Dynamic scheme of water circulation in karstic aquifers as constrained by Sr and Pb isotopes. Application to the Hérault watershed,Southern France     

Emmanuelle?Petelet-GiraudEmail author  Jean-Marc?Luck  Dalila?Ben Othman  Philippe?Negrel 《Hydrogeology Journal》2003,11(5):560-573

This paper focuses on the relationship between the karst aquifers and the Hérault River (southern France) as a function of hydrologic conditions. The combination of major and trace element, and Sr and Pb isotopes determined on dissolved load in karstic springs makes it possible to identify a dynamic scheme of the hydrology of the karstic area.In the headwaters part of this area, the Sourcettes Spring is fed by an interrupted stream that infiltrates at the basement-sedimentary cover contact. Internal geochemical processes are also pointed out: (1) water–rock interactions during underground circulation, and (2) water originating from different layers of the aquifer may show different chemistry depending on the hydrological conditions. The Vernède Spring, is fed by a second water supply during high flows (previously considered as unconnected). Finally, the Cent-Fonts Springs have been confirmed to be fed by the Buège interrupted stream.Pb isotopes on the dissolved and particulate loads of the river samples make it possible to discriminate the natural (local rocks) versus anthropogenic (mining district and road traffic) Pb sources. The Pb isotope investigations on karstic water make it possible to differentiate between neighboring springs presenting identical Sr isotope and element ratios, and to point out different underground circulation.

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Resumen Este artículo trata de la relación río-acuífero kárstico en la cuenca de Hérault (Francia), en función de las condiciones hidrológicas. La combinación de elementos principales, elementos traza, e isótopos de estroncio y plomo en muestras de manantiales kársticos permite construir un esquema dinámico de la zona.El manantial de Sourcettes, en la parte alta de la región, está alimentado por una corriente interrumpida que se infiltra a través la cubierta sedimentaria del lecho. También, se apunta a los procesos internos geoquímicos: (1) interacciones roca-acuífero, (2) aguas procedentes de capas diferentes del acuífero, dependiendo de las condiciones hidrológicas. El manantial de Vernède, en el sector oriental de la cuenca, se nutre de una segunda fuente de agua en períodos de aguas altas, que anteriormente se consideraba desconenctada. Finalmente, se ha confirmado que los manantiales de Cent-Fonts captan las aguas del curso interrumpido del Buège.Los isótopos de plomo, tanto en fase disuelta como en suspensión de muestras de río, permiten discriminar entre orígenes naturales (rocas naturales) y antrópicos (minería y tráfico) de este elemento. Las investigaciones en aguas kársticas llevan a diferenciar entre manantiales vecinos que tienen relaciones de isótopos de estroncio idénticas, así como a proponer circulaciones distintas en el acuífero por drenaje o por mineralización no diseminada del plomo.

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Résumé Cet article s'intéresse à la relation entre le karst et une rivière dans le bassin de l'Hérault (France), en fonction des conditions hydrologiques. La combinaison des éléments majeurs, des traces et des isotopes de Sr et Pb déterminés dans la charge dissoute de sources karstiques permet de construire un schéma dynamique de la région karstique.Dans la partie la plus haute de cette région, la source des Sourcettes est alimentée par un cours d'eau qui s'infiltre au contact de la série sédimentaire sur le socle. Des processus géochimiques sont également mis en évidence: (1) des interactions eau-roche au cours du trajet souterrain, (2) de l'eau provenant de différents niveaux de l'aquifère en fonction des conditions hydrologiques. Dans la partie orientale du bassin, la source Vernède reçoit une seconde alimentation lors des fortes crues, précédemment considérée comme n'étant pas connectée. Finalement, on confirme que la source des Cent-Fonts est alimentée par les pertes de la rivière de la Buèges.Les isotopes du Pb dans les charges dissoute et solide des échantillons de rivières ont conduit à faire la distinction entre les sources naturelle (roches locales) et anthropique (mines et trafic routier). Les études sur les isotopes du Pb dans les eaux karstiques permettent de différencier les sources voisines présentant des rapports d'éléments et de signatures isotopiques du Sr identiques, et à distinguer différentes circulations souterraines drainant ou non des minéralisations disséminées de Pb.

