A grain-size correction for metal pollution indexes in river sediments     

Thomas Vincent Gloaguen  Paula Núbia Soares Dalto Motta  Carolina Fonseca Couto 《国际泥沙研究》2021,36(3):362-372

According to the List of Hazardous Substances of the Agency of the Toxic Substances and Disease Registry(ATSDR 2017),some metallic elements such as Pb or Cd are still considered as the most polluting elements in the world.These elements accumulate in sediments,and there are various methods available that differentiate lithogenic sources from anthropogenic sources.For that,the natural geochemical background is required,however,its definition is far from unanimous:it can be a global or local value,single or statistically estimated value,depending on the studies.Our study is focused on the Suba
e River in the state of Bahia,Northeastern Brazil,which was historically contaminated by lead metallurgy.The river sediments were sampled at 21 locations:one at the discharge point of the plant's rainwater basin,ten upstream,and ten downstream.The total contents of Fe,Ti,Mn,Pb,Zn,Cu,Cr,particle-size distribution,and organic matter were analyzed.The conventional geochemical indexes,i.e.,the pollution degree(mCd),pollution load index,and enrichment factor indicated contamination by Zn,Pb,Cr,and Cu.Then,a new enrichment factor is introduced,assuming that the sediments come from erosion of soils in the watershed.After obtaining the natural concentrations of metals in the clay,silt,and sand fractions of uncontaminated reference soils,we corrected the pollution indexes by calculating a new individual background in each sediment sample,according to its grain size distribution.This new approach provided more precise indexes in the assessment of sediment pollution,by highlighting higher contamination of Zn and Pb(around 50%)and at the same time the absence of Cr and Cu contamination,two metals not involved with the metallurgical activity.  相似文献   

Effects of fishing on the structure and functioning of estuarine and nearshore ecosystems   总被引：9，自引：0，他引：9  

Blaber  S. J. M.; Cyrus  D. P.; Albaret  J.-J.; Ching  Chong Ving; Day  J. W.; Elliott  M.; Fonseca  M. S.; Hoss  D. E.; Orensanz  J.; Potter  I. C.; Silvert  W. 《ICES Journal of Marine Science》2000,57(3):590-602

  相似文献   

Intertidal Rocky Shore Communities of the Continental Portuguese Coast: Analysis of Distribution Patterns     

Diana Boaventura  Pedro R  Luís Cancela da Fonseca  Stephen J. Hawkins 《Marine Ecology》2002,23(1):69-90

  相似文献   

Variability of labile metals in estuarine sediments in areas under the influence of antifouling paints,southern Brazil     

Luiza Dy Fonseca Costa  Nicolai Mirlean  Julio Cesar Wasserman  Mônica Wallner-Kersanach 《Environmental Earth Sciences》2016,75(7):580

  相似文献   

Vapour source and spatiotemporal variation of precipitation isotopes in Southwest Spain     

Claus Kohfahl  Rolf Fonseca Rodríguez  Fernando Ruiz Bermudo  Iñaki Vadillo 《水文研究》2021,35(12):e14445

The δ²H and δ¹⁸O composition of 77 precipitation samples collected between January 2014 and April 2019 from two sites across the Guadalquivir Basin, SW Spain, were analysed. The first site is located in an urban area of Seville at 100 km distance to the Atlantic coast and the second site is located in a dune area of the Doñana National Park a few kilometres from the coast. Sampling was performed within intervals of at least 14 days if rain occurred but frequently intervals were longer according to the rainfall incidence. Samples from both sites are available for the period February 2016 to June 2018 with six samples containing identical rain events at both locations. Precipitation weighted averages and local meteoric water lines produced by weighting and non-weighting regression methods are presented for its use in hydrological applications. Results show a remarkably high variability in δ²H and δ¹⁸O values and precipitation weighted average d-excess values of 11.8‰ and 13‰ at the sites Plaza de España and Doñana, respectively. Temperature and amount effects were found to be weak. A significant influence of secondary evaporation for single rainfall events during summer was identified by enriched isotopic signatures with reduced d-excess values plotting close or below the global meteoric water line. Backward trajectory analysis of 115 days with daily rainfall above 3 mm yield a predominant Atlantic Ocean vapour source with negligible Mediterranean influence and therefore, d-excess variability is attributed to the different ocean surface conditions of relative humidity and sea surface temperature. Parallel sampling indicate very similar isotopic signatures at both sites and point to the existence of thermal effects of the Plaza de España site in Seville city during the summer season.  相似文献   

Timing of high-pressure metamorphic events in the Bulgarian Rhodopes from Lu–Hf garnet geochronology     

M.?KirchenbaurEmail author  J.?Pleuger  S.?Jahn-Awe  T.?J.?Nagel  N.?Froitzheim  R.?O.?C.?Fonseca  C.?Münker 《Contributions to Mineralogy and Petrology》2012,163(5):897-921

Within the Mediterranean realm, the Rhodopes represent a nappe stack of oceanic and continental fragments assembled along the Eurasian continental margin during the Alpine orogeny. The timing of the high-pressure (HP) metamorphism has long been ambiguous, lacking detailed geochronological and geochemical control on subduction-exhumation and nappe stacking processes. Here we apply the Lu–Hf and Sm–Nd chronometers to a suite of representative eclogite samples covering two different key units of the Rhodopean nappe stack: (1) the Kimi Complex (Upper Allochthon) and (2) the Middle Allochthon. In addition to geochronology, we also determined whole rock Hf and Nd isotope compositions as well as major and trace element concentrations in order to constrain the nature of the eclogite protoliths. Two HP metamorphic events were revealed by Lu–Hf geochronology: (1) a Lower Cretaceous event in the Upper Allochthon (126.0 ± 1.7 Ma) and (2) an Eocene event in the Middle Allochthon (44.6 ± 0.7 Ma; 43.5 ± 0.4 Ma; 42.8 ± 0.5 Ma), at conditions of ca. 700°C/20–25 kbar. Our new data provide direct evidence for multiple subduction events in the Rhodopes. Exhumation and subsequent thrusting of the Middle Allochthon on the Lower Allochthon can be narrowed down to the time span between 42 and 34 Ma. In a broader tectonic context, the Eocene ages for the HP metamorphism support the view that the Rhodopes represent a large-scale tectonic window, exposing the deepest nappe units of the Hellenides.  相似文献   

