On a global scale, peridotitic garnet inclusions in diamonds from the subcratonic lithosphere indicate an evolution from strongly sinusoidal REEN, typical for harzburgitic garnets, to mildly sinusoidal or “normal” patterns (positive slope from LREEN to MREEN, fairly flat MREEN–HREEN), typical for lherzolitic garnets. Using the Cr-number of garnet as a proxy for the bulk rock major element composition it becomes apparent that strong LREE enrichment in garnet is restricted to highly depleted lithologies, whereas flat or positive LREE–MREE slopes are limited to less depleted rocks. For lherzolitic garnet inclusions, there is a positive relation between equilibration temperature, enrichment in MREE, HREE and other HFSE (Ti, Zr, Y), and decreasing depletion in major elements. For harzburgitic garnets, relations are not linear, but it appears that lherzolite style enrichment in MREE–HREE only occurs at temperatures above 1150–1200 °C, whereas strong enrichment in Sr is absent at these high temperatures. These observations suggest a transition from melt metasomatism (typical for the lherzolitic sources) characterized by fairly unfractionated trace and major element compositions to metasomatism by CHO fluids carrying primarily incompatible trace elements. Melt and fluid metasomatism are viewed as a compositional continuum, with residual CHO fluids resulting from primary silicate or carbonate melts in the course of fractional crystallization and equilibration with lithospheric host rocks.
Eclogitic garnet inclusions show “normal” REEN patterns, with LREE at about 1× and HREE at about 30× chondritic abundance. Clinopyroxenes approximately mirror the garnet patterns, being enriched in LREE and having chondritic HREE abundances. Positive and negative Eu anomalies are observed for both garnet and clinopyroxene inclusions. Such anomalies are strong evidence for crustal precursors for the eclogitic diamond sources. The trace element composition of an “average eclogitic diamond source” based on garnet and clinopyroxene inclusions is consistent with derivation from former oceanic crust that lost about 10% of a partial melt in the garnet stability field and that subsequently experienced only minor reenrichment in the most incompatible trace elements. Based on individual diamonds, this simplistic picture becomes more complex, with evidence for both strong enrichment and depletion in LREE.
Trace element data for sublithospheric inclusions in diamonds are less abundant. REE in majoritic garnets indicate source compositions that range from being similar to lithospheric eclogitic sources to strongly LREE enriched. Lower mantle sources, assessed based on CaSi–perovskite as the principal host for REE, are not primitive in composition but show moderate to strong LREE enrichment. The bulk rock LREEN–HREEN slope cannot be determined from CaSi–perovskites alone, as garnet may be present in these shallow lower mantle sources and then would act as an important host for HREE. Positive and negative Eu anomalies are widespread in CaSi–perovskites and negative anomalies have also been observed for a majoritic garnet and a coexisting clinopyroxene inclusion. This suggests that sublithospheric diamond sources may be linked to old oceanic slabs, possibly because only former crustal rocks can provide the redox gradients necessary for diamond precipitation in an otherwise reduced sublithospheric mantle. 相似文献
In a diamond from New South Wales (Australia), cubic and octahedral growth sectors, as identified by cathodoluminescence (CL), show slight differences in N-contents of 29 and 42 ppm respectively but no significant differences in either δ13C, δ15N and nitrogen aggregation state with values at +1.96‰, +19.4‰, and 25% Type IaAB aggregation, respectively.Two gem cubes from the Orapa kimberlite (Botswana) were studied by CL revealing a nonfaceted cubic growth. Accordingly, nine other gem cubes were combusted and yielded δ13C-values from -5.33‰ to -6.63‰, δ15N from -1.0‰ to -5.5‰, and nitrogen contents from 914 to 1168 ppm, with nitrogen aggregation state being only Type IaA (zero % B). The gem cubes show striking similarities to fibrous/coated diamonds, not only in both δ13C ranges (less than 3‰ from -5 to -8‰), but also in the high levels of nitrogen (≈ 1000 ppm), suggesting that the two diamond types are related. Additionally, no δ15N variation was detected between the cube and octahedral growth sectors of the Australian diamond, in the cube sectors of the nine gem cubes from Botswana, nor in fibrous/coated diamonds previously studied. These analyses contrast with an earlier study on a synthetic diamond, which reported a strong kinetic fractionation of N-isotopes of about 40‰ between cube and octahedral growth. The present evidence, therefore, suggests that kinetic fractionation of N-isotopes does not operate during natural diamond formation. 相似文献