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Estimation de la température maximale d'enfouissement du Toarcien et du Callovo-Oxfordien au centre du bassin de Paris par les marqueurs organiques     

Cédric Ménétrier  Marcel Élie  Luis Martinez  Antoine Le Solleuz  Jean-Robert Disnar  Cécile Robin  François Guillocheau  Christophe Rigollet 《Comptes Rendus Geoscience》2005,337(15):1323-1330

The thermal history of the central part of the Paris basin is reconstructed using C₃₁ hopane $\mathrm{S}/\mathrm{R}$ isomerisation ratios and organic matter transformation ratios measured on Lower Toarcian and Callovo-Oxfordian samples. Maximum burial palaeotemperatures range between 90 and 115?°C for the Toarcian shales, and between 75 and 95?°C for the Callovo-Oxfordian samples, from the East to the centre of the basin, respectively. The amount of Late Cretaceous erosion was evaluated to be between ca. 400 to 600 m in the eastern part of the studied area and 100 to 300 m in the centre of the basin. To cite this article: C. Ménétrier et al., C. R. Geoscience 337 (2005).  相似文献   

Flank spreading and collapse of weak-cored volcanoes   总被引：1，自引：1，他引：0  

Emmanuelle?CecchiEmail author  Benjamin?van?Wyk de Vries  Jean-Marc?Lavest 《Bulletin of Volcanology》2004,67(1):72-91

Volcanoes subjected to hydrothermal activity develop weak cores as a result of alteration and due to elevated pore pressures. Edifices constructed at the angle of repose of volcanoclastics, or at even more gentle slopes, respond to internal weakening by initially deforming slowly, but may then collapse catastrophically. Such a process has so far been described for only a few volcanoes, such as Casita, Nicaragua; however, the conditions for flank spreading are widespread and many, if not most volcanoes should suffer some alteration-related flank spreading. We provide analogue models that characterise the structure — surface deformation fields and internal structures — of a spreading flank. Deformation creates a characteristic concave-convex-concave flank profile producing structures such as basal thrusts, summit normal faults, grabens and strike-slip relay faults. Three deformation regimes are found: a pit collapse regime is associated with very small volumes of ductile material located far from the edifice surface. This would not appear in nature, as time for deformation is greater than the lifetime of a volcano, unless very low rock viscosities are present. The other two regimes are flank spreading regimes, one symmetric and one asymmetric. The latter is the most common, as most volcanic structures are asymmetrical in form and in distribution of physical properties. The deformation is controlled by altered region dimensions, volume and position relative to the edifice, and to a lesser extent by its shape. As the flanks spread, landslides are created, initially on the steepened portion, but also from fault scarps. Major flank collapse may occur leading to explosive hydrothermal decompression and to a debris avalanche rich in hydrothermally altered material. We provide several new examples of volcanoes that have structures and morphologies compatible with flank spreading. We suggest that it is a common feature, important in the tectonics and hazards of many volcanoes.Editorial Responsibility: J. Gilbert  相似文献   

Galileo civil signal modulations     

Emilie Rebeyrol  Olivier Julien  Christophe Macabiau  Lionel Ries  Antoine Delatour  Laurent Lestarquit 《GPS Solutions》2007,11(3):159-171

