Distribution of dissolved species and suspended particulate copper in an intertidal ecosystem affected by copper mine tailings in Northern Chile   总被引：1，自引：0，他引：1  

Santiago Andrade  James Moffett  Juan A. Correa   《Marine Chemistry》2006,101(3-4):203-212

The coastline near Chañaral in Northern Chile is one of the most highly Cu-contaminated zones in the world due to discharges from mining activities for more than 60 years. The speciation of Cu has been studied to determine the importance of organic complexation in highly contaminated areas, and to assess the likely physiological impacts of Cu on marine organisms. Dissolved Cu concentrations of up to 500 nM were measured, completely saturating organic ligands and leading to free Cu²⁺ concentrations in excess of 10^− 8 M. These values are higher than those reported in any other marine environment, and because they occur over an extensive area, provide a unique opportunity to study the effects of Cu on marine ecosystems and to see how Cu behaves when its speciation is predominantly inorganic. We found strong gradients in free Cu²⁺ between Chañaral and adjacent areas with lower Cu, where speciation is dominated by organic complexation. There is also a significant increase in the partitioning of Cu onto suspended particles in the contaminated areas, consistent with previous studies that showed that organic ligands stabilize Cu in the dissolved phase, whilst “excess” Cu is rapidly scavenged. Those high dissolved Cu concentrations persist in spite of solid phase partitioning and advective processes along this open-ocean coastline, suggesting that Cu inputs into the system are still very large. Measurements were made using anodic stripping voltammetry with a thin mercury film coated with Nafion, which previous workers have shown can mitigate ambiguity in the data arising from inadvertent reduction of organic complexes. Our findings suggest that this is a useful methodology for contaminated systems.  相似文献   

Tidally incised valleys on tropical carbonate shelves: An example from the northern Great Barrier Reef, Australia     

Peter T. Harris  Andrew Heap  Vicki Passlow  Michael Hughes  James Daniell  Mark Hemer  Ole Anderson 《Marine Geology》2005,220(1-4):181-204

The formation of incised valleys on continental shelves is generally attributed to fluvial erosion under low sea level conditions. However, there are exceptions. A multibeam sonar survey at the northern end of Australia's Great Barrier Reef, adjacent to the southern edge of the Gulf of Papua, mapped a shelf valley system up to 220 m deep that extends for more than 90 km across the continental shelf. This is the deepest shelf valley yet found in the Great Barrier Reef and is well below the maximum depth of fluvial incision that could have occurred under a − 120 m, eustatic sea level low-stand, as what occurred on this margin during the last ice age. These valleys appear to have formed by a combination of reef growth and tidal current scour, probably in relation to a sea level at around 30–50 m below its present position.

Tidally incised depressions in the valley floor exhibit closed bathymetric contours at both ends. Valley floor sediments are mainly calcareous muddy, gravelly sand on the middle shelf, giving way to well-sorted, gravely sand containing a large relict fraction on the outer shelf. The valley extends between broad platform reefs and framework coral growth, which accumulated through the late Quaternary, coincides with tidal current scour to produce steep-sided (locally vertical) valley walls. The deepest segments of the valley were probably the sites of lakes during the last ice age, when Torres Strait formed an emergent land-bridge between Australia and Papua New Guinea. Numerical modeling predicts that the strongest tidal currents occur over the deepest, outer-shelf segment of the valley when sea level is about 40–50 m below its present position. These results are consistent with a Pleistocene age and relict origin of the valley.

Based on these observations, we propose a new conceptual model for the formation of tidally incised shelf valleys. Tidal erosion on meso- to macro-tidal, rimmed carbonate shelves is enhanced during sea level rise and fall when a tidal, hydraulic pressure gradient is established between the shelf-lagoon and the adjacent ocean basin. Tidal flows attain a maximum, and channel incision is greatest, when a large hydraulic pressure gradient coincides with small channel cross sections. Our tidal-incision model may explain the observation of other workers, that sediment is exported from the Great Barrier Reef shelf to the adjacent ocean basins during intermediate (rather than last glacial maximum) low-stand, sea level positions. The model may apply to other rimmed shelves, both modern and ancient.  相似文献   

An unsteady wave driver for narrowbanded waves: modeling nearshore circulation driven by wave groups     

