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21.
Three tree-ring rainfall reconstructions from China and Korea are used in this paper to investigate the East Asian summer monsoon-related precipitation variation over the past 160 years. Statistically, there is no linear correlation on a year-by-year basis between Chinese and Korean monsoon rainfall, but region-wide synchronous variation on a decadal-scale was observed. More rainfall intervals were 1860–1890, 1910–1925, and 1940–1960, and dry or even drought periods were 1890–1910, 1925–1940, and 1960–present. Reconstructions also display that the East Asian summer monsoon precipitation suddenly changed from more into less around mid-1920. These tree-ring precipitation records were also confirmed by Chinese historical dryness/wetness index and Korean historical rain gauge data.  相似文献   
22.
Summary The lower ultramafic part of the Chalkidiki Ophiolite Complex consists of a successive alternation of chromitite, dunite, and harzburgite, which is repeated periodically in a cyclic manner. This cyclic pattern is consistent with an origin as magmatic cumulates. However, the tectonic fabric superimposed on the cumulate texture of this sequence suggest a solid-state deformation at considerable depth.In the present study, the textural and chemical features of chromite are discussed. The interrelationships between the compositions of chromite, its mode of occurrence as well as the associated silicates are emphasized. It is found that the investigated chromites have properties in common with both podiforn and stratiform chromites. From a geometrical and structural point of view, they are of podiform type. On the other hand, their appreciably high iron content, the strong interdependence between the composition of chromite and the coexisting silicates together with the cryptic layering exhibited by the two mineral groups contrast markedly with podiform chromites.An alternative hypothesis is proposed involving fractional crystallization of an ultrabasic melt introduced to the magma chamber as periodic inflows of essentially the same composition. An upwelling upper-mantle that is subjected to stepwise partial fusion may fulfill these conditions.
Chemismus und Texturen von Chromiten in ultramafischen Gesteinen des Chalkidiki Komplexes, Nordost-Griechenland
Zusammenfassung Der untere, ultramafische Teil des Chalkidiki Komplexes besteht aus einer wechselnden Abfolge von Chromititen, Duniten und Harzburgiten, die sich zyklisch wiederholt. Diese zyklische Abfolge ist in guter Übereinstimmung mit einer Entstehung als magmatische Kumulate. Das tektonische Gefüge, das auf die Kumulat-Texturen überprägt wurde, weist jedoch auf Deformationen in festem Zustand in beträchtlicher Tiefe hin.Die vorliegende Untersuchung befaßt sich mit dem Chemismus und den Texturen der Chromite. Besonderes Interesse wendet sich dabei den Wechselbeziehungen zwischen den Zusammensetzungen, der Art des Vorkommens und den assoziierten Silikaten zu. Dabei zeigt sich, daß die untersuchten Chromite in vieler Hinsicht Ähnlichkeiten sowohl mit podiformen wie mit stratiformen Vorkommen erkennen lassen. Geometrisch und texturell gesehen gehören sie dem podiformen Typ an. Nicht in Einklang damit stehen jedoch die beträchtlichen Eisengehalte sowie die deutlichen Wechselbeziehungen zwischen der Zusammensetzung von Chromit und der koexistierenden Silikate, und schließlich auch der kryptische Lagenbau, den die zwel Mineralgruppen erkennen lassen. Ein genetisches Modell wird vorgeschlagen, das fraktionierte Kristallisation einer ultrabasischen Schmelze von im wesentlichen gleichmäßiger Zusammensetzung vorsieht, die in periodischen Abständen der Magmenkammer zugeführt wurde. Eine Aufwölbung des oberen Mantels, die schrittweiser, partieller Aufschmelzung ausgesetzt ist, könnte diesen Bedingungen entsprechen.


With 11 Figures  相似文献   
23.
A geochemical and end‐member mixing analysis (EMMA) is undertaken in Devil Canyon catchment, located in southern California, to further understanding of watershed behaviour and source water contributions after an acute and extensive wildfire. Physical and chemical transformations in post‐fire watersheds are known to increase overland flow and decrease infiltration, mainly due to formation of a hydrophobic layer at, or near, the soil surface. However, less is known about subsurface flow response in burned watersheds. The current study incorporates EMMA to evaluate and quantify source water contributions before, and after, a catchment affected by wildfires in southern California during the fall of 2003. Pre‐ and post‐fire stream water data were available at several sampling sites within the catchment, allowing the identification of contributing water sources at varying spatial scales. Proposed end‐member observations (groundwater, overland flow, shallow subsurface flow) were also collected to constrain and develop the catchment mixing model. Post‐fire source water changes are more evident in the smaller and faster responding sub‐basin (interior sampling point). Early post‐fire storm events are dominated by overland flow with no significant soil water or groundwater flow contribution. Inter‐storm streamwater in this smaller basin shows an increase in groundwater and a decrease in soil water. In the larger, baseflow‐dominated system, source water components appear less affected by fire. A slight increase in lateral flow is observed with only a slight decrease in baseflow. Changes in the post‐fire flow regimes affect nutrient loading and chemical response of the basin. Relatively rapid recovery of the chaparral ecosystem is evidenced, with active re‐growth and evapotranspiration evidenced by the fourth post‐fire rainy season. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
24.
