Experimentally-controlled carbon and oxygen isotope exchange between bioapatites and water under inorganic and microbially-mediated conditions     

Antoine Zazzo  Christophe Lécuyer  André Mariotti 《Geochimica et cosmochimica acta》2004,68(1):1-12

Modern bone and enamel powders have reacted at 301 K with ¹³C- and ¹⁸O-labelled waters under inorganic and microbial conditions. The aim of the study is to investigate the resistance of stable isotope compositions of bioapatite carbonate (δ¹³C, δ¹⁸Oc) and phosphate (δ¹⁸Op) to isotopic alteration during early diagenesis. Rapid and significant carbon and oxygen isotope changes were observed in the carbonate and phosphate fractions of bone apatite before any detectable change occurred in the crystallinity or organic matter content. These observations indicate that chemical alterations of bone apatite are likely to start within days of death. Enamel crystallites are much more resistant than bone crystallites, but are not exempt of alteration. Non removable carbon and oxygen isotope enrichments were measured in the carbonate phase of bone (50-90%) and enamel (40%) after the acetic acid treatment. This result indicates that a significant part of ¹³C and ¹⁸O-labelled coming from the aqueous fluid has been durably incorporated into the apatite structure, probably through isotopic exchange or secondary carbonate apatite precipitation. As a result, acetic acid pre-treatments that are currently used to remove exogenous material by selective dissolution, are not adequate to restore pristine δ¹³C and δ¹⁸Oc values of fossil apatites. Under inorganic conditions, kinetics of oxygen isotope exchange are 10 times faster in carbonate than in phosphate. On the opposite, during biologically-mediated reactions, the kinetics of oxygen isotope exchange between phosphate and water is, at least, from 2 to 15 times faster than between carbonate and water. Enamel is a more suitable material than bone for paleoenvironmental or paleoclimatical reconstructions, but interpretations of δ¹⁸Op or δ¹³C values must be restricted to specimens for which no or very limited trace of microbial activity can be detected.  相似文献   

The impact of internal waves on upper continental slopes: insights from the Mozambican margin (southwest Indian Ocean)     

Elda Miramontes  Gwenael Jouet  Estelle Thereau  Miguel Bruno  Pierrick Penven  Charline Guerin  Pascal Le Roy  Laurence Droz  Stephan J. Jorry  F. Javier Hernández-Molina  Antoine Thiéblemont  Ricardo Silva Jacinto  Antonio Cattaneo 《地球表面变化过程与地形》2020,45(6):1469-1482

Evidences of sedimentation affected by oceanic circulation, such as nepheloid layers and contourites are often observed along continental slopes. However, the oceanographic processes controlling sedimentation along continental margins remain poorly understood. Multibeam bathymetry and high-resolution seismic reflection data revealed a contourite depositional system in the Mozambican upper continental slope composed of a contourite terrace (a surface with a gentle seaward slope dominated by erosion) and a plastered drift (a convex-shape sedimentary deposit). A continuous alongslope channel and a field of sand dunes (mainly migrating upslope), formed during Holocene, were identified in the contourite terrace at the present seafloor. Seismic reflection data of the water column show internal waves and boluses propagating in the pycnocline near the upper slope. The channel and the dunes are probably the result of the interaction of the observed internal waves with the seafloor under two different conditions. The alongslope channel is located in a zone where intense barotropic tidal currents may arrest internal solitary waves, generating a hydraulic jump and focused erosion. However, upslope migrating dunes may be formed by bottom currents induced by internal solitary waves of elevation propagating landwards in the pycnocline. These small-scale sedimentary features generated by internal waves are superimposed on large-scale contouritic deposits, such as plastered drifts and contourite terraces, which are related to geostrophic currents. These findings provide new insights into the oceanographic processes that control sedimentation along continental margins that will help interpretation of palaeoceanographic conditions from the sedimentary record. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd  相似文献   

Linking uplift,erosion, and sedimentation using landscape evolution models: Madagascar since the Late Cretaceous     

Ruohong Jiao  Jean Braun  Antoine Delaunay  Cécile Robin  François Guillocheau 《地球表面变化过程与地形》2023,48(1):215-229

We present a study to estimate the large-scale landscape history of a continental margin, by establishing a source-to-sink volume balance between the eroding onshore areas and the offshore basins. Assuming erosion as the primary process for sediment production, we strive to constrain a numerical model of landscape evolution that balances the volumes of eroded materials from the continent and that deposited in the corresponding basins, with a ratio imposed for loss of erosion products. We use this approach to investigate the landscape history of Madagascar since the Late Cretaceous. The uplift history prescribed in the model is inferred from elevations of planation surfaces formed at various ages. By fitting the volumes of terrigenous sediments in the Morondava Basin along the west coast and the current elevation of the island, the landscape evolution model is optimized by constraining the erosion law parameters and ratios of sediment loss. The results include a best-fit landscape evolution model, which features two major periods of uplift and erosion during the Late Cretaceous and the middle to late Cenozoic. The model supports suggestions from previous studies that most of the high topography of the island was constructed since the middle to late Miocene, and on the central plateau the erosion has not reached an equilibrium with the high uplift rates in the late Cenozoic. Our models also indicate that over the geological time scale a significant portion of materials eroded from Madagascar was not archived in the offshore basin, possibly consumed by chemical weathering, the intensity of which might have varied with climate.  相似文献