Knowledge of the time-scales of emplacement and thermal history during assembly of composite felsic plutons in the shallow crust are critical to deciphering the processes of crustal growth and magma chamber development. Detailed petrological and chemical study of the mid-Cretaceous, composite Emerald Lake pluton, from the northern Canadian Cordillera, Yukon Territory, coupled with U–Pb and 40Ar/39Ar geochronology, indicates that this pluton was intruded as a series of magmatic pulses. Intrusion of these pulses produced a strong petrological zonation from augite syenite, hornblende quartz syenite and monzonite, to biotite granite. Our data further indicate that multiple phases were emplaced and cooled to below the mineral closure temperatures over a time-scale on the order of the resolution of the 40Ar/39Ar technique (1 Myr), and that emplacement occurred at 94.3 Ma. Simple thermal modelling and heat conduction calculations were used to further constrain the temporal relationships within the intrusion. These calculations are consistent with the geochronology and show that emplacement and cooling were complete in less than 100 kyr and probably 70±5 kyr. These results demonstrate that production, transport and emplacement of the different phases of the Emerald Lake pluton occurred essentially simultaneously, and that these processes must also have been closely related in time and space. By analogy, these results provide insights into the assembly and petrogenesis of other complex intrusions and ultimately lead to an understanding of the processes involved in crustal development. 相似文献
We use new data from the SALPEX'96 campaign to examine the evolution of orographically modified flow over and around New Zealand's Southern Alps. We consider prefrontal situations for which the larger-scale synoptic pattern generates an incoming northwesterly flow perpendicular to the mountain axis, calculate the nondimensional parameters which control the wind flow and determine how long it takes orographic modifications to become established. We place flows over the New Zealand Alps in a Rossby number/Blocking number parameter space and compare them with flows over other mountain ranges on the globe. Using model and aircraft data, we show the region of modified flow extends over 100 km upstream of the Southern Alps.We show 2D model simulations represent many aspects of the flow modification satisfactorily, although they tend to overdevelop the final state of the Barrier Jet flow. In 3D, using real data to force the boundaries, the migratory nature of the weather systems in the area would generally limit the time available for a modified steady state to develop. In addition, in situations where there is significant lateral variation of initial fields, the 2D results may only be applicable for a few hours.From the point of view of potential to influence alpine rainfall processes, for the case studied, the gradual uplift associated with the modified flow between 1 and 2 km above sea level extended far enough upstream in saturated air to enable cloud drops to grow to drizzle drops before reaching the much more substantial updrafts at the foot of the Alps. This allows vigorous prefrontal precipitation to occur over the foothills and mountains due largely to warm rain processes. 相似文献
Research into torrent erosion focuses heavily on bedload transport dynamics and debris flow propagation during specific events. As a result, there is limited understanding of the sediment budgets operating in torrent systems over longer timescales. The aim of this study is to construct a sediment budget of the main geomorphological processes operating in a mountain torrent sediment system over a full year. The study site is Iron Crag which is a small torrent system (catchment area 2.4 ha) situated in the northern Lake District, UK. The site has the characteristic morphology of a torrent: multiple hillslope sediment sources, steep channel, gorges, and a basal alluvial fan. A measurement scheme was designed to monitor process activity, linking the sediment sources and sinks, from December 1998 to December 1999. Over this time period the sediment budget demonstrates that 184 tonnes of sediment was supplied to the alluvial fan (which acted primarily as a sediment sink). Channel (70%) and bank (25%) sources dominated the sediment supply, and surface processes and rockfall on the hillslopes (5%) made only a minor contribution. Temporal variations in process activity are significant. Surface processes and rockfall display seasonal variations in yield, whilst channel and bank yields are influenced by individual storm events. Site–specific meteorological data are used to explain these observations and freeze–thaw activity and rainfall characteristics are shown to be important controlling factors. 相似文献