The spatial and temporal variations of precipitation and runoff for 139 basins in South Korea were investigated for 34 years (1968–2001). The Precipitation‐Runoff Modelling System (PRMS) was selected for the assessment of basin hydrologic response to varying climates and physiology. A non‐parametric Mann–Kendall's test and regression analysis are used to detect trends in annual, seasonal, and monthly precipitation and runoff, while Moran's I is adapted to determine the degree of spatial dependence in runoff trend among the basins. The results indicated that the long‐term trends in annual precipitation and runoff were increased in northern regions and decreased in south‐western regions of the study area during the study period. The non‐parametric Mann–Kendall test showed that spring streamflow was decreasing, while summer streamflow was increasing. April precipitation decreased between 15% and 74% for basins located in south‐western part of the Korean peninsula. June precipitation increased between 18% and 180% for the majority of the basins. Trends in seasonal and monthly streamflow show similar patterns compared to trends in precipitation. Decreases in spring runoff are associated with decreases in spring precipitation which, accompanied by rising temperatures, are responsible for reducing soil moisture. The regional patterns of precipitation and runoff changes show a strong to moderate positive spatial autocorrelation, suggesting that there is a high potential for severe spring drought and summer flooding in some parts of Korea if these trends continue in the future. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
25.
26.
Fall velocity-diameter relationships for four different snowflake types (dendrite, plate, needle, and graupel) were investigated in northeastern South Korea, and a new algorithm for classifying hydrometeors is proposed for distrometric measurements based on the new relationships. Falling ice crystals (approximately 40 000 particles) were measured with a two-dimensional video disdrometer (2DVD) during a winter experiment from 15 January to 9 April 2010. The fall velocity-diameter relationships were derived for the four types of snowflakes based on manual classification by experts using snow photos and 2DVD measurements: the coefficients (exponents) for different snowflake types were 0.82 (0.24) for dendrite, 0.74 (0.35) for plate, 1.03 (0.71) for needle, and 1.30 (0.94) for graupel, respectively. These new relationships established in the present study (PS) were compared with those from two previous studies. Hydrometeor types were classified with the derived fall velocity-diameter relationships, and the classification algorithm was evaluated using 3× 3 contingency tables for one rain-snow transition event and three snowfall events. The algorithm showed good performance for the transition event: the critical success indices (CSIs) were 0.89, 0.61 and 0.71 for snow, wet-snow and rain, respectively. For snow events, the algorithm performance for dendrite and plate (CSIs = 1.0 and 1.0, respectively) was better than for needle and graupel (CSIs = 0.67 and 0.50, respectively).  相似文献   
27.
Floodplain ecosystems are affected by flood dynamics, nutrient supply as well as anthropogenic activities. Heavy metal pollution poses a serious environmental challenge. Pollution transfer from the soil to vegetation is still present at the central location of Elbe River, Germany. The goal of this study was to assess and separate the current heavy metal contamination of the floodplain ecosystem, using spectrometric field and laboratory measurements. A standardized pot experiment with floodplain vegetation in differently contaminated soils provided the basis for the measurements. The dominant plant types of the floodplains are: Urtica dioica, Phalaris arundinacea and Alopecurus pratensis, these were also chemically analysed. Various vegetation indices and methods were used to estimate the red edge position, to normalise the spectral curve of the vegetation and to investigate the potential of different methods for separating plant stress in floodplain vegetation. The main task was to compare spectral bands during phenological phases to find a method to detect heavy metal stress in plants. A multi-level algorithm for the curve parameterisation was developed. Chemo-analytical and ecophysiological parameters of plants were considered in the results and correlated with spectral data. The results of this study show the influence of heavy metals on the spectral characteristics of the focal plants. The developed method (depth CR1730) showed significant relationship between the plants and the contamination.  相似文献   
28.
