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11.
The present study highlights the synthesis of CuO–ZnO nanocomposite via facile hydrothermal method at 150 °C and autogenous pressure. The structural and textural features of prepared composite material was characterized by several characterization techniques such as X-ray powder diffraction, Fourier transform infrared spectroscopy, Scanning electron microscopy, and energy-dispersive X-ray spectroscopy. The optimized prepared nanocomposite was utilized for photocatalytic degradation of aromatic Direct Blue 71 dye (DB71) under natural sunlight conditions. The catalytic activity results by CuO–ZnO nanocomposite were observed to be higher than the reagent-grade zinc oxide under visible light conditions. The response surface methodology protocol (RSM) with central composite design was optimized by different photodegradation operational parameters such as pH, dye concentration, catalyst amount, and reaction time. The optimized RSM results demonstrated that a quadratic polynomial model was found suitable to define the relation between the photocatalytic activity and operational parameters. Moreover, the observed high R 2 value (0.9786) confirms a strong evaluation of experimental data. To achieve maximum DB71 degradation, optimized condition was found at 177.13 min of contact time, 3.93 solution pH, and 24.34 mg/L of dye concentration with 1.85 g/L of catalyst dose The identical optimum conditions resulted maximum 89.58% DB71 degradation.  相似文献   
12.
Understanding the geological uncertainty of hydrostratigraphic models is important for risk assessment in hydrogeology. An important feature of sedimentary deposits is the directional ordering of hydrostratigraphic units (HSU). Geostatistical simulation methods propose efficient algorithm for assessing HSU uncertainty. Among different geostatistical methods to simulate categorical data, Bayesian maximum entropy method (BME) and its simplified version Markov-type categorical prediction (MCP) present interesting features. In particular, the zero-forcing property of BME and MCP can provide a valuable constrain on directional properties. We illustrate the ability of MCP to simulate vertically ordered units. A regional hydrostratigraphic system with 11 HSU and different abundances is used. The transitional deterministic model of this system presents lateral variations and vertical ordering. The set of 66 (11 × 12/2) bivariate probability functions is directly calculated on the deterministic model with fast Fourier transform. Despite the trends present in the deterministic model, MCP is unbiased for the HSU proportions in the non-conditional case. In the conditional cases, MCP proved robust to datasets over-representing some HSU. The inter-realizations variability is shown to closely follow the amount and quality of data provided. Our results with different conditioning datasets show that MCP replicates adequately the directional units arrangement. Thus, MCP appears to be a practical method for generating stochastic models in a 3D hydrostratigraphic context.  相似文献   
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Natural Resources Research - Groundwater over-exploitation in arid and semiarid environments has led to many land subsidence cases. Immense economic losses incurred from land subsidence occurrences...  相似文献   
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Ocean Dynamics - The climatic change has led to the sea-level rise (SLR), which is expected to continue based on the current industrial and human activities. Previous studies indicated that most of...  相似文献   
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China Ocean Engineering - The breakwaters have experienced many changes during their construction history. These changes have been considered to improve their performance, depending on their...  相似文献   
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