Surveillance for previously unmonitored organic contaminants in the San Francisco Estuary     

Oros DR  Jarman WM  Lowe T  David N  Lowe S  Davis JA 《Marine pollution bulletin》2003,46(9):1102-1110

The San Francisco Estuary Regional Monitoring Program initiated surveillance monitoring to identify previously unmonitored synthetic organic contaminants in the San Francisco Estuary. Organic extracts of water samples were analyzed using gas chromatography-mass spectrometry in full scan mode. The major contaminant classes identified in the samples were fire retardants, pesticides, personal care product ingredients, and plasticizers. Evidence from the literature suggests that some of these contaminants can persist in the environment, induce toxicity, and accumulate in marine biota and in higher food chain consumers. The major sources of these contaminants into the marine environment are the discharge of municipal and industrial wastewater effluents, urban stormwater, and agricultural runoff. As a proactive effort, it is suggested that surveillance studies be used routinely in monitoring programs to identify and prevent potential problem contaminants from harming the marine environment.  相似文献   

Contaminant concentrations in sport fish from San Francisco Bay, 1997     

Davis JA  May MD  Greenfield BK  Fairey R  Roberts C  Ichikawa G  Stoelting MS  Becker JS  Tjeerdema RS 《Marine pollution bulletin》2002,44(10):1117-1129

In 1997, seven sport fish species were sampled from seven popular fishing areas in San Francisco Bay. Mercury exceeded a human health screening value in 44 of 84 (52%) samples. All collected samples of leopard shark and striped bass exceeded the mercury screening value of 0.23 microg/g wet weight. PCBs exceeded the screening value in 51 of 72 (71%) samples. DDT, chlordane, and dieldrin, had lower numbers of samples above screening values: 16 of 72 (22%) for DDT, 11 of 72 (15%) for chlordanes, and 27 of 72 (37%) for dieldrin. Concentrations of PCBs and other trace organics were highest in white croaker and shiner surfperch, the two species with the highest fat content in their muscle tissue. Fish from one location, Oakland Harbor, had significantly elevated wet weight concentrations of mercury, PCBs, DDTs, and chlordanes compared to other locations. Removal of skin from white croaker fillets reduced lipid concentrations by 27-49% and concentrations of trace organics by 33-40%.  相似文献   

Short-Period Waves That Heat the Corona Detected at the 1999 Eclipse     

Pasachoff  Jay M.  Babcock  Bryce A.  Russell  Kevin D.  Seaton  Daniel B. 《Solar physics》2002,207(2):241-257

As a part of a study of the cause of solar coronal heating, we searched for high-frequency (1 Hz) intensity oscillations in coronal loops in the [Fexiv] coronal green line. We summarize results from observations made at the 11 August 1999 total solar eclipse from Râmnicu-Vâlcea, Romania, through clear skies. We discuss the image reduction and analysis through two simultaneous series of coronal CCD images digitized at 10 Hz for a total time of about 140 s. One series of images was taken through a 3.6 Å filter isolating the 5303 Å[Fexiv] coronal green line and the other through a 100 Å filter in the nearby K-corona continuum. Previous observations, described in Pasachoff et al. (2000), showed no evidence for oscillations in the [Fexiv] green line at a level greater than 2% of coronal intensity. We describe several improvements made over the 1998 eclipse that led to increased image clarity and sensitivity. The corona was brighter in 1999 with the solar maximum, further improving the data. We use Fourier analysis to search in the [Fexiv] channel for intensity oscillations in loops at the base of the corona. Such oscillations in the 1-Hz range are predicted as a result of density fluctuations from the resonant absorption of MHD waves. The dissipation of a significant amount of mechanical energy from the photosphere into the corona through this mechanism could provide sufficient energy to heat the corona. A Monte Carlo model of the data suggests the presence of enhanced power, particularly in the 0.75–1.0 Hz range, and we conclude that MHD waves remain a viable method for coronal heating.  相似文献   

Fish Remains from Homestead Cave and Lake Levels of the Past 13,000 Years in the Bonneville Basin     

Jack M. Broughton  David B. Madsen  Jay Quade 《Quaternary Research》2000,53(3):392

