PCBs in fish from the southern Baltic Sea: levels, bioaccumulation features, and temporal trends during the period from 1997 to 2006   总被引：1，自引：0，他引：1  

Szlinder-Richert J  Barska I  Mazerski J  Usydus Z 《Marine pollution bulletin》2009,58(1):85-92

Levels of seven marker polychlorinated biphenyls (PCBs) have been determined in five species of Baltic fish collected during 1997-2006. Downward time trends in the concentrations of heavier congeners of PCBs in different Baltic fish, with the exception of cod, have been observed between 1997 and 2001. In case of sprat and herring samples, the statistical significance of the time trends of the PCBs: 101, 118, 153, 138 and 180 concentrations has been proved. Species-specific bioaccumulation of PCBs has been indicated, and the lowest and highest levels of PCBs (expressed on the basis of lipid weight) have been observed in sprat and salmon samples, respectively. PCB profiles have been found to be similar in all the fish species tested. Sampling location has not been a crucial factor for the observed levels of various PCBs. In some fish species, PCB concentrations are negatively correlated with the fat content but have no relation with the fish length.  相似文献   

Bridging the gap between field data and global models: current strategies in aeolian research     

Joanna Bullard 《地球表面变化过程与地形》2010,35(4):496-499

Modern global models of earth‐atmosphere‐ocean processes are becoming increasingly sophisticated but still require validation against empirical data and observations. This commentary reports on international initiatives amongst aeolian researchers that seek to combine field‐based data sets and geomorphological frameworks for improving the quality of data available to constrain and validate global models. These include a second iteration of the Dust Indicators and Records from Terrestrial Marine Palaeoenvironments (DIRTMAP2) database, the Digital Atlas of Sand Seas and Dunefields of the World and a new geomorphology‐based land surface map produced by the QUEST (Quantifying Uncertainties in the Earth System) Working Group on Dust. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Two-dimensional equilibrium morphological modelling of a tidal inlet: an entropy based approach     

Joanna Marie Nield  David John Walker  Martin Francis Lambert 《Ocean Dynamics》2005,55(5-6):549-558

The management of tidal inlets requires the accurate prediction of equilibrium morphologies. In areas where the flow from rivers is highly regulated, it is important to give decision makers the ability to determine optimal flow management schemes, in order to allow tidal inlets to function as naturally as possible, and minimise the risk of inlet closure. The River Murray Mouth in South Australia is one such problem area. Drought and the retention of water for irrigation and urban water consumption have limited the amount of water entering the estuary. As a result, sediment from the coastal environment is being deposited in the mouth of the estuary, reducing the effect of further coastal interactions. Currently, situations such as this are modelled using traditional process-based methods, where wave, current, sediment transport and sediment balance modules are linked together in a time-stepping process. The modules are reapplied and assessed until a stable morphology is formed. In this paper, new options for modelling equilibrium morphologies of tidal inlets are detailed, which alleviate some of the shortfalls of traditional process-based models, such as the amplification of small errors and reliance on initial conditions. The modelling problem is approached in this paper from a different angle and involves the use of entropy based objective functions, which are optimised in order to find equilibrium morphologies. In this way, characteristics of a system at equilibrium can be recognised and a stable system predicted without having to step through time. This paper also details the use of self-organisation based modelling methods, another non-traditional model application, where local laws and feedback result in the formation of a global stable equilibrium morphology. These methods represent a different approach to traditional models, without some of the characteristics that may add to their limitations. Responsible Editor: Alejandro Souza  相似文献   

Crosshole seismic waveform tomography – II. Resolution analysis     

Ying Rao  Yanghua Wang  Joanna V. Morgan 《Geophysical Journal International》2006,166(3):1237-1248

In an accompanying paper, we used waveform tomography to obtain a velocity model between two boreholes from a real crosshole seismic experiment. As for all inversions of geophysical data, it is important to make an assessment of the final model, to determine which parts of the model are well-resolved and can confidently be used for geological interpretation. In this paper we use checkerboard tests to provide a quantitative estimate of the performance of the inversion and the reliability of the final velocity model. We use the output from the checkerboard tests to determine resolvability across the velocity model. Such tests can act as good guides for designing appropriate inversion strategies. Here we discovered that, by including both reference-model and smoothing constraints in initial inversions, and then relaxing the smoothing constraint for later inversions, an optimum velocity image was obtained. Additionally, we noticed that the performance of the inversion was dependent on a relationship between velocity perturbation and checkerboard grid-size: larger velocity perturbations were better-resolved when the grid-size was also increased. Our results suggest that model assessment is an essential step prior to interpreting features in waveform tomographic images.  相似文献   

Assessment of key transport parameters in a karst system under different dynamic conditions based on tracer experiments: the Jeita karst system,Lebanon     

Joanna Doummar  Armin Margane  Tobias Geyer  Martin Sauter 《Hydrogeology Journal》2018,26(7):2283-2295

