Chondrules in the Qingzhen type-3 enstatite chondrite: Possible precursor components and comparison to ordinary chondrite chondrules     

Jeffrey N. Grossman  Alan E. Rubin  Ermanno R. Rambaldi  R.Sundar Rajan  John T. Wasson 《Geochimica et cosmochimica acta》1985,49(8):1781-1795

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Anomalous isotopic concentrations in the sea off Southern California     

Louis Brown  Jeffrey Klein  Roy Middleton 《Geochimica et cosmochimica acta》1985,49(1):153-157

Measurements are reported of the ¹⁰Be concentrations in 15 sediments from the sea off southern California. The sedimentation patterns are modelled with a two component system, one component having the high ¹⁰Be concentration of pelagic sediment and the other the low concentration of continental runoff. The pelagic component, brought to the region by the California Current with the Pacific Ocean as reservoir, is very likely the source not only of anomalously high ¹⁰Be deposition but also of similar effects with ²¹⁰¹Pb, ^239,240pu and ²⁴¹Pu.  相似文献   

The relationship of soil Po and Pb geochemical dispersion patterns to uranium mineralization     

Jeffrey W. Card  Keith Bell 《Journal of Geochemical Exploration》1985,23(2)

²¹⁰Po and ²¹⁰Pb measurements of soils delineated uranium anomalies at three out of four test sites in Ontario, Canada. Measurements were made of ²¹⁰Po in solutions produced by both complete digestion and partial leaching of soil samples. Direct plating of ²¹⁰Po onto metal plates was followed by measuring the alpha activity. Subsequent plating of ²¹⁰Po in-grown from ²¹⁰Pb in solution several months later confirmed the anomalies.The ²¹⁰Po and ²¹⁰Pb anomalies at three of the test sites coincided with ²²⁶Ra and ²²²Rn anomalies. Samples from the fourth uranium occurrence associated with a known ²²²Rn anomaly failed to show either a ²²⁶Ra anomaly on the one hand, or ²¹⁰Po or ²¹⁰Pb anomalies on the other. This suggests that the ²¹⁰Po and ²¹⁰Pb anomalies were probably produced by the decay of ²²⁶Ra contained within secondary dispersion haloes.Although anomalies due to the ²¹⁰Po and ²¹⁰Pb products of ²²²Rn have now been documented, prospecting methods based on their use as direct tracers of the migration paths of ²²²Rn require much further development.  相似文献   

¹⁰Be accumulation in a soil chronosequence     

Milan J. Pavich  Louis Brown  Jeffrey Klein  Roy Middleton 《Earth and Planetary Science Letters》1984,68(2):198-204

We have measured the concentration of the cosmogenic isotope¹⁰Be in soil samples from various horizons at six sites, including three independently dated Rappahannock River terraces and a previously undated Piedmont soil to which we have assigned an age. All of the incident¹⁰Be can be accounted for in one of these soils and a second is within a factor of two. In three soils, whose concentrations vary widely with depth, a significant fraction of the incident¹⁰Be cannot be accounted for. Incomplete sampling, and enhanced Be mobility caused by organic components, are the probable reasons for the low inventory of Be from these three soils. Overall, the data from these six sites indicate that¹⁰Be accumulation could be used to assign ages to soils if Be is not mobilized and lost from the soil profile.  相似文献   

Alteration of the upper oceanic crust,DSDP site 417: mineralogy and chemistry     

Jeffrey C. Alt  Jose Honnorez 《Contributions to Mineralogy and Petrology》1984,87(2):149-169

Basalts from DSDP Site 417 (109 Ma) exhibit the effects of several stages of alteration reflecting the evolution of seawater-derived solution compositions and control by the structure and permeability of the crust. Characteristic secondary mineral assemblages occur in often superimposed alteration zones within individual basalt fragments. By combining bulk rock and single phase chemical analyses with detailed mineralogic and petrographic studies, chemical changes have been determined for most of the alteration stages identified in the basalts.

1. Minor amounts of saponite, chlorite, and pyrite formed locally in coarse grained portions of massive units, possibly at high temperatures during initial cooling of the basalts. No chemical changes could be determined for this stage.
2. Possible mixing of cooled hydrothermal fluids with seawater resulted in the formation of celadonite-nontronite and Fe-hydroxide-rich black halos around cracks and pillow rims. Gains of K, Rb, H₂O, increase of Fe³⁺/Fe^T, and possibly some losses of Ca and Mg occurred during this stage.
3. Extensive circulation of oxygenated seawater resulted in the formation of various smectites, K-feldspar, and Fe-hydroxides in brown and light grey alteration zones around formerly exposed surfaces. K, Rb, H₂O, and occasionally P were added to the rocks, Fe³⁺/Fe^T increased, and Ca, Mg, Si and occasionally Al and Na were lost.
4. Anoxic alteration occurred during reaction of basalt with seawater at low water-rock ratios, or with seawater that had previously reacted with basalt. Saponite-rich dark grey alteration zones formed which exhibit very little chemical change: generally only slight increases in Fe³⁺/Fe^T and H₂O occurred.
5. Zeolites and calcite formed from seawater-derived fluids modified by previous reactions with basalt. Chemical changes involved increases of Ca, Na, H₂O, and CO₂ in the rocks.
6. A late stage of anoxic conditions resulted in the formation of minor amounts of Mn-calcites and secondary sulfides in previously oxidized rocks. No chemical changes were determined for this stage.

