A thermochemical study of glasses and crystals along the joins silica-calcium aluminate and silica-sodium aluminate     

Alexandra Navrotsky  Gilles Peraudeau  Paul McMillan  Jean-Pierre Coutures 《Geochimica et cosmochimica acta》1982,46(11):2039-2047

Enthalpies of solution in molten 2PbO · B₂O₃ at 985 K are reported for series of glasses xCa_0.5AlO₂-(1?x)SiO₂ (O ≤ x ≤ 0.99) and xNaAlO₂-(1?x)SiO₂ (0 ≤ x ≤ 0.56). The data are compared to values for the corresponding crystalline aluminosilicates and to preliminary data for systems containing KAlO₂ and Mg_0.5AlO₂. The enthalpies of mixing of glasses become more exothermic with increasing basicity of the mono- or divalent oxide. The tendency toward immiscibility on the silica-rich side, indicated by the shape of the heat of mixing curve between x = 0 and x = 0.4, is pronounced in the calcium aluminate system, but not in the sodium aluminate system. The shape of the heat of mixing curve, which is roughly symmetrical about x = 0.5, can be rationalized in terms of glass structure by considering essentially random substitution of Si and Al on a continuous three dimensional tetrahedral framework, with stabilization arising from electrostatic interactions between aluminum and the nonframework cation balancing the destabilizing effects arising from perturbation of the aluminosilicate framework by the nonframework cation. These trends are consistent with the variation of physical properties of aluminosilicate melts.  相似文献   

Naturally Enhanced Ion-Acoustic Spectra And Their Interpretation     

Francis Sedgemore-Schulthess  Jean-Pierre St. Maurice 《Surveys in Geophysics》2001,22(1):55-92

Incoherent scatter radars are designed to detect scatter from thermalfluctuations in the ionosphere. These fluctuations contain, among other things,features associated with ion-acoustic waves driven by random motions within theplasma. The resulting spectra are generally broad and noisy, but neverthelessthe technique can, through a detailed analysis of spectra, be used to measure arange of physical parameters in the Earth's upper atmosphere, and provides apowerful diagnostic in studies of magnetosphere-ionosphere coupling,thermosphere dynamics and the geospace environment in general. In recent yearsthere has been much interest in naturally occurring (as opposed to artificiallystimulated) enhanced ion-acoustic spectra seen in the auroral zone andcusp/cleft region. A study of the plasma instability processes that lead tosuch spectra will help us to better understand auroral particle acceleration,wave-particle and wave-wave interactions in the ionosphere, and theirassociation with magnetospheric processes. There is now a substantial body ofliterature documenting observations of enhanced ion-acoustic spectra, but thereremains controversy over generation mechanisms. We present a review ofliterature documenting observations of naturally enhanced ion-acoustic spectra,observed mainly along the geomagnetic field direction, along with a discussionof the theories put forward to explain such phenomena.  相似文献   

Application de méthodes d’analyse biochimique à un problème taxonomique: les Corégones du lac de Neuchâtel1, 2, 4     

Jean-Pierre Par Bargetzi 《Aquatic Sciences - Research Across Boundaries》1960,22(2):641-758

Sans résumé Travail réalisé avec l’appui du Fonds national suisse de la Recherche. La rédaction du présent travail est antérieure au mémoire deDottrens [254]³). La parution du texte de cet auteur a très exactement co?ncidé avec la présentation de notre thèse. Ces deux recherches ont été accomplies indépendamment. D’après les conclusions deDottrens, les Corégones du lac de Neuchatel doivent désormais être désignés par Le mot ?ichtyologie? et les termes de la même famille sont orthographiés avec un seul ?h? en accord avec une décision récente de l’Académie.  相似文献   

Deformation pattern in a heterogeneous material: Folded and cleaved sedimentary cover immediately overlying a crystalline basement (Oisans, French Alps)     

Jean-Pierre Gratier  Pierre Vialon 《Tectonophysics》1980,65(1-2)

Particularly well exposed structures in folded and cleaved sedimentary cover immediately overlying a crystalline basement have been studied. Chemical analysis (X.R.F. and microprobe) reveal pressure solution process and give the possibilities of measurement of mass transfer. Study of fluid inclusion veins has determined the temperature pressure conditions: thermal effect of the basement and decrease of temperature and pressure with the age of various synkinematic veins.Characteristic examples of the behaviour of a heterogeneous material during coaxial and non-coaxial deformation are shown:

1. (1) Successive different asymmetrical folds, various cleavages and fractures appear in a shear zone parallel to the main fabric with variations of thickness and rock behaviour.

2. (2) Evolution of cleavage in such a shear zone (with or without slipping) is linked to the relations between the rotation of contraction direction and the rate of the cleavage process.