Artificial tracer experiments were conducted in the mature karst system of Jeita (Lebanon) under various flow conditions using surface and subsurface tracer injection points, to determine the variation of transport parameters (attenuation of peak concentration, velocity, transit times, dispersivity, and proportion of immobile and mobile regions) along fast and slow flow pathways. Tracer breakthrough curves (TBCs) observed at the karst spring were interpreted using a two-region nonequilibrium approach (2RNEM) to account for the skewness in the TBCs’ long tailings. The conduit test results revealed a discharge threshold in the system dynamics, beyond which the transport parameters vary significantly. The polynomial relationship between transport velocity and discharge can be related to the variation of the conduit’s cross-sectional area. Longitudinal dispersivity in the conduit system is not a constant value (α?=?7–10 m) and decreases linearly with increasing flow rate because of dilution effects. Additionally, the proportion of immobile regions (arising from conduit irregularities) increases with decreasing water level in the conduit system. From tracer tests with injection at the surface, longitudinal dispersivity values are found to be large (8–27 m). The tailing observed in some TBCs is generated in the unsaturated zone before the tracer actually arrives at the major subsurface conduit draining the system. This work allows the estimation and prediction of the key transport parameters in karst aquifers. It shows that these parameters vary with time and flow dynamics, and they reflect the geometry of the flow pathway and the origin of infiltrating (potentially contaminated) recharge.  相似文献   

Pricing of uncertain certified emission reductions in a Chinese coal mine methane project with an extended Rubinstein-Ståhl model     

Xiangyang Xu  Joanna Horabik  Zbigniew Nahorski 《Climatic change》2014,124(3):617-632

The development of coal mine methane (CMM) projects is subject to various kinds of risk, one of these being their highly variable methane content. In this study, a new methodology is proposed to reflect the impact of this uncertainty on a negotiated Certified Emission Reduction (CER) price, which is based on the available information. To simulate a process of price negotiation the Rubinstein-Ståhl bargaining game is utilized, where a buyer’s discount factor is unknown. It is assumed that a buyer’s willingness to accomplish price negotiations depends on the CER uncertainty. The bargaining model has been extended by introducing dependence of its three parameters on the probability of a failure to fulfil the contracted CER amount. To quantify this probability, we develop a conditional distribution given information on the point estimate of methane amount for the project under consideration, and on the distribution of available estimates from coal mines having similar characteristics. The proposed approach is applied to a particular CMM capture and utilization project in Anhui province, China. The results indicate that the uncertainty influence is significant, particularly when the credibility of a seller increases, i.e. the probability of a failure to fulfil the project decreases. The analysis can be of use to both negotiating parties at an early stage of a comprehensive CMM project planning.  相似文献   

Sulfide saturation history of the Stillwater Complex, Montana: chemostratigraphic variation in platinum group elements   总被引：1，自引：0，他引：1  

Reid R. Keays  Peter C. Lightfoot  Paul R. Hamlyn 《Mineralium Deposita》2012,47(1-2):151-173

A platinum group element (PGE) investigation of a 5.3?km-thick stratigraphic section of the Stillwater Complex, Montana was undertaken to refine and test a geochemical technique to explore for platiniferous horizons in layered mafic/ultramafic complexes. PGE, Au, major, and trace elements were determined in 92 samples from outcrops along traverses in the Chrome Mountain and Contact Mountain areas in the western part of the Stillwater Complex where the J-M reef occurs ～1,460?m above the floor of the intrusion. A further 29 samples from a drill hole cored in the immediate vicinity of the J-M reef were analyzed to detail compositional variations directly above and below the J-M reef. Below the J-M reef, background concentrations of Pt (10?ppb) and Pd (7?ppb) are features of peridotites with intermediate S concentrations (mostly 100–200?ppm) and rocks from the Bronzitite, Norite I, and Gabbronorite I zones (mostly <100?ppm S). A sustained increase in S abundance commences at the J-M reef and continues to increase and peaks in the center of the 600?m-thick middle banded series. Over this same interval, Pt, Pd, and Au are initially elevated and then decrease in the order Pd?>?Pt?>?Au. Within the middle and upper banded series, S abundances fluctuate considerably, but exhibit an overall upward increase. The behavior of these elements records periodic sulfide saturation during deposition of the Peridotite zone, followed by crystallization under sulfide-undersaturated conditions until saturation is achieved at the base of the J-M reef. Following formation of the reef, sulfide-saturated conditions persisted throughout the deposition of most of the remaining Lower Layered Series. This resulted in a pronounced impoverishment in PGE abundance in the remaining magma, a condition that continued throughout deposition of the remainder of a succession, which is characterized by very low Pt (1.5?ppb) and Pd (0.7?ppb) abundances. Because only unmineralized rock was selected for study in the 5.3?km-thick section, the results provide an unbiased picture of the variation in background PGE levels during crystallization of the Stillwater Complex. In contrast, the variations in the drill core samples through the reef provide a detailed record of ore formation. Plots of Pt, Pd, Pd/S, and Pt?+?Pd as a function of stratigraphic height in the intrusion show that the location of the J-M reef is defined by an abrupt change in these concentrations and ratios. Although this is the most abrupt change, three other anomalies in PGE abundance and ratios are apparent in the profiles and coincide with known laterally extensive sub-economic sulfide concentrations above the J-M reef. The uppermost of these is the PGE-bearing Picket Pin sulfide horizon. The relative ease with which mineralized horizons can be pinpointed in these diagrams indicates that a similar approach could be used in exploration programs in other ultramafic/mafic intrusions. Our observations exclude the possibilities of either magma mixing within the Stillwater chamber or the fluxing of a volatile-rich fluid as the mechanisms responsible for the genesis of the J-M reef. Rather, our data indicate that the J-M reef formed from a parental magma that was strongly enriched in PGE; this magma likely formed at depth below the Stillwater magma chamber by the interaction of the parental magma with S-rich meta-sedimentary rocks, followed by the re-dissolution of these sulfides in the Stillwater magma.  相似文献   