The Jornada Experimental Range and the New Mexico State University Chihuahuan Desert Rangeland Research Center are fruitful areas to study the long-term effects of rangeland remediation treatments which started in the 1930s. A number of diverse manipulations were completed under the direction of federal agency and university scientists, and abundant remote sensing imagery is available to assist in relocating the treatments and evaluating their success. This is particularly important because few of the treatments were maintained following the loss of scientific personnel coinciding with the start of World War II, and most records of Civilian Conservation Corps scientific work were lost with the disbanding of the agency in 1942. Aerial photography, which was systematically used to image the United States beginning in the 1930s, can be used to identify types of treatments, measure areal coverage, estimate longevity, and help plan locations for new experiments. No long-lasting vegetation response could be determined for contour terraces, brush water spreaders, strips grubbed free of shrubs (despite the fact that these strips have remained visible for 65 years), and mechanical rootplowing and seeding. Distinct positive, long-term vegetation responses could be seen in aerial photos for water retention dikes, certain fenced exclosures, and some boundaries where different land management practices meet. It appears from both aerial photos and existing conventional records that experimental manipulation of rangelands has often been ineffective on the landscape scale because treatments are not performed over large enough contiguous areas and hydrological and ecological processes overwhelm the treatments. In addition, treatments are not maintained over time, treatment evaluation periods are sometimes too short, multi-purpose treatments are not used to maximize effects, and treatments are often not located in appropriate sites. 相似文献
A new in‐situ remediation concept termed a Horizontal Reactive Media Treatment Well (HRX Well®) is presented that utilizes horizontal wells filled with reactive media to passively treat contaminated groundwater in‐situ. The approach involves the use of large‐diameter directionally drilled horizontal wells filled with granular reactive media generally installed parallel to the direction of groundwater flow. The design leverages natural “flow‐focusing” behavior induced by the high in‐well hydraulic conductivity of the reactive media relative to the aquifer hydraulic conductivity to passively capture and treat proportionally large volumes of groundwater within the well. Clean groundwater then exits the horizontal well along its downgradient sections. Many different types of solid granular reactive media are already available (e.g., zero valent iron, activated carbon, ion exchange resins, zeolite, apatite, chitin); therefore, this concept could be used to address a wide range of contaminants. Three‐dimensional flow and transport simulations were completed to assess the general hydraulic performance, capture zones, residence times, effects of aquifer heterogeneity, and treatment effectiveness of the concept. The results demonstrate that capture and treatment widths of up to tens of feet can be achieved for many aquifer settings, and that reductions in downgradient concentrations and contaminant mass flux are nearly immediate. For a representative example, the predicted treatment zone width for the HRX Well is approximately 27 to 44 feet, and contaminant concentrations immediately downgradient of the HRX Well decreased an order of magnitude within 10 days. A series of laboratory‐scale physical tests (i.e., tank tests) were completed that further demonstrate the concept and confirm model prediction performance. For example, the breakthrough time, peak concentration and total mass recovery of methylene blue (reactive tracer) was about 2, 35, and 20 times (respectively) less than chloride (conservative tracer) at the outlet of the tank‐scale HRX Well. 相似文献
This paper describes the development of the first operational seasonal hydrological forecasting service for the UK, the Hydrological Outlook UK (HOUK). Since June 2013, this service has delivered monthly forecasts of streamflow and groundwater levels, with an emphasis on forecasting hydrological conditions over the next three months, accompanied by outlooks over longer time horizons. This system is based on three complementary approaches combined to produce the outlooks: (i) national-scale modelling of streamflow and groundwater levels based on dynamic seasonal rainfall forecasts, (ii) catchment-scale modelling where streamflow and groundwater level models are driven by historical meteorological forcings (i.e. the Ensemble Streamflow Prediction, ESP, approach), and (iii) a catchment-scale statistical method based on persistence and historical analogues. This paper provides the background to the Hydrological Outlook, describes the various component methods in detail and then considers the impact and usefulness of the product. As an example of a multi-method, operational seasonal hydrological forecasting system, it is hoped that this overview provides useful information and context for other forecasting initiatives around the world. 相似文献