On the shearing behaviour of an artificially cemented soil   总被引：2，自引：1，他引：1  

Sara Rios  António Viana da Fonseca  Béatrice Anne Baudet 《Acta Geotechnica》2014,9(2):215-226

Ground improvement by cementation is a technique widely used because of the easiness of application and relatively low cost. To date, however, there is no global understanding of the behaviour of artificially cemented soil with respect to its dosage, so that in practice methodologies still rely on previous used scenarios rather than scientific facts. This paper presents results of low-to-high-pressure triaxial tests performed on pure and cemented specimens of decomposed granite where the dosage was controlled, chosen as a function of the ratio of porosity to volumetric cement content or adjusted porosity/cement index. The behaviour of the cemented soil was analysed in terms of peak strength and failure envelopes, stress dilatancy and state boundary surfaces, on which the influence of the porosity/cement index was examined.  相似文献   

Simulation of Geological Contacts from Interpreted Geological Model Using Multiple-Point Statistics   总被引：2，自引：1，他引：1  

Alexandre Boucher  Joao Felipe Costa  Luis Gustavo Rasera  Eduardo Motta 《Mathematical Geosciences》2014,46(5):561-572

Applications of multiple-point statistics (mps) algorithms to large non-repetitive geological objects such as those found in mining deposits are difficult because most mps algorithms rely on pattern repetition for simulation. In many cases, an interpreted geological model built from a computer-aided design system is readily available but suffers as a training image due to the lack of patterns repetitiveness. Porphyry copper deposits and iron ore formations are good examples of such mining deposits with non-repetitive patterns. This paper presents an algorithm called contactsim that focuses on reproducing the patterns of the contacts between geological types. The algorithm learns the shapes of the lithotype contacts as interpreted by the geologist, and simulates their patterns at a later stage. Defining a zone of uncertainty around the lithological contact is a critical step in contactsim, because it defines both the zones where the simulation is performed and where the algorithm should focus to learn the transitional patterns between lithotypes. A larger zone of uncertainty results in greater variation between realizations. The definition of the uncertainty zone must take into consideration the geological understanding of the deposit, and the reliability of the contact zones. The contactsim algorithm is demonstrated on an iron ore formation.  相似文献   

Solubility of palladium in picritic melts: 1. The effect of iron     

V. Laurenz  R.O.C. Fonseca  P.J. Sylvester 《Geochimica et cosmochimica acta》2010,74(10):2989-350

In order to improve our understanding of HSE geochemistry, we evaluate the effect of Fe on the solubility of Pd in silicate melts. To date, experimentally determined Pd solubilities in silicate melt are only available for Fe-free anorthite-diopside eutectic compositions. Here we report experiments to study the solubility of Pd in a natural picritic melt as a function of pO₂ at 1300 °C in a one atm furnace. Palladium concentrations in the run products were determined by laser-ablation-ICP-MS. Palladium increases from 1.07 ± 0.26 ppm at FMQ-2, to 306 ± 19 ppm at FMQ+6.6. At a relative pO₂ of FMQ the slope in log Pd concentration vs. log pO₂ space increases considerably, and Pd concentrations are elevated over those established for AnDi melt compositions. In the same pO₂ range, ferric iron significantly increases relative to ferrous iron. Furthermore, at constant pO₂ (FMQ+0.5) Pd concentrations significantly increase with increasing X_FeO-total in the melt. Therefore, we consider ferric Fe to promote the formation of Pd²⁺ enhancing the solubility of Pd in the picrite melt significantly.The presence of FeO in the silicate melt has proven to be an important melt compositional parameter, and should be included and systematically investigated in future experimental studies, since most natural compositions have substantial FeO contents.  相似文献   

Interaction of acid mine drainage with waters and sediments at the Corona stream, Lousal mine (Iberian Pyrite Belt, Southern Portugal)   总被引：1，自引：0，他引：1  

E. Ferreira da Silva  C. Patinha  P. Reis  E. Cardoso Fonseca  J. X. Matos  J. Barrosinho  J. M. Santos Oliveira 《Environmental Geology》2006,50(7):1001-1013

This study investigates the geochemical characteristics of the acid mine drainage discharged from the abandoned mine adits and tailing piles in the vicinity of the Lousal mine and evaluates the extent of pollution on water and on the stream sediments of the Corona stream. Atmospheric precipitation interacting with sulphide minerals in exposed tailings produces runoff water with pH values as low as 1.9–2.9 and high concentrations of (9,249–20,700 mg l⁻¹), Fe (959–4,830 mg l⁻¹) and Al (136–624 mg l⁻¹). The acidic effluents and mixed stream water carry elevated Cu, Pb, Zn, Cd and As concentrations that exceed the water quality standards. However, the severity of contamination generally decreases 4 km downstream of the source due to mixing with fresh waters, which causes the dilution of dissolved toxic metals and neutralization of acidity. Some natural attenuation of the contaminants also occurs due to the general reduced solubility of most trace metals, which may be removed from solution, by either co-precipitation or adsorption to the iron and aluminium precipitates.  相似文献