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81.
82.
Jean-Marie Gamier Jean-Marie Martin Jean-Marie Mouchel Alain J. Thomas 《Marine Chemistry》1991,36(1-4)
The reactivity of the Rhône estuarine suspended matter is investigated through three operational parameters: the heat of immersion in water (HI), the ammonium saturation index (ASI) and the specific surface area (SSA). The two former parameters are highly correlated for samples collected both in surface river water and in its plume water and in a deeper nepheloid layer. Using both ASI and HI theoretical contributions of each main individual suspended matter component, it is shown that actual and calculated HI values are in agreement, whereas measured ASI values are significantly lower than those calculated. Surface normalization of these reactive properties is discussed on the basis of the SSA measured by the (BET) N2 adsorption. This evaluation, on freeze-dried suspended matter, appears to underestimate the actual particulate reactive surface area in the natural environment; indeed, it is shown that the ammonium ion surfacial density obtained from ASI and SSA data is unrealistically high.To verify that HI and ASI may be considered as criteria for the surface potential reactivity of particles, it has been attempted to relate these parameters and the extent of sorption of radioactive tracer, which is either discharged in the Rhone river or introduced in a batch experiment. Relationships between both ASI and HI and the content of 54Mn, 60Co, 65Zn, 109Cd and 137Cs, which are established for some of them, suggest that HI and ASI are useful indicators of particulate affinity for certain metals. 相似文献
83.
Causes and consequences of bimodal grain-size distribution of tephra fall deposited during the August 2006 Tungurahua eruption (Ecuador) 总被引:2,自引:2,他引:0
Julia Eychenne Jean-Luc Le Pennec Liliana Troncoso Mathieu Gouhier Jean-Marie Nedelec 《Bulletin of Volcanology》2012,74(1):187-205
The violent August 16–17, 2006 Tungurahua eruption in Ecuador witnessed the emplacement of numerous scoria flows and the deposition
of a widespread tephra layer west of the volcano. We assess the size of the eruption by determining a bulk tephra volume in
the range 42–57 × 106 m3, which supports a Volcanic Explosivity Index 3 event, consistent with calculated column height of 16–18 km above the vent
and making it the strongest eruptive phase since the volcano’s magmatic reactivation in 1999. Isopachs west of the volcano
are sub-bilobate in shape, while sieve and laser diffraction grain-size analyses of tephra samples reveal strongly bimodal
distributions. Based on a new grain-size deconvolution algorithm and extended sampling area, we propose here a mechanism to
account for the bimodal grain-size distribution. The deconvolution procedure allows us to identify two particle subpopulations
in the deposit with distinct characteristics that indicate dissimilar transport-depositional processes. The log-normal coarse-grained
subpopulation is typical of particles transported downwind by the main volcanic plume. The positively skewed, fine-grained
subpopulation in the tephra fall layer shares close similarities with the elutriated co-pyroclastic flow ash cloud layers
preserved on top of the scoria flow deposits. The area with the higher fine particle content in the tephra layer coincides
with the downwind prolongation of the pyroclastic flow deposits. These results indicate that the bimodal distribution of grain
size in the Tungurahua fall deposit results from synchronous deposition of lapilli from the main plume and fine ash elutriated
from scoria flows emplaced on the western flank of the volcano. Our study also reveals that inappropriate grain-size data
processing may produce misleading determination of eruptive type. 相似文献
84.
Perrin Mireille Plenier Guillaume Dautria Jean-Marie Cocuaud Emmanuel Prévot Michel 《Marine Geophysical Researches》2000,21(3-4):181-194
Thirty-two flows (247 cores) were sampled in the V1 (Geotimes) and V2 (Lasail) volcanic units of the Semail ophiolite, Oman (Aswad, Fizh, Hilti, Sarami, Wuqbah, and Tayin massifs). Paleomagnetic analysis of the samples was complicated by a large overlap of the two components of magnetization carried by the rocks: a crystalline remanent magnetization (CRM) acquired in the present day field, probably during weathering, and an older CRM probably produced by oxidation of the original titanomagnetites during hydrothermal event(s). If the magnetization carried by the V1 samples was acquired during the hydrothermal event related to the emplacement of these lava, e.g., during and/or shortly after cooling, the tectonic unity of the northern domain has to be questioned and a differential rotation considered between the Aswad and Hilti-Sarami massifs but, by the time of emplacement of the V2 series, this northern area seems to behave as one large unit. As only one set of data is available for the southern Tayin-Sumail massif, it is premature but a possible relative rotation on the order of 90° can be suspected between the Hilti-Sarami and Tayin-Sumail massifs, rotation which would have occurred after emplacement of the V2 series. 相似文献
85.
José Manuel Tunqui Neira Vazken Andréassian Gaëlle Tallec Jean-Marie Mouchel 《水文研究》2021,35(11):e14428
Concentration–discharge ( ) relationships are widely used to assess the link between hydrological and biogeochemical processes at the catchment scale. relationships are mainly calibrated using mono-objective methods to represent, either concentrations or discharge-weighted concentrations (i.e., load). Based on its wide use in hydrological modelling, we test a multi-objective calibration for the relationship parameters, using both concentration and load, and compare it to a mono-objective calibration applied on either concentrations or load. This work is carried out on a high-frequency dataset (ORACLE-Orgeval Observatory, France). Our findings show that the multi-objective calibration yield a better representation of relationships parameters during the high and low-flow events. The multi-objective calibration can be used for all forms of relationships and avoids issues of under-representation of dilution processes characterized by high-discharge, low-concentration periods. 相似文献
86.
Laurie Biscara Thierry MulderPhilippe Martinez François BaudinHenri Etcheber Jean-Marie JouanneauThierry Garlan 《Marine and Petroleum Geology》2011,28(5):1061-1072
In order to define the nature and distribution of the organic matter (OM) preserved in the modern Ogooué deep sea turbidite system (Gabon), bulk geochemical techniques (Rock-Eval pyrolysis, elemental and isotopic analyses) and palynofacies were applied to three piston cores collected in the Cape Lopez Canyon and lobe and on the continental slope, north of the canyon.The hemipelagic sedimentation in the study area is characterized by high accumulations of well-preserved OM (∼2-3 wt. TOC %). Bulk geochemical and palynofacies analysis indicate both a marine and terrestrial origin of the OM. Contribution of the marine source is higher on the slope than in the canyon and lobe.OM accumulation in turbidites is strongly controlled by the combined influence of the Cape Lopez Canyon and littoral drift. In the canyon and lobe, turbidites show generally low TOC content (0.5 wt. %) and OM is oxidized. The origin of the OM is interpreted as both marine and terrestrial, with a higher contribution of continental source versus marine source. The low TOC contents are due to the large siliciclastic fraction transported by the littoral drift and diverted in the Cape Lopez Canyon during high energy processes (e.g. storms) which tend to dilute the OM in the turbidites. Transport by long-shore currents and/or turbiditic flows leads to oxidation of the OM.On the continental slope located north of the Cape Lopez Canyon, large amounts of OM are deposited in turbidites (up to 14 wt. %). The OM is predominantly derived from terrestrial land plants and has not been subjected to intense oxidation. These deposits are characterized by high hydrocarbon potential (up to 27 kg HC/t rock), indicating a good potential as gas-prone source rock. Because Cape Lopez Canyon captures a significant part of the sediment transported by the littoral drift, the siliciclastic sedimentary flux is reduced north of the canyon; OM is thus concentrated in the turbidites. Variation in TOC content within turbidite laminae can be explained by the burst and sweep deposition process affecting the boundary layer of the turbulent flow.This study confirms that gravity flows play a preponderant role in the accumulation and preservation of OM in deep water and that deep sea turbidite systems could be regarded as an environment where organic sedimentation occurs. 相似文献
87.
Mohamed Younes Ahmed Said Taibi Hanène Souli Jean-Marie Fleureau 《Geotechnical and Geological Engineering》2013,31(4):1335-1348
The use of electro-osmosis in geotechnical engineering has been considered since 1930. Its application has been tested in several sectors like the fight against rising damp in porous materials, the consolidation of soils as well as the remediation of the soils contaminated by oil and heavy metals, etc. The paper presents an experimental study of the electrokinetic phenomena resulting from the application of an electric field to argillaceous sandstones. The electroosmotic tests required the development of a completely new experimental device composed of a confining cell, of a system of measurement and control of the pH of the electrolyte near the electrodes, of a system of control and measurement of the voltage and current at the edges of the sample, and of a system of measurement of inlet (anodic) and outlet (cathodic) flows. Various boundary conditions are considered with and without control of pH. In addition, a micro structural modelling of the electrokinetic phenomena makes it possible to quantify the electro osmotic conductivity with a good agreement with experiments. 相似文献
88.
Brigitte Schmieder Nicole Mein Yuanyong Deng Cristiana Dumitrache Jean-Marie Malherbe Joachim Staiger E. E. Deluca 《Solar physics》2004,223(1-2):119-141
This paper is focused on the formation of two filaments in a complex center of decaying active regions (AR 8329 and AR 8326), located in the northern hemisphere. The observations were obtained in Hα by the Multi-channel Subtractive Double Pass spectrograph (MSDP mounted on the German telescope VTT in Tenerife) and EUV lines with TRACE (Transition Region And Corona Explorer). High Doppler shifts are found to be related to the ends of filament segments where canceling magnetic fields are also located (as seen on magnetograms from Big Bear Solar Observatory). At these locations, velocities along the line of sight, derived by using a cloud model method reach −20 km s−1, the segments of filaments merge and frequently a time-related sub-flare is observed by TRACE. The chirality of the filament segments has been determined by different methods: the segments of dextral chirality join together and form a long dextral filament, and a single filament of sinistral chirality forms end to end with the dextral filament but does not merge with it. Assuming a model of twisted flux tube for filament material, we suggest that the dextral filament has negative helicity and a relationship between its formation and the close by sunspot with the same sign of helicity. 相似文献
89.
Eric H. Oelkers Jacques Schott Jean-Marie Gauthier Teresa Herrero-Roncal 《Geochimica et cosmochimica acta》2008,72(20):4948-4961
Steady-state muscovite dissolution rates have been measured at temperatures from 60 to 201 °C and 1 ? pH ? 10.3 as a function of reactive solution K, Si, and Al concentration. The pegmatitic muscovite used in these experiments has a composition consistent with (Na0.09, K0.86)Fe0.05Al2.92Si3.05O10(OH1.95, F0.06). All experiments were performed in titanium mixed-flow reactors. All experiments were performed at far-from-equilibrium conditions with respect to muscovite. All reactive solutions were undersaturated with respect to secondary product phases other than for some experiments which were supersaturated with respect to bohemite and diaspore; steady-state dissolution was stoichiometric for all experiments that were undersaturated with respect to these phases.The variation of rates with reactive solution composition depends on the solution pH. At pH ? 7 rates were found to decrease significantly with increasing reactive fluid Al activity but be independent of aqueous SiO2 activity. pH < 7 rates measured in the present study from 60 to 175 °C are consistent with
90.
Aurélia Mouret Pierre Anschutz Pascal Lecroart Gwénaëlle Chaillou Christelle Hyacinthe Jonathan Deborde Frans J. Jorissen Bruno Deflandre Sabine Schmidt Jean-Marie Jouanneau 《Geo-Marine Letters》2009,29(3):133-149
Manganese is a major redox reactive element of benthic metabolism. We have built a database of existing knowledge on the benthic
geochemistry of Mn in the Bay of Biscay, in order to comprehensively assess the behaviour of Mn in a variety of environments
during early diagenesis. The database contains vertical profiles of particulate and dissolved Mn species of 59 cores collected
during 17 cruises between 1997 and 2006 at nine stations positioned between 140 and 4,800 m water depths. At all studied stations,
Mn species follow the conventional distribution, where Mn(III,IV) species are enriched in the oxic layer, and dissolved Mn
is present in the anoxic sediments. A minor part of Mn-oxides originates from sedimenting particles. The major part is of
diagenetic origin, and derives from the oxidation of upward-diffusing dissolved Mn(II). Mn-oxide inventories are higher at
the deeper stations than at the shallower ones. This difference cannot be attributed to different sources of sedimenting particles,
but it must depend on sedimentation rate and diagenetic processes. At depth, dissolved Mn(II) concentrations are constant.
This probably reflects equilibrium with an authigenic Mn(II) phase, which is the ultimate phase into which Mn is fossilized.
The Mn content of deeper anoxic sediments is similarly low in all the cores studied, associated with corresponding trends
of Mn content in sedimenting particles of the Bay of Biscay. Bioturbation, rather than redox oscillations, can convey Mn(III,IV)
species downwards into the anoxic sediments where they are reduced, associated with a peak of dissolved Mn. Because dissolved
Mn(II) is re-oxidized when it diffuses towards the oxic layer, the inventory of the diagenetic Mn(III,IV) phase remains at
steady state, especially at stations where the oxic layer is thick. It then becomes possible to calculate the residence time
of diagenetic Mn(III,IV) particles within the oxic layer, using the upward-directed flux of pore water Mn(II). By applying
this residence time to the accumulation of sediments within the oxic layer, we obtain the sediment mass accumulation rate.
The values calculated for the sediments of the Bay of Biscay fit well with accumulation rates obtained from radionuclides
or sediment traps. The method has also been validated with data collected in other marine sedimentary environments.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献