Recognition of such alteration sequences is important in understanding the evolution of submarine hydrothermal systems and in interpreting chemical exchange due to seawater-basalt reactions.  相似文献   

An oxygen isotopic profile through the upper kilometer of the oceanic crust, DSDP Hole 504B   总被引：2，自引：0，他引：2  

Jeffrey C. Alt  Karlis Muehlenbachs  Jose Honnorez 《Earth and Planetary Science Letters》1986,80(3-4):217-229

DSDP Hole 504B is the deepest basement hole in the oceanic crust, penetrating through a 571.5 m pillow section, a 209 m lithologic transition zone, and 295 m into a sheeted dike complex. An oxygen isotopic profile through the upper crust at Site 504 is similar to that in many ophiolite complexes, where the extrusive section is enriched in¹⁸O relative to unaltered basalts, and the dike section is variably depleted and enriched. Basalts in the pillow section at Site 504 haveδ¹⁸O values generally ranging from +6.1 to +8.5‰ SMOW(mean= +7.0‰), although minor zeolite-rich samples range up to 12.7‰. Rocks depleted in¹⁸O appear abruptly at 624 m sub-basement in the lithologic transition from 100% pillows to 100% dikes, coinciding with the appearance of greenschist facies minerals in the rocks. Whole-rock values range to as low as +3.6‰, but the mean values for the lithologic transition zone and dike section are +5.8 and +5.4‰, respectively.

Oxygen and carbon isotopic data for secondary vein minerals combined with the whole rock data provide evidence for the former presence of two distinct circulation systems separated by a relatively sharp boundary at the top of the lithologic transition zone. The pillow section reacted with seawater at low temperatures (near 0°C up to a maximum of around 150°C) and relatively high water/rock mass ratios (10–100); water/rock ratios were greater and conditions were more oxidizing during submarine weathering of the uppermost 320 m than deeper in the pillow section. The transition zone and dikes were altered at much higher temperatures (up to about 350°C) and generally low water/rock mass ratios ( 1), and hydrothermal fluids probably contained mantle-derived CO₂. Mixing of axial hydrothermal fluids upwelling through the dike section with cooler seawater circulating in the overlying pillow section resulted in a steep temperature gradient ( 2.5°C/m) across a 70 m interval at the top of the lithologic transition zone. Progressive reaction during axial hydrothermal metamorphism and later off-axis alteration led to the formation of albite- and Ca-zeolite-rich alteration halos around fractures. This enhanced the effects of cooling and¹⁸O enrichment of fluids, resulting in local increases inδ¹⁸O of rocks which had been previously depleted in¹⁸O during prior axial metamorphism.  相似文献   

Corroded cobbles in Southern Death Valley: Their relationship to honeycomb weathering and lake shorelines     

Paul R. Butler  Jeffrey F. Mount 《地球表面变化过程与地形》1986,11(4):377-387

In southern Death Valley, pits similar in morphology to honeycomb weathering (herein referred to as corrosion pits) occur on the surfaces of cobbles that are associated with wave-produced benches. The pitted cobbles include a variety of igneous, metamorphic, and siliciclastic rocks; corrosion pits are rare to absent in limestones or dolomites. Pit morphology is controlled by cobble lithology. In massive rocks the pits are arcuate, elongate, and gently tapering; corrosion of laminated or foliated rocks has produced irregular, more jagged pits. The presence of desert varnish has strongly inhibited the corrosion process. The corroded cobbles are inferred to reflect both chemical and physical weathering of rocks along Pleistocene lacustrine strandlines. Corrosion took place through salt-weathering and/or heat-moisture expansion processes and through chemical dissolution of selected minerals as a result of splash-zone wetting and drying. The ancient lake waters may have had high pH and high total dissolved solids contents. The recognition of corroded cobbles may be important in the reconstruction of the position of ancient shorelines for certain types of alkaline lakes and in the reconstruction of their ancient chemistries.  相似文献   

The formation of clear taenite in ordinary chondrites     

G.Jeffrey Taylor  Dieter Heymann 《Geochimica et cosmochimica acta》1971

The metallic phases in six bronzite and six hypersthene chondrites were studied metallographically and by electron microprobe. All of the chondrites studied contain zoned taenite. In bronzite chondrites, only about 5 per cent of the zoned taenite abuts on kamacite (the rest being apparently isolated from it) whereas in hypersthene chondrites an average of over 20 per cent abuts on kamacite. The compositions of the centers of zoned taenite can be used to obtain cooling rates by Wood's method. Including Wood's results, 14 out of 18 ordinary chondrites have cooling rates between 1 and 10°C/m.y.  相似文献   