Andrew B. Kennedy  James T. Kirby   《Coastal Engineering》2003,48(4):257-275

In this paper, we derive an unsteady refraction–diffraction model for narrowbanded water waves for use in computing coupled wave–current motion in the nearshore. The end result is a variable coefficient, nonlinear Schrödinger-type wave driver (describing the envelope of narrow-banded incident waves) coupled to forced nonlinear shallow water equations (describing steady or unsteady mean flows driven by the short-wave field). Comparisons with experimental data show that good accuracy can be obtained for cases of nonbreaking wave transformation. Numerical simulations show that the interaction of wave groups with longshore topographic nonuniformities generates strong edge wave resonances, providing a generating mechanism for low-order edge waves.  相似文献   

Influence of relative sea level changes on the construction of the Mississippi Fan     

Arnold H. Bouma  James M. Coleman  Charles E. Stelting  Barry Kohl 《Geo-Marine Letters》1989,9(3):161-170

A conceptual sea-level-driven depositional model for individual fanlobes (channel-overbank systems) of the Mississippi Fan does not permit direct application of the sequence stratigraphic principles of Vail and colleagues. Deep Sea Drilling Project Leg 96 results suggest that, during initial relative lowering of sea level, the canyon and upper fan channel were formed; excavated fine-grained slope sediments may have formed a debris flow deposit base for the fanlobe. Continued lowering produced constructional channel-levee-overbank deposits. Rising relative sea level inhibited input of coarse clastics, and channel depressions filled with muds. A blanket of (hemi)pelagics represents relative high sea level stand.  相似文献   

An evaluation of the Emerald/Western Bank juvenile haddock closed area     

Frank  Kenneth T.; Shackell  Nancy L.; Simon  James E. 《ICES Journal of Marine Science》2000,57(4):1023-1034

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Spatial Variation in the Structure of Kelp Forest Communities Along a Wave Exposure Gradient     

Christopher  Harrold  James  Watanabe Susan  Lisin 《Marine Ecology》1988,9(2):131-156

Abstract. Four sites were sampled in kelp (Macrocysiis pyrifera) forests occupying rocky bottom habitats along a wave exposure gradient in central California. Consistent betwecn-site differences were found in the three major structural elements - the surface canopy, the undcrstory assemblage, and the ground cover/turf assemblage - of kelp forest communities. Macrocysiis pyrifera was found at all four sites. Nereucyslis tuelkeana only at the most exposed site. The understory kelps Laminaria setchellii and Pterygopltora californica were also characteristic of exposed sites. Articulated coralline algae were more abundant at exposed sites than protected, while fleshy red algae showed the opposite pattern. All four study sites were located along 8.5 km of coastline, and thus were assumed to have available to them the same species pool for colonization. The substrate composition was the same and the amount of unconsolidated substrate was similar at all four sites. We suggest that exposure to wave-generated water motion, through its influence on the surface canopy and therefore on the amount of light reaching the bottom, is responsible for these between-site differences.  相似文献   

Observations of natural fluorescence with an underwater radiometer     

James C. Kitchen  Hasong Pak 《Journal of Oceanography》1987,43(6):356-362

Measurements of subsurface irradiance spectra in the ocean consistently indicate intensities of long-wavelength visible light (589 nm) greater than could be derived from the penetration of sunlight. This can be attributed to natural fluorescence and/or to spectral crosstalk due to light leakage through the blocking filters of each discrete detector. A comparison of observed profiles with modelled contributions from these two possible sources indicates that both factors are contributing. At 671 and 694 nm wavelength, the excess signal appears to be predominantly fluorescence while that at 589 nm is mostly crosstalk. Both effects appear to be important at 625 nm although the amount of excess light is small compared to the other wavelengths.The above observations and interpretations are consistent with the optical design of the instrument used and the shape of natural irradiance spectra. Fluorescence efficiencies derived from the irradiance measurements correlate well with measuredin situ fluorescence.  相似文献   

A detailed magnetic study of the Reykjanes Ridge between 63°00′N and 63°40′N     

Jean-Christophe Sempéré  Leo Kristjansson  Hans Schouten  James R. Heirtzler  G. Leonard Johnson 《Marine Geophysical Researches》1990,12(3):215-234