Isotopic Approach to Determining the Fate of Ammonium Regenerated from Sediments in a Eutrophic Sub-estuary of Waquoit Bay,MA     

Joanna K. York  Gabrielle Tomasky  Ivan Valiela  Anne E. Giblin 《Estuaries and Coasts》2010,33(5):1069-1079

We measured fluxes of NH₄⁺ and NO₃⁻ and δ¹⁵N of NH₄⁺, sediment, and porewater NH₄⁺ from incubated sediment cores along a nitrate gradient and in different seasons from Childs River, MA. NH₄⁺ flux was low at the downstream site with the lowest concentration of organic matter (high salinity) but otherwise did not differ along the estuary. The δ¹⁵N of regenerated NH₄⁺ ranged from +6.1‰ to +15.3‰ but did not vary significantly with season or salinity; the mean for the entire estuary was +10.4 ± 0.5‰. Based on differences between the δ¹⁵N of regenerated NH₄⁺ and sediment, and expected isotopic fractionation due to remineralization, we concluded that nitrification occurred after remineralization of NH₄⁺. Differences between the δ¹⁵N of regenerated NH₄⁺ and the δ¹⁵N of porewater NH₄⁺ provided further evidence of nitrification. We estimated that 11% to 48% of remineralized NH₄⁺ underwent coupled nitrification–denitrification before release into the water column. In spite of losses to denitrification, NH₄⁺ flux released 1.4 mol N m⁻² year⁻¹ to the water column and could provide 42% of phytoplankton nitrogen requirements.  相似文献   

The symbiotic binary system RX Puppis: a possible recurrent nova with a Mira companion     

Joanna Miko&#;ajewska  Estela Brandi †  Warren Hack  Patricia A. Whitelock  Rodolfo Barba ‡  Lia Garcia  Freddy Marang 《Monthly notices of the Royal Astronomical Society》1999,305(1):190-210

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Early‐stage aeolian protodunes: Bedform development and sand transport dynamics          下载免费PDF全文

Matthew C. Baddock  Joanna M. Nield  Giles F.S. Wiggs 《地球表面变化过程与地形》2018,43(1):339-346

Early‐stage aeolian bedforms, or protodunes, are elemental in the continuum of dune development and act as essential precursors to mature dunes. Despite this, we know very little about the processes and feedback mechanisms that shape these nascent bedforms. Whilst theory and conceptual models have offered some explanation for protodune existence and development, until now, we have lacked the technical capability to measure such small bedforms in aeolian settings. Here, we employ terrestrial laser scanning to measure morphological change at the high frequency and spatial resolution required to gain new insights into protodune behaviour. On a 0.06 m high protodune, we observe vertical growth of the crest by 0.005 m in two hours. Our direct measurements of sand transport on the protodune account for such growth, with a reduction in time‐averaged sediment flux of 18% observed over the crestal region. Detailed measurements of form also establish key points of morphological change on the protodune. The position on the stoss slope where erosion switches to deposition is found at a point 0.07 m upwind of the crest. This finding supports recent models that explain vertical dune growth through an upwind shift of this switching point. Observations also show characteristic changes in the asymmetric cross‐section of the protodune. Flow‐form feedbacks result in a steepening of the lee slope and a decline in lower stoss slope steepness (by 3°), constituting a reshaping of protodune form towards more mature dune morphology. The approaches and findings applied here, (a) demonstrate an ability to quantify processes at requisite spatial and temporal scales for monitoring early‐stage dune evolution, (b) highlight the crucial role of form‐flow feedbacks in enabling early‐stage bedform growth, alluding to a fluctuation in feedbacks that require better representation in dune models, and (c) provide a new stimulus for advancing understanding of aeolian bedforms. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献