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31.
Theδ18O (SMOW) values of the Kirkpatrick Basalt (Jurassic) on Mt. Falla, Queen Alexandra Range, vary between +6.3‰ and +8.6‰ The apparent enrichment of these rocks in18O excludes the possibility that they were altered by interaction with aqueous solutions of meteoric origin. Theδ18O values of the flows correlate significantly with the initial87Sr/86Sr ratios and all major elements. These correlations confirm the hypothesis that the basalt magma was contaminated by rocks of the continental crust through which it was extruded. Estimates of the chemical composition of the basalt magma and the contaminant, based on extrapolations of the new oxygen data, generally confirm earlier estimates based on extrapolations of initial87Sr/86Sr ratios. The87Sr/86Sr ratio of the uncontaminated basalt was 0.7093 which indicates that magma may have originated by melting either in old Rb-enriched lithospheric mantle under Antarctica or in the overlying crust, or both.  相似文献   
32.
The use of fish in environmental monitoring has become increasingly important in recent years as anthropogenic substances, many of which function as prooxidants, are accumulating in aquatic environments. We have measured a battery of antioxidant defenses as a measure of oxidative status, as well as protein carbonylation as a measure of oxidative damage, in corkwing wrasse (Symphodus melops) captured near a disused copper mine, where water and sediment are contaminated with heavy metals, and an aluminum smelter, a site contaminated with PAHs. Results were compared to two different reference sites. Fish at the heavy metal site had lower glucose-6-phosphate dehydrogenase activity and elevated protein carbonyls (1.8 times) compared to fish from the reference site. At the PAH site, EROD was increased 2-fold, while total glutathione and methemoglobin reductase concentration, were decreased. No differences were seen in protein carbonyl levels at the PAH site. Measures of both antioxidant defenses and oxidative damage should be used when assessing effects of xenobiotics on oxidative stress in fish species.  相似文献   
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34.
Microdiamond and graphite occur in quartzofeldspathic rocks (saidenbachites) of the central Erzgebirge in Saxony. Zircon from such rocks contains not only relatively high but also variable amounts of early formed graphite and later crystallized diamond, however no carbonate. Six purified zircon concentrates were analysed by mass spectrometry for δ13C(PDB) values which were between −24 and −33‰. The carbon inclusions resulted in C contents of the concentrates as high as 0.5 wt%. It is hypothesized that the observed δ13C signature results from organic material in the sedimentary protoliths of the saidenbachites probably deposited not earlier than Mid‐Devonian. This material was transformed to graphite during early metamorphism and subsequently to diamond after an anatectic event at great depths (>150 km). During these processes, the δ13C signature of the carbon did not (significantly) change.  相似文献   
35.
We present results from a suite of N-body simulations that follow the formation and accretion history of the terrestrial planets using a new parallel treecode that we have developed. We initially place 2000 equal size planetesimals between 0.5 and 4.0 AU and the collisional growth is followed until the completion of planetary accretion (>100 Myr). A total of 64 simulations were carried out to explore sensitivity to the key parameters and initial conditions. All the important effect of gas in laminar disks are taken into account: the aerodynamic gas drag, the disk-planet interaction including Type I migration, and the global disk potential which causes inward migration of secular resonances as the gas dissipates. We vary the initial total mass and spatial distribution of the planetesimals, the time scale of dissipation of nebular gas (which dissipates uniformly in space and exponentially in time), and orbits of Jupiter and Saturn. We end up with 1-5 planets in the terrestrial region. In order to maintain sufficient mass in this region in the presence of Type I migration, the time scale of gas dissipation needs to be 1-2 Myr. The final configurations and collisional histories strongly depend on the orbital eccentricity of Jupiter. If today’s eccentricity of Jupiter is used, then most of bodies in the asteroidal region are swept up within the terrestrial region owing to the inward migration of the secular resonance, and giant impacts between protoplanets occur most commonly around 10 Myr. If the orbital eccentricity of Jupiter is close to zero, as suggested in the Nice model, the effect of the secular resonance is negligible and a large amount of mass stays for a long period of time in the asteroidal region. With a circular orbit for Jupiter, giant impacts usually occur around 100 Myr, consistent with the accretion time scale indicated from isotope records. However, we inevitably have an Earth size planet at around 2 AU in this case. It is very difficult to obtain spatially concentrated terrestrial planets together with very late giant impacts, as long as we include all the above effects of gas and assume initial disks similar to the minimum mass solar nebular.  相似文献   
36.