Spectrum limitations for navigation systems require that the various navigation signals broadcast by the Galileo system must be combined and must utilize bandwidth-efficient modulations. At the L1 band, one of the most important questions is how to combine all the Open Service signals and the Public Regulated Service signal at the payload level, while maintaining good performance at reception. The Interplex modulation, a particular phase-shifted-keyed/phase modulation (PSK/PM), was chosen to transmit these signals because it is a constant-envelope modulation, thereby allowing the use of saturated power amplifiers with limited signal distortion. The Interplex modulation was also taken as baseline at the E6 band to transmit the three channels and the services associated on the same carrier frequency. At the E5 band, the modulation must combine two different services on a same constant envelope composite signal, while keeping the simplicity of a BOC implementation. The constant envelope Alternate Binary Offset Carrier (ALTBOC) modulation was chosen as the solution to transmit the Galileo E5 band signal. The main objective of this paper is to study these Galileo modulations. After the introduction, the E5 band signals are described, followed by the Alternate BOC modulation which has been chosen to transmit them. The second part describes the general formulation of the Interplex modulation and its key parameters for an optimal multiplexing of the Galileo L1 band signals. Since the Galileo Open Service signals at the L1 band are still not yet completely specified, different test cases are considered and their impact on the resulting choice for the Interplex modulation parameters is exposed.  相似文献   

Redox potential measurements and Mössbauer spectrometry of Fe adsorbed onto Fe (oxyhydr)oxides     

Ewen Silvester  Laurent Charlet  Antoine Géhin  Emmanuelle Liger 《Geochimica et cosmochimica acta》2005,69(20):4801-4815

The redox properties of Fe^II adsorbed onto a series of Fe^III (oxyhydr)oxides (goethite, lepidocrocite, nano-sized ferric oxide hydrate (nano-FOH), and hydrous ferric oxide (HFO)) have been investigated by rest potential measurements at a platinum electrode, as a function of pH (−log₁₀[H⁺]) and surface coverage. Using the constant capacitance surface complexation model to describe Fe^II adsorption onto these substrates, theoretical values of the suspension redox potential (E_H) have been computed, under the assumption that Fe^II adsorption occurs at crystal growth sites of the substrate surface. Good agreement between calculated and experimental E_H values is observed for nano-FOH and HFO, however the redox potentials measured for lepidocrocite and goethite are significantly more oxidizing than predicted. Mössbauer spectroscopic analysis of ⁵⁷Fe^II adsorbed onto HFO and goethite shows that in both cases the adsorbed ⁵⁷Fe^II is incorporated into the crystal structure of the substrate, in broad agreement with the thermodynamic model, but is almost completely oxidized to ⁵⁷Fe^III. The mechanism by which the adsorbed ⁵⁷Fe^II is oxidized is not resolved in this work, but is thought to be due to electron transfer to the substrate, rather than a net oxidation of the suspension. The disagreement between experimental and calculated rest potential measurements in the goethite and lepidocrocite systems is thought to be due to the poor electrochemical equilibration of these suspensions with the platinum electrode, rather than a failure of the thermodynamic model. The model developed for the redox potential of adsorbed Fe^II allows direct assessment of the reactivity of this species towards oxidized pollutants.  相似文献   

Zn and Cu isotopic variations in chondrites and iron meteorites: Early solar nebula reservoirs and parent-body processes   总被引：3，自引：0，他引：3  

Jean-Marc Luck  Dalila Ben Othman 《Geochimica et cosmochimica acta》2005,69(22):5351-5363

