants Phalacrocorax capensis breeding in South Africa decreased by nearly 50% from approximately 107 000 pairs in 1977–1981 to 57 000 pairs in 2010–2014. Although four colonies had >10 000 pairs in 1977–1981, there was just one such colony in 2010–2014. Almost all the decrease occurred after the early 1990s off north-west South Africa, between the Orange River estuary and Dassen Island. South of this, the number breeding in the two periods was stable, with some colonies being formed or growing rapidly in the 2000s. The proportion of South Africa’s Cape cormorants that bred south of Dassen Island increased from 35% in 1977–1981 to 66% in 2010–2014, with the opposite situation observed in the north-west. This matched a shift to the south and east in the distributions of two of the Cape cormorant’s main prey species, anchovy Engraulis encrasicolus and sardine Sardinops sagax. In 2014, an apparent scarcity of prey in the north-west resulted in Cape cormorants attempting to take bait from hooks of fishing lines over an extended period, a behaviour not previously recorded. The number of Cape cormorants breeding in the south may be constrained by the absence of large islands between Dyer Island in the west and Algoa Bay in the east. If so, it may be possible to bolster the southern population through the provision of appropriate breeding habitat, such as platforms, or restricting human disturbance at suitable mainland cliff breeding sites.  相似文献   
66.
Seasonal variations in coccolithophore abundance, chlorophyll, nutrients and production of particulate organic and inorganic carbon (POC and PIC) were determined along a coastal to oceanic east-west transect (Line P) culminating at Ocean Station Papa in the northeastern subarctic Pacific between 1998 and 2000. Offshore stations generally exhibited low seasonality in chlorophyll concentrations, with moderate seasonality in POC production. Near shelf stations showed a similar pattern to offshore stations, but were also characterized by sporadic events of higher POC productivity. During the 1998 El Niño, June was characterized by low chlorophyll and POC productivity along the transect, presumably as a result of depleted surface nitrate. In contrast, during the 1999 La Niña, and in 2000, higher POC productivity and surface nitrate occurred along the transect in June. Chlorophyll and POC productivity were similar in late summer in all 3 years. The coccolithophore population was usually numerically dominated by Emiliania huxleyi, particularly in June. Along the transect, abundance of coccolithophores was much higher in June during the 1998 El Niño (mean of 221 cells ml−1) than in the 1999 La Niña (mean of 40 cells ml−1), with their abundance in late summers of both years being very low. Abundances were even higher along the transect in June and the late summer of 2000 with sporadic ‘blooms’ of >1000 cells ml−1 at some stations (cruise averages 395 and 552 cell ml−1, respectively). Production rates of PIC did not consistently correlate with areas of high coccolithophore abundance. PIC production was high (100-250 mg C m−2 d−1) along the transect during June 1998, and low (1-40 mg C m−2 d−1) during both winters, June 1999 and during late summers of 1998 and 1999. The year 2000 was more complicated, with high rates of PIC production accompanying high abundance of coccolithophores in late summer, but lower rates of PIC production accompanying high coccolithophore numbers in June. Our data suggest that the abundance of coccolithophores and the production rates of PIC in the subarctic are higher than previously thought. Occasional PIC:POC production ratios of 1 or greater in 1998 and 2000 suggest that coccolithophores in this region could have a significant impact on the efficiency of the biological carbon pump.  相似文献   
67.
Two suites of regionally metamorphosed semi-pelitic schists were studied in order to investigate the paragenesis of low temperature plagioclase, from which something may be inferred as to the nature of the peristerite solvus at the temperatures and pressures of formation of these rocks: one from the Gile Mountain Formation in the Hanover and Mt. Cube quadrangles, eastern Vermont, U.S.A.; the other from the Alpine schists along the Haast River, South Westland, New Zealand. Plagioclase, muscovite, biotite, chlorite, carbonate, and garnet compositions were determined with an ARL EMX electron probe microanalyzer. The variation in plagioclase composition with increasing grade in the Vermont schists suggests that the peristerite solvus is asymmetrical with a near vertical albite-rich side and a sloping oligoclase-rich side. The top of the solvus appears to lie slightly above the temperature expressed by the almandine isograd in these schists. The compositions of the coexisting albite and oligoclase in the New Zealand rocks suggest a lower geothermal gradient than in Vermont, creating a different pattern of variation in plagioclase composition. Distribution diagrams of Mg, Ti, and AlIV for muscovite-biotite and chlorite-biotite pairs in both suites of rocks support the hypothesis that the plagioclase relations observed represent equilibrium.  相似文献   
68.