Immediately southwest of Iceland, the Reykjanes Ridge consists of a series ofen échelon, elongate ridges superposed on an elevated, smooth plateau. We have interpreted a detailed magnetic study of the portion of the Reykjanes Ridge between 63°00N and 63°40N on the Icelandic insular shelf. Because the seafloor is very shallow in our survey area (100–500 m), the surface magnetic survey is equivalent to a high-sensitivity, nearbottom experiment using a deep-towed magnetometer. We have performed two-dimensional inversions of the magnetic data along profiles perpendicular to the volcanic ridges. The inversions, which yield the magnetization distribution responsible for the observed magnetic field, allow us to locate the zones of most recent volcanism and to measure spreading rates accurately. We estimate the average half spreading rate over the last 0.72 m.y. to have been 10 mm/yr within the survey area. The two-dimensional inversions allow us also to measure polarity transition widths, which provide an indirect measure of the width of the zone of crustal accretion. We find a mean transition width on the order of 4.5±1.6 km. The observed range of transition widths (2 to 8.4 km) and their mean value are characteristic of slow-spreading centers, where the locus of crustal accretion may be prone to lateral shifts depending on the availability of magmatic sources. These results suggest that, despite the unique volcanotectonic setting of the Reykjanes Ridge, the scale at which crustal accretion occurs along it may be similar to that at which it occurs along other slow-spreading centers. The polarity transition width measurements suggest a zone of crustal accretion 4–9 km wide. This value is consistent with the observed width of volcanic systems of the Reykjanes Peninsula. The magnetization amplitudes inferred from our inversions are in general agreement with NRM intensity values of dredge samples measured by De Boer (1975) and ourselves. Our thermomagnetic measurements do not support the hypothesis that the low amplitude of magnetic anomalies near Iceland is the result of a high oxidation state of the basalts. We suggest that the observed reduction in magnetic anomaly amplitude toward Iceland may be the result of an increase in the size of pillows and other igneous units.  相似文献   

The reliability of analytical data for tributyltin (TBT) in sea water and its implications on water quality criteria     

James W. Readman  Laurence D. Mee 《Marine environmental research》1991,32(1-4)

To investigate the reliability of analytical data for tributyltin (TBT) in sea water, split water samples were distributed to ten laboratories in six countries. The sub-surface samples comprised: (i) an offshore (0·5 km) water sample, (ii) the same sample but spiked with an undisclosed quantity of TBT standard compound (175 ng TBT⁺ liter⁻¹), and (iii) a sample taken from a yacht marina. The seven acceptable data sets were in good agreement for the spiked sample (178 ± 26 ng TBT⁺ liter⁻¹) but showed a greater variation in concentrations reported for the yacht marina sample (366 ± 93 ng TBT⁺ liter⁻¹). Atomic absorption and gas chromatographic-flame photometric detection techniques produced results of similar accuracy and precision. Samples acidified with 1 ml of 10% (v/v) acetic acid appeared stable for more than 2 weeks when stored refrigerated and in darkness. Analyses of the offshore seawater sample revealed TBT contamination (9 ± 7 ng TBT⁺ liter⁻¹) indicating dispersion of the compound to the shelf waters off Monaco. The spread in values reported by the laboratories demonstrates inherent difficulties in obtaining good precision below approximately 20 ng TBT⁺ liter⁻¹. This observation is discussed with respect to the setting and enforcing of water quality standards.  相似文献   

Sea Grant in Latin America?: Adapting the US Sea Grant model of linked applied research,extension, and education to a Latin American Context—Is there a fit?     

S. Matthew Wilburn  James Tobey  Jill Hepp  Stephen Olsen  Barry Costa-Pierce 《Marine Policy》2007

This paper explores the application of the US Sea Grant model of applied research, extension, and education to two case studies in Latin America: Coastal Ecuador and the Gulf of Fonseca. The analysis is based on a series of meetings and roundtables with in-country partners and leaders of the US Sea Grant program. We conclude that the Sea Grant model provides an institutional structure that Latin America lacks and the model's features would improve governance of marine and coastal resources through more effective linkages between coastal communities, universities, and policy/decision makers at local, national, and international levels.  相似文献