A late Quaternary ichthyofauna from Homestead Cave, Utah, provides a new source of information on lake history in the Bonneville basin. The fish, represented by 11 freshwater species, were accumulated between 11,200 and 1000 ¹⁴C yr B.P. by scavenging owls. The ⁸⁷Sr/⁸⁶Sr ratio of Lake Bonneville varied with its elevation; ⁸⁷Sr/⁸⁶Sr values of fish from the lowest stratum of the cave suggest they grew in a lake near the terminal Pleistocene Gilbert shoreline. In the lowest deposits, a decrease in fish size and an increase in species tolerant of higher salinities or temperatures suggest multiple die-offs associated with declining lake levels. An initial, catastrophic, post-Provo die-off occurred at 11,300–11,200 ¹⁴C yr B.P. and was followed by at least one rebound or recolonization of fish populations, but fish were gone from Lake Bonneville sometime before 10,400 ¹⁴C yr B.P. This evidence is inconsistent with previous inferences of a near desiccation of Lake Bonneville between 13,000 and 12,000 ¹⁴C yr B.P. Peaks in Gila atraria frequencies in the upper strata suggest the Great Salt Lake had highstands at 3400 and 1000 ¹⁴C yr B.P.  相似文献   

Climate Warming and Water Management Adaptation for California   总被引：1，自引：3，他引：1  

Stacy K. Tanaka  Tingju Zhu  Jay R. Lund  Richard E. Howitt  Marion W. Jenkins  Manuel A. Pulido  Mélanie Tauber  Randall S. Ritzema  Inês C. Ferreira 《Climatic change》2006,76(3-4):361-387

The ability of California's water supply system to adapt to long-term climatic and demographic changes is examined. Two climate warming and a historical climate scenario are examined with population and land use estimates for the year 2100 using a statewide economic-engineering optimization model of water supply management. Methodologically, the results of this analysis indicate that for long-term climate change studies of complex systems, there is considerable value in including other major changes expected during a long-term time-frame (such as population changes), allowing the system to adapt to changes in conditions (a common feature of human societies), and representing the system in sufficient hydrologic and operational detail and breadth to allow significant adaptation. While the policy results of this study are preliminary, they point to a considerable engineering and economic ability of complex, diverse, and inter-tied systems to adapt to significant changes in climate and population. More specifically, California's water supply system appears physically capable of adapting to significant changes in climate and population, albeit at a significant cost. Such adaptation would entail large changes in the operation of California's large groundwater storage capacity, significant transfers of water among water users, and some adoption of new technologies.  相似文献   

Inter-relationships of MnO₂ precipitation, siderophore-Mn complex formation, siderophore degradation, and iron limitation in Mn-oxidizing bacterial cultures     

Dorothy L. Parker  Takami Morita  Rebecca Verity  James K. McCarthy 《Geochimica et cosmochimica acta》2007,71(23):5672-5683

To examine the pathways that form Mn^(III) and Mn^(IV) in the Mn^(II)-oxidizing bacterial strains Pseudomonas putida GB-1 and MnB1, and to test whether the siderophore pyoverdine (PVD) inhibits Mn^(IV)O₂ formation, cultures were subjected to various protocols at known concentrations of iron and PVD. Depending on growth conditions, P. putida produced one of two oxidized Mn species - either soluble PVD-Mn^(III) complex or insoluble Mn^(IV)O₂ minerals - but not both simultaneously. PVD-Mn^(III) was present, and MnO₂ precipitation was inhibited, both in iron-limited cultures that had synthesized 26-50 μM PVD and in iron-replete (non-PVD-producing) cultures that were supplemented with 10-550 μM purified PVD. PVD-Mn^(III) arose by predominantly ligand-mediated air oxidation of Mn^(II) in the presence of PVD, based on the following evidence: (a) yields and rates of this reaction were similar in sterile media and in cultures, and (b) GB-1 mutants deficient in enzymatic Mn oxidation produced PVD-Mn^(III) as efficiently as wild type. Only wild type, however, could degrade PVD-Mn^(III), a process linked to the production of both MnO₂ and an altered PVD with absorbance and fluorescence spectra markedly different from those of either PVD or PVD-Mn^(III). Two conditions, the presence of bioavailable iron and the absence of PVD at concentrations exceeding those of Mn, both had to be satisfied for MnO₂ to appear. These results suggest that P. putida cultures produce soluble Mn^(III) or MnO₂ by different and mutually inhibitory pathways: enzymatic catalysis yielding MnO₂ under iron sufficiency or PVD-promoted oxidation yielding PVD-Mn^(III) under iron limitation. Since PVD-producing Pseudomonas species are environmentally prevalent Mn oxidizers, these data predict influences of iron (via PVD-Mn^(III) versus MnO₂) on the global oxidation/reduction cycling of various pollutants, recalcitrant organic matter, and elements such as C, S, N, Cr, U, and Mn.  相似文献   