The Luna 20 lithic fragments,and the composition and origin of the lunar highlands     

G.Jeffrey Taylor  Michael J Drake  John A Wood  Ursula B Marvin 《Geochimica et cosmochimica acta》1973,37(4):1087-1106

Luna 20 soil 22003,1 (250–500 μ) is similar to Apollo 16 soil 61501,47 (250–500 μ) in terms of the percentage of different types of particles. However, among the lithic fragments, the Apollo 16 sample contains a greater percentage of fragments with more than 70 wt. % modal plagioclase and a significantly greater proportion of KREEP-rich particles. Modal analyses of non-mare lithic fragments in Luna 20 and Apollo 11, 14, 15 and 16 indicate that the KREEP-poor highland regions (the bulk of the lunar terrae), though relatively feldspathic, are compositionally inhomogeneous, ranging in plagioclase content from approximately 35 to 100 wt. %. The average plagioclase content lies in the range 45–70 wt.%. Luna 20 pyroxene analyses cluster in two groups, one more magnesian than the other. The groups persist when pyroxene analyses from KREEP-poor noritic, troctolitic and anorthositic lithic fragments from Apollo 11, 14, 15 and 16 and Luna 20 are included. Olivine compositions mimic these pyroxene groups.Within each pyroxene group Cr₂O₃ and TiO₂ decrease as $\text{Fe}\text{(Fe + Mg)}$ increases, suggesting a relationship by fractional crystallization. The two groups suggest that at least two magma compositions were involved. To account for these observations we envisage a Moon-wide magma system in which initial accretionary heterogeneities were imperfectly erased by diffusion and convection. During the cooling of this magma system fractional crystallization was effected by the flotation of plagioclase and sinking of pyroxene, olivine and perhaps ilmenite. The endproduct was an upper layer enriched in plagioclase and a lower layer enriched in mafic silicates. KREEP-rich rocks, which are predominantly noritic in major element composition, may be mechanical mixtures of KREEP-poor norite and material residual after fractional crystallization of the surface magma system.  相似文献   

Ultracataclasis, sintering, and frictional melting in pseudotachylytes from East Greenland     

Daniel Curewitz  Jeffrey A. Karson 《Journal of Structural Geology》1999,21(12):89

Large volumes of pseudotachylyte (an intrusive, fault-related rock interpreted to form by a combination of cataclasis and melting) occur in Tertiary normal faults and accommodation zones along 400 km of the East Greenland volcanic rifted margin. Analysis of representative pseudotachylyte samples reveals a wide range of mesoscopic and microscopic textures, mineralogies, and chemistries in the aphanitic pseudotachylyte matrix. Three distinct types of pseudotachylyte (referred to as angular, rounded and glassy) are identified based on these characteristics. Angular pseudotachylyte (found primarily in dike-like reservoir zones) is characterized by angular grains visible on all scales, with micron-scale fragments of mica and amphibole. Its matrix is enriched in Fe₂O₃, MgO, and TiO₂ relative to the host rock, with minor increases in CaO, K₂O, and small decreases in Na₂O. Rounded pseudotachylyte is found in reservoir zones, injection veins (pseudotachylyte-filled extension fractures), and fault veins (small faults with pseudotachylyte along their surfaces). It is characterized by smooth-surfaced, compacted grains on microscopic scales, and encloses rounded, interpenetrative lithic clasts on outcrop scale. Its matrix is enriched in Fe₂O₃, MgO, TiO₂, and Al₂O₃ relative to the host rock, with minor depletion in Na₂O and K₂O. Glassy pseudotachylyte is found primarily along fault surfaces. Its matrix is characterized by isotropic, conchoidally fractured material containing microscopic, strain-free amphibole phenocrysts, and is enriched in TiO₂, Al₂O₃, K₂O, Fe₂O₃, MgO, CaO, and Na₂O relative to the host rock. These observations suggest that angular pseudotachylyte was produced by cataclasis, with enrichment in metallic oxides resulting from preferential crushing of mechanically weak amphibole and mica minerals found in the gneissic host rock. Cataclasis and concomitant frictional heating resulted in the textural and chemical modification of angular pseudotachylyte by sintering or melting, producing rounded and glassy pseudotachylyte, respectively. Compositional and textural observations constrain the temperatures reached during frictional heating (700–900°C) which in turn delimit the amount of frictional heat imparted to the pseudotachylytes during slip. Our results suggest that the East Greenland pseudotachylytes formed during small seismic events along faults at shallow crustal levels. Consistent relative ages and widespread occurrence of pseudotachylyte-bearing faults in East Greenland suggest that widespread microseismicity accompanied the early development of this volcanic rifted margin.  相似文献