High-precision Zn isotopic variations are reported for carbonaceous chondrites (CC), equilibrated (EOC) and unequilibrated (UOC) ordinary chondrites, iron meteorites from the IAB-IIICD (nonmagmatic) and IIIA (magmatic) groups, and metal from the Brenham pallasite. For irons, δ⁶⁵Cu values are also reported. Data have also been obtained on a coarse-grained type-B calcium-, aluminum-rich refractory inclusion (CAI) from Allende and on acid leaches of Allende (CV3), Krymka (LL3), and Charsonville (H6). Variations expressed as δ⁶⁶Zn (deviation in parts per thousand of ⁶⁶Zn/⁶⁴Zn in samples relative to a standard) spread over a range of 0.3‰ for carbonaceous chondrites, 2‰ for ordinary chondrites, and 4‰ for irons.The measured ⁶⁶Zn/⁶⁴Zn, ⁶⁷Zn/⁶⁴Zn, and ⁶⁸Zn/⁶⁴Zn ratios vary linearly with mass difference and define a common isotope fractionation line with terrestrial samples, which demonstrates that Zn was derived from an initially single homogeneous reservoir. The δ⁶⁶Zn values are correlated with meteorite compositions and slightly decrease in the order CI, CM, CV-CO, and to UOC. The isotopically light Zn of Allende CAI and the acid-resistant residues of Allende and Krymka show that the light component is associated with refractory material, presumably minerals from the spinel-group. This, together with the reverse correlation between relative abundances of light Zn isotopes and volatile element abundances, suggests that Zn depletion in planetary bodies with respect to CI cannot be ascribed to devolatilization of CI-like material. These observations rather suggest that refractory material reacted with a gas phase enriched in the lighter Zn isotopes. Alternatively, chondrules with their associated rims should carry a light Zn isotopic signature. The δ⁶⁶Zn values of unequilibrated chondrites are rather uniform, whereas equilibrated chondrites show distinctly more isotopic variability.The values of δ⁶⁵Cu-δ⁶⁶Zn in irons define two trends. The moderate and positively correlated Cu and Zn isotope variations in IIIA and pallasite samples probably reflect crystallization of silicate, sulfide, and solid metal from the liquid metal. The range of δ⁶⁶Zn values of the IAB-IIICD group is large (>3‰) and contrasts with the moderate fractionation of Cu isotopes. We interpret this feature and the negative δ⁶⁶Zn-δ⁶⁵Cu correlation as reflecting mixing, possibly achieved by percolation, between metals from a regolith devolatilized at low temperature (enriched in heavy zinc) and metallic liquids formed within the parent body.  相似文献   

High-resolution δC intratooth profiles in bovine enamel: Implications for mineralization pattern and isotopic attenuation     

Antoine Zazzo  Marie Balasse 《Geochimica et cosmochimica acta》2005,69(14):3631-3642

We present the first high-resolution carbon isotope and carbonate content profiles generated through the thickness of enamel from a steer fed C₃- then C₄-dominant food. Carbonate contents decrease by ∼2 wt% from the enamel surface to the innermost enamel layer, and each carbon isotope profile shows a mixture of enamel portions mineralized over several months. Downward and outward increasing contribution of C₄ food to the enamel δ¹³C values reveal two components of the mineralization gradient: a vertical component from the tip of the tooth crown to the neck, and a horizontal component from the enamel-dentine junction to the outer enamel. We use our results to infer mineralization parameters for bovines and to calculate expected isotopic attenuations for an array of environmental inputs and microsampling strategies, using the model developed by Passey and Cerling [Geochim. Cosmochim. Acta. 66 (2002) 3225-3234]. Although it seems unlikely that any strategy will perfectly isolate discrete time slices, sampling the innermost enamel layer might offer the advantage of significantly reducing the isotope damping that would become independent of the structure of the input signal.  相似文献   

Does sediment resuspension by storms affect the fate of polychlorobiphenyls (PCBs) in the benthic food chain? Interactions between changes in POM characteristics, adsorption and absorption by the mussel Mytilus galloprovincialis   总被引：1，自引：0，他引：1  

Franois Charles  Susanna Lopez-Legentil  Antoine Grmare  Jean Michel Amouroux  Martin Desmalades  Gilles Vtion  Karine Escoubeyrou 《Continental Shelf Research》2005,25(19-20):2533

