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991.
Seven mylonitic samples and two coarse muscovites from the central Pyrenees have been dated by the 40Ar-39Ar method. Whole rock specimens of mylonite were cut out of thin-section chips allowing complete characterisation of mineralogy and texture. Several specimens showed rising staircase patterns in the range 50–90 Ma, with much higher ages in the highest temperature steps. This is believed to reflect mixing of argon released from micas with excess argon contained in plagioclase and released mainly at high temperatures. One biotite-quartz mylonite gave a plateau age of 93 ± 2 Ma. Other inferred mica ages are about 60–73 Ma for biotite and 50–60 Ma for muscovite; it is probable that biotite contains excess argon and that 50 Ma approximates to the cooling age in the mylonites. One coarse muscovite collected immediately below the major Mérens shear zone gave a Hercynian plateau age, while another collected within the Mérens zone gave a partially reset Hercynian age.Taken together, the data indicate that the shear zones were active in Alpine times < 100 Ma and probably about 50 Ma ago. They are believed to have formed during the early stages of Eocene compression in the Pyrenees. Deformation and resultant uplift probably terminated an important thermal event in this part of the Pyrenean basement, which may have begun at the time of the mid-Cretaceous North Pyrenean metamorphism (90–100 Ma).  相似文献   
992.
Sediment, pollen, and plant macrofossil stratigraphies from two small oligotrophic Chamaedaphne-Sphagnum peatlands provide data about local hydrologic changes in northern Michigan during the Holocene. Gleason Bog started about 8000 yr B.P. as a shallow pond that supported rich fen vegetation. After it was partly filled with peat and sand (about 4000 yr B.P.), the vegetation changed to oligotrophic bog. At Gates Bog paludification starting about 3800 yr B.P. caused peat accumulation over sand without an initial pond phase. The onset of peat accumulation at both sites is attributed to a rise in the water table resulting from the onset of cool and moist late Holocene climates. The water table of Gleason Bog is linked to the water level of adjacent Douglas Lake, which may have undergone a simultaneous rise. The results emphasize the individuality of hydrological conditions and hydroseral development in northern Michigan peatlands.  相似文献   
993.
The natural occurrence of hydroxide in olivine   总被引:1,自引:0,他引:1  
Polarized infrared (IR) spectra of olivine single crystals from 17 different localities show a tremendous variability in both mode and abundance of hydroxide (OH) incorporation. Kimberlitic olivines contain the most total OH at an estimated concentration level of 976 H/106Si, whereas olivines from basalts contain the least at 3 H/106Si. Olivines of metamorphic and hydrothermal origin have widely varying concentration levels intermediate between those of basalts and kimberlites. Over 30 distinct OH absorption bands have been identified. Most of these bands are not unique to individual localities but may be found in samples from several different localities. Pleochroism is consistent among localities, but relative band intensities vary. No evidence is found for molecular H2 in olivine. Hydrous minerals have been identified in