Detailed acoustic surveys of benthic sediments were conducted in July 1995 and September 1998 in the vicinity of Humboldt Bay, California. During these surveys, a band of enhanced acoustic backscatter was observed offshore from the bay entrance, approximately parallel to the isobaths, in water depths ranging from 16-24 m. In order to assess the cause of the increase in backscatter levels, a more comprehensive study was conducted in August and September 1999 using 100 kHz side-scan sonar, bottom grab sampling and underwater video recording. New observations indicated that a dense population of sand dollars ( Dendraster excentricus ) coincided with the enhanced backscatter band. Compared to the two previous acoustic studies, the central section of the band expanded westward by 180 m and the southern section of the band shifted eastward by 160 m, possibly resulting from a change in the biological or physical factors which influence the location and breadth of sand dollars. The relationship between high sand dollar abundance and enhanced acoustic backscatter was further verified in the nearshore region off Samoa Beach California, where a dense, banded population of sand dollars was previously observed. Video footage confirmed the presence of a band of sand dollars, also nominally parallel to the isobaths, in water depths of 8-15 m. A band of enhanced backscatter coincided with the dense sand dollar population. The identification of dense aggregations of sand dollars through enhanced acoustic backscatter could lead to the use of acoustic techniques to study sand dollar distributions and abundance.  相似文献   
69.
Vertical profiles of temperature and salinity have been measured for 50 years along Line P between the North American west coast and mid Gulf of Alaska. These measurements extend 1425 km into the gulf at 13 or more sampling stations. The 10-50-m deep layer of Line P increased in temperature by 0.9 °C from 1958 to 2005, but is significant only at the 90% level due to large interannual variability. Most of this increase in temperature accompanies the 1977 shift in wind patterns. Temperature changes at 100-150 m and salinity changes in both layers are not statistically significant. Much of the variance in temperature is in the upper 50 m of Line P, and temperature changes tend to be uniform along Line P except for waters on the continental margin. Salinity changes are dominated by variability in the halocline between 100 and 150 m depth and are less uniform along Line P. Largest oscillations in temperature and salinity are between 1993 and 2003. These events can be understood by considering changes in eastward wind speed and wind patterns that are revealed in the first two modes of the Pacific Decadal Oscillation. Changes in these patterns are indicators for both Ekman surface forcing (Surface ocean currents flow to the right of the wind direction) and Ekman pumping (Surface waters diverge away from regions of positive wind stress curl, leading to upwelling of colder saltier water). Changes in temperature along the nearshore part of Line P suggest Ekman surface forcing is the stronger of the two processes in the upper layer. The change in salinity anomalies in the halocline along the seaward end of Line P, following the wind shift in 1977, is in agreement with enhanced upwelling caused by stronger Ekman pumping in this region.  相似文献   
70.
The stable isotopic (2H/1H and 18O/16O) composition of precipitation has been used for a variety of hydrological and paleoclimate studies, a starting point for which is the behaviour of stable isotopes in modern precipitation. To this end, daily precipitation samples were collected over a 7‐year period (2008–2014) at a semi‐arid site located at the Macquarie Marshes, New South Wales (Australia). The samples were analysed for stable isotope composition, and factors affecting the isotopic variability were investigated. The best correlation between δ 18O of precipitation was with local surface relative humidity. The reduced major axis precipitation weighted local meteoric water line was δ 2H = 7.20 δ 18O + 9.1. The lower slope and intercept (when compared with the Global Meteoric Water Line) are typical for a warm dry climate, where subcloud evaporation of raindrops is experienced. A previously published model to estimate the degree of subcloud evaporation and the subsequent isotopic modification of raindrops was enhanced to include the vertical temperature and humidity profile. The modelled results for raindrops of 1.0 mm radius showed that on average, the measured D‐excess (=δ 2H ? 8 δ 18O) was 19.8‰ lower than that at the base of the cloud, and 18% of the moisture was evaporated before ground level (smaller effects were modelled for larger raindrops). After estimating the isotopic signature at the base of the cloud, a number of data points still plotted below the global meteoric water line, suggesting that some of the moisture was sourced from previously evaporated water. Back trajectory analysis estimated that 38% of the moisture was sourced over land. Precipitation samples for which a larger proportion of the moisture was sourced over land were 18O and 2H‐enriched in comparison to samples for which the majority of the moisture was sourced over the ocean. The most common weather systems resulting in precipitation were inland trough systems; however, only East Coast Lows contributed to a significant difference in the isotopic values. Copyright © 2016 Australian Nuclear Science and Technology Organisation. Hydrological Processes. © 2016 John Wiley & Sons, Ltd.  相似文献   
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