Environmental parameters and gross sedimentation rates (GSR) were monitored at a fixed site located in the Bay of Banyuls-sur-Mer (NW Mediterranean), between March 1997 and April 1998, together with the main biochemical characteristics of both sedimenting and sedimented particulate organic matter (POM). Three storms which occurred during this time period resulted in natural sediment resuspension. This is indicated by the corresponding increase in GSR and a decrease in the enzymatically hydrolysable amino acids/totally hydrolysable amino acids ratio (EHAA/THAA), within the sedimenting POM. Only the strongest storm resulted in (1) a transitory increase in fine-grained particles, (2) concomitant increases in organic carbon, carbohydrates, lipids and THAA, and (3) a decrease in the EHAA/THAA ratio in surficial sediments. For most of the assayed parameters, the values recorded after the December 1997 storm corresponded to extremes for the whole period under study. This emphasises the role of storms in controlling the characteristics of sedimented and sedimenting POM.Ten sediment types, with contrasting biochemical characteristics, were selected for experiments; these were based on the results of the monitoring survey and were used during adsorption and absorption experiments involving ¹⁴C tetrachlorobiphenyl (TCB). Adsorption rates differed significantly between the sediment types, but did not correlate with any of the assayed biochemical parameters. Absorption efficiency by the mussel Mytilus galloprovincialis also differed between the sediment types; it correlated positively with all the assayed biochemical parameters, except lipids. Comparison between the magnitudes of the increase in GSR, together with the decrease in absorption efficiency during resuspension events, suggests that resuspension tends to enhance the transfer of organic pollutants in the benthic food chain.  相似文献   

Evolution of particle size and concentration in the Rhône river mixing zone: : influence of salt flocculation     

Antoine Thill  Stphane Moustier  Jean-Marie Garnier  Claude Estournel  Jean-Jacques Naudin  Jean-Yves Bottero 《Continental Shelf Research》2001,21(18-19)

The salt induced flocculation phenomenon is often proposed as a major mechanism influencing the deposition of the suspended matter near the mouth of major rivers. However, depending on the particular mixing conditions between fresh water and marine water and on suspended solids (SS) reactivity, salt induced aggregation may be a minor factor controlling fast deposition of SS. This work combines field studies and laboratory experiments in order to assess the importance of salt induced flocculation in the case of the saltwedge estuary of the Rhône river. Sampling of the mixing zone has been performed in contrasted hydrodynamic conditions from a low water discharge period (500 m³ s⁻¹) to a small flood event (2400 m³ s⁻¹) for particle counting and salinity measurements. Through laboratory experiments, it is shown that the Rhône river particulate matter has a poor average reactivity regarding salt induced flocculation. Considering the hydrodynamics of the estuary, we show that the evolution of the concentration of larger particles (>5 μm) can be explained by settling and dilution. In contrast, the smallest measured fraction (2–5 μm) shows a more complex behavior and settling processes alone cannot explain the observed particle concentrations during the field studies. Four hypotheses are discussed for explaining the 2–5 μm particle concentration evolutions.  相似文献   

Spatial patterns of water surface topography at a river confluence     

Pascale M. Biron  Antoine Richer  Alistair D. Kirkbride  Andr G. Roy  Sangsoo Han 《地球表面变化过程与地形》2002,27(9):913-928

Understanding flow structures in river confluences has largely been the product of interpretations made from measured flow velocity data. Here, we turn the attention to the investigation of the patterns of both the average and standard deviations of the micro‐topography of the water surface at an asymmetrical natural discordant confluence for different flow conditions. Water surface topography is measured using a total station to survey the position of a reflector mounted on a custom‐built raft. To limit error problems related to changes in the water level, measurements are taken and analysed by cross‐stream transects where five water surface profiles are taken before moving to the next transect. Three‐dimensional numerical simulations of the flow dynamics at the field site are used to examine predicted water surface topography for a steady‐state situation. The patterns are interpreted with respect to flow structure dynamics, visual observations of boils, and bed topography. Results indicate that coherent patterns emerge at the water surface of a discordant bed confluence for different flow conditions. The zone of stagnation and the mixing layer are characterized by super‐elevation, a lateral tilt is present at the edge of the mixing layer, and a zone of super‐elevation is present on the tributary side at the downstream junction corner. The latter seems associated with periodical upwelling and is not present in the numerical simulations that do not take into account instantaneous velocity fluctuations. Planform curvature, topographic steering related to the tributary mouth bar, and turbulent structures associated with the mixing layer all play a key role in the pattern of both the average and standard deviation of the water surface topography at confluences. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献