Past studies suggested that a basin-wide regime shift occurred in 1988–1989, impacting marine ecosystem and fish assemblages in the western North Pacific. However, the detailed mechanisms involved in this phenomenon are still yet unclear. In the Ulleung basin of the East Sea, filefish, anchovy and sardine dominated the commercial fish catches in 1986–1992, but thereafter common squid comprised > 60% of the total catch in 1993–2010. To illuminate the mechanisms causing this dramatic shift in dominant fisheries species, I related changes in depth-specific oceanographic conditions from 0 to 500 m to inter-annual changes in the fish assemblage structure from 1986 to 2010. In the upper layer of 50–100 m depths, water temperature suddenly increased in 1987–1989, and consequently warm-water epi-pelagic species (anchovy, chub mackerel, and common squid) became dominant, while sardine, relatively cold-water epi-pelagic species, nearly disappeared. An annual index of the volume transport by the Korea Strait Bottom Cold Water, originating from the deep water of the Ulleung Basin, displayed a sudden intensification in 1992–1993, accompanied by decreased water temperature and increased water density in the deep water and replacement of dominant bentho-pelagic species from filefish, warm-water species, to herring and cod, cold-water species. The results suggest that climate-driven oceanic changes and the subsequent ecological impacts can occur asynchronously, often with time lags of several years, between the upper and the deep layer, and between epi-pelagic and deepwater fish assemblages.  相似文献   
29.
This study examined the chemical speciation and mobility of As and heavy metals in a tailings impoundment in Samsanjeil mine located in Gosung, Korea, as well as the factors affecting them. XRD, SEM, and 5-step sequential extraction were used to examine the samples at two sampling sites (NN and SN sites). The pH of the tailings decreased with increasing depth at the NN site (from 7.2 to 2.8), whereas no significant differences were observed at the SN site (8.1–8.8). The samples at the SN site showed a larger amount of calcite than those at the NN site, indicating that calcite plays an important role buffering the pH in the study sites. Jarosite was found only at the lower part of the NN site, where calcite was not found. The mineralogical observation of jarosite and calcite was also confirmed by SEM. The concentrations of As and heavy metals in the tailings were as follows: Cu > As > Zn > > Pb > Co > Cr > Ni > Cd. The total concentrations of Ni, Zn, Co, and Cd were higher at the SN site than those at the NN site. On the other hand, the concentrations of As and Cr existing as oxyanions were higher at the NN site, which can be explained by the mobility changes of those elements affected by pH variations. At the NN site, the fractions of heavy metals bound to the Fe/Mn oxides, except for As and Cr, decreased, and Cu, Zn, and Co showed an increasing fraction of exchangeable metals with increasing depth. This suggests that the pH and resulting surface charge of minerals, such as goethite and jarosite, are the dominant factors controlling the chemical speciation of metals. These results highlight the importance of mineralogy in controlling the mobility and possible bioavailability of heavy metals in tailings.  相似文献   
30.
Titanium- and water-rich metamorphic olivine (Fo 86–88) is reported from partially dehydrated serpentinites from the Voltri complex, Ligurian Alps. The rocks are composed of mostly antigorite and olivine in addition to magnetite, chlorite, clinopyroxene and Ti-clinohumite. In situ secondary ion mass spectrometry (SIMS) data show that metamorphic olivine has very high and strongly correlated H2O (up to 0.7 wt%) and TiO2 contents (up to 0.85 wt%). Ti-rich olivine shows colourless to yellow pleochroism. Olivine associated with Ti-clinohumite contains low Ti, suggesting that Ti-rich olivine is not the breakdown product of Ti-clinohumite. Fourier transform infrared spectroscopy (FTIR) absorption spectra show peaks of serpentine, Ti-clinohumite and OH-related Si vacancies. Combining FTIR and SIMS data, we suggest the presence of clustered planar defects or nanoscale exsolutions of Ti-clinohumite in olivine. These defects or exsolutions contain more H2O (x ~ 0.1 in the formula 4Mg2SiO4·(1?x)Mg(OH,F)2·xTiO2) than Ti-clinohumite in the sample matrix (x = 0.34–0.46). In addition to TiO2 and H2O, secondary olivine contains significant Li (2–60 ppm), B (10–20 ppm), F (10–130 ppm) and Zr (0.9–2.1 ppm). It is enriched in 11B (δ11B = +17 to +23 ‰). Our data indicate that secondary olivine may play a significant role in transporting water, high-field strength and fluid-mobile elements into the deeper mantle as well as introduce significant B isotope anomalies. Release of hydrogen from H2O-rich olivine subducted into the deep mantle may result in strongly reduced mantle domains.  相似文献   
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