Particle trapping in stratified estuaries: consequences of mass conservation     

David A. Jay  Philip M. Orton  Thomas Chisholm  Douglas J. Wilson  Annika M. V. Fain 《Estuaries and Coasts》2007,30(6):1095-1105

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Modeling errors in upward continuation for INS gravity compensation     

Christopher Jekeli  Jong-Ki Lee  Jay H. Kwon 《Journal of Geodesy》2007,81(5):297-309

Accurate upward continuation of gravity anomalies supports future precision, free-inertial navigation systems, since the latter cannot by themselves sense the gravitational field and thus require appropriate gravity compensation. This compensation is in the form of horizontal gravity components. An analysis of the model errors in upward continuation using derivatives of the standard Pizzetti integral solution (spherical approximation) shows that discretization of the data and truncation of the integral are the major sources of error in the predicted horizontal components of the gravity disturbance. The irregular shape of the data boundary, even the relatively rough topography of a simulated mountainous region, has only secondary effect, except when the data resolution is very high (small discretization error). Other errors due to spherical approximation are even less important. The analysis excluded all measurement errors in the gravity anomaly data in order to quantify just the model errors. Based on a consistent gravity field/topographic surface simulation, upward continuation errors in the derivatives of the Pizzetti integral to mean altitudes of about 3,000 and 1,500 m above the mean surface ranged from less than 1 mGal (standard deviation) to less than 2 mGal (standard deviation), respectively, in the case of 2 arcmin data resolution. Least-squares collocation performs better than this, but may require significantly greater computational resources.  相似文献   

A cellular automata model of surface water flow   总被引：1，自引：0，他引：1  

Jay A. Parsons  Mark A. Fonstad 《水文研究》2007,21(16):2189-2195

Previous cellular automata models of surface water flow have been constructed to reflect steady, gradually‐varied flow conditions. While these models are extremely important in showing the near‐equilibrium forms that result from the interactions of water and boundary material, highly dynamic forms and processes require models that represent unsteady flow conditions. In order to simulate unsteady flow in a cellular model of surface water flow, the conservation of mass and the Manning's equations are coupled with an algorithm to delay the movement of water from one pixel to the next until the correct timing is reached. This approach yields highly realistic flood wave hydrographs when compared with flood observations in the Walnut Gulch Experiment Watershed. Coupling this unsteady flow model with simple laws of sediment erosion, transport, and deposition should allow event‐based simulations of watershed and river channel geomorphologic change. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Sampling Trace-Level Organic Solutes with Polymeric Tubing Part 2. Dynamic Studies     

Louise V. Parker  Thomas A. Ranney 《Ground Water Monitoring & Remediation》1998,18(1):148-155

This is the second part of a study conducted to determine whether polymeric sampling tubing can affect organic analyte concentrations during a sampling event. In this part of the study, we looked for sorption and desorption of tricholoroethylene (TCE) and leaching of organic constituents in water pumped through five types of polymeric tubing. The materials tested were a rigid fluoropolymer, a flexible fluoropolymer, low-density polyethylene (LDPE), and two plasticized polypropylene tubings. The effects of tubing length and flow rate were examined.
The least sorptive tubings, both initially and at equilibrium, were the fluoropolymers. However, in some instances the LDPE tubing had little effect on TCE concentrations. This was when a slow flow rate was used to sample relatively shallow wells (50 feet [15 m] or less) or when a faster flow rate (1 L/min) was used to sample wells that are less than 500 feet (152 m). Further testing is recommended using more sorptive analytes.
Using high performance liquid chromatography (HPLC), we were unable to detect any constituents leaching from any of the tubings used in these studies, even when a slow flow rate was used. However, desorption of sorbed analytes is a concern for all the tubings tested, including the rigid fluoropolymer.  相似文献