We propose a mechanism for the oxidation of gaseous CO into CO2 occurring on the surface mineral hematite (Fe2O3(s)) in hot, CO2-rich planetary atmospheres, such as Venus. This mechanism is likely to constitute an important source of tropospheric CO2 on Venus and could at least partly address the CO2 stability problem in Venus’ stratosphere, since our results suggest that atmospheric CO2 is produced from CO oxidation via surface hematite at a rate of 0.4 petagrammes (Pg) CO2 per (Earth) year on Venus which is about 45% of the mass loss of CO2 via photolysis in the Venusian stratosphere. We also investigated CO oxidation via the hematite mechanism for a range of planetary scenarios and found that modern Earth and Mars are probably too cold for the mechanism to be important because the rate-limiting step, involving CO(g) reacting onto the hematite surface, proceeds much slower at lower temperatures. The mechanism may feature on extrasolar planets such as Gliese 581c or CoRoT-7b assuming they can maintain solid surface hematite which, e.g. starts to melt above about 1200 K. The mechanism may also be important for hot Hadean-type environments and for the emerging class of hot Super-Earths with planetary surface temperatures between about 600 and 900 K.  相似文献   
37.
In this article, an approach for the efficient numerical solution of multi-species reactive transport problems in porous media is described. The objective of this approach is to reformulate the given system of partial and ordinary differential equations (PDEs, ODEs) and algebraic equations (AEs), describing local equilibrium, in such a way that the couplings and nonlinearities are concentrated in a rather small number of equations, leading to the decoupling of some linear partial differential equations from the nonlinear system. Thus, the system is handled in the spirit of a global implicit approach (one step method) avoiding operator splitting techniques, solved by Newton’s method as the basic algorithmic ingredient. The reduction of the problem size helps to limit the large computational costs of numerical simulations of such problems. If the model contains equilibrium precipitation-dissolution reactions of minerals, then these are considered as complementarity conditions and rewritten as semismooth equations, and the whole nonlinear system is solved by the semismooth Newton method.  相似文献   
38.
This study investigates the disaster-induced population displacement scenario at individual household level in Bangladesh. ‘Population displacement’ is seen here as an alternative adaptation option to natural hazard for the survivors after cyclone Aila. The changes both in origin and destination community due to population displacement are described here on the basis of social ‘inclusion’ and ‘exclusion’ concept. The field survey was conducted during March–July 2010, and a sample of 280 respondents from 12 villages in southwest coastal Bangladesh was interviewed. Findings show that at the end of emergency aid, male members of the family started moving towards nearer cities to find an income. Based on the income and asset distribution at the community level, this study developed a societal cluster of displacement and demonstrates the societal changes because of cyclone-induced population displacement.  相似文献   
39.
We use a high-resolution ΛCDM numerical simulation to calculate the mass function of dark matter haloes down to the scale of dwarf galaxies, back to a redshift of 15, in a  50 h −1 Mpc  volume containing 80 million particles. Our low-redshift results allow us to probe low-σ density fluctuations significantly beyond the range of previous cosmological simulations. The Sheth & Tormen mass function provides an excellent match to all of our data except for redshifts of 10 and higher, where it overpredicts halo numbers increasingly with redshift, reaching roughly 50 per cent for the  1010–1011 M  haloes sampled at redshift 15. Our results confirm previous findings that the simulated halo mass function can be described solely by the variance of the mass distribution, and thus has no explicit redshift dependence. We provide an empirical fit to our data that corrects for the overprediction of extremely rare objects by the Sheth & Tormen mass function. This overprediction has implications for studies that use the number densities of similarly rare objects as cosmological probes. For example, the number density of high-redshift  ( z ≃ 6) QSOs  , which are thought to be hosted by haloes at 5σ peaks in the fluctuation field, are likely to be overpredicted by at least a factor of 50 per cent. We test the sensitivity of our results to force accuracy, starting redshift and halo-finding algorithm.  相似文献   
40.
Large‐scale simulations of flow in deformable porous media require efficient iterative methods for solving the involved systems of linear algebraic equations. Construction of efficient iterative methods is particularly challenging in problems with large jumps in material properties, which is often the case in geological applications, such as basin evolution at regional scales. The success of iterative methods for this type of problems depends strongly on finding effective preconditioners. This paper investigates how the block‐structured matrix system arising from single‐phase flow in elastic porous media should be preconditioned, in particular for highly discontinuous permeability and significant jumps in elastic properties. The most promising preconditioner combines algebraic multigrid with a Schur complement‐based exact block decomposition. The paper compares numerous block preconditioners with the aim of providing guidelines on how to formulate efficient preconditioners. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
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