3. (3) Fold axes changed from the horizontal y direction to the vertical (or E—W transversal to the crystalline massif) X direction, with increase of the (X/Z) and (X/Y) ratios (obtained by fossils and reconstructed fold shape). This strain is always heterogeneous and the most deformed zone frequently evolves to discontinuities with slip.

4. (4) Indentation exists on all scale: from hard object (100 μ, with parenthesis form of pressure solution cleavage apparent on map distribution of various element) to basement block (with variation of strain value in the indented cover).

A model of the evolution of the deformation of sedimentary cover immediately overlying a crystalline basement is given in conclusion.  相似文献   

Les tremblements de terre en France: J. Vogt (Editeur), Bureau de Recherches Géologiques et Miniéres, Mémoire 96, 1979, 80.00 FF, US $ 20.00     

Jean-Pierre Roth 《Tectonophysics》1980,70(1-2)

  相似文献   

Upper Limit of Iodine Oxide in the Lower Stratosphere     

Irene Pundt  Jean-Pierre Pommereau  Celine Phillips  Eric Lateltin 《Journal of Atmospheric Chemistry》1998,30(1):173-185

It has been suggested that iodine oxides, IOx, could play a significant role in the ozone destruction in the lower stratosphere. To investigate this suggestion, spectra from nine SAOZ uv-visible spectrometer balloon flights were examined for the IO absorption signature between 405 and 450 nm. IO was not detected, either at mid- or high latitude, in the morning or the evening, in summer or winter. An upper limit of 0.2 parts per trillion by volume (pptv) at 20 km and 0.1 pptv at 15 km at the 95% confidence level (2), was derived from the best measurements at 90° SZA at sunset and sunrise. Since a photochemical model shows that 70% of inorganic iodine should be in the form IO at that time, it is concluded that unless iodine chemistry is different from that assumed at the moment, the role of iodine in stratospheric ozone depletion is small.  相似文献   

Uncertainty assessment and analysis of the calibrated parameter values of an urban storm water quality model   总被引：1，自引：0，他引：1  

Eric Gaume  Jean-Pierre Villeneuve  Michel Desbordes 《Journal of Hydrology》1998,210(1-4):38-50

  相似文献   

Experimental study of silica diffusion during metasomatic reactions in the presence of water at 550°C and 1000 bars     

Jean-Pierre Ildefonse  Victor Gabis 《Geochimica et cosmochimica acta》1976,40(3):297-303

Metasomatic reactions between quartz and incompatible oxides or hydroxides were experimentally studied at 550°C and 1000 bars water pressure. Two porous pellets of the initial reagents pressed one against the other were used. Reaction rims in the millimeter range develop at the initial boundary in the oxide pellet. All the experiments show that an important transfer of silica occurs by diffusion in the stationary intergranular solution.The chemical transfer of silica through the intergranular fluid is quantitatively determined by studying the kinetics of growth of the forsterite rim in the system quartz-brucite. The kinetics limiting stage being silica transfer, the experiments allow the determination of the diffusion coefficient of silica through the solution. At 550°C and 1000 bars, a value of 2.4 × 10^?1cm² s¹ is found.This high value shows the importance of chemical diffusion in the intergranular fluid of rocks during metamorphic processes.  相似文献   

Evidence for enhanced hydration on the northern flank of Olympus Mons, Mars     

Giancarlo Bellucci  Joern Helbert  Francesca Altieri  Dennis Reiss  Jean-Pierre Bibring  Stephan van Gasselt  Harald Hoffmann  Yves Langevin  Gerhard Neukum  Franois Poulet 《Icarus》2007,192(2):361-377

In this paper we report about a small region on the northern scarp of Olympus Mons showing an increase of the 3 μm hydration band in the OMEGA spectra, together with low superficial temperatures. Although water ice clouds can occurs on the flank of big martian volcanoes, radiative transfer modeling indicates that atmospheric water ice alone cannot justify the shape of the observed band. A fit of the 1.9–3 μm absorption features is obtained by hypothesizing that the study region consists of a mixture of dust and water ice covered by an optically thin (τ=0.08 at 3 μm) layer of dust. Thermal modeling also suggests that water ice in this region may be stable during most of the martian year due to the saturation of the atmosphere. If water ice is responsible for the observed spectral behavior, it might consist of a number of ice or snow patches possibly deposited in small depressions.  相似文献   

Generation?2 testbed of Fresnel imager: first results on the sky     

Laurent Koechlin  Jean-Pierre Rivet  Paul Deba  Truswin Raksasataya  Thierry Gharsa  Ren?? Gili 《Experimental Astronomy》2011,30(2-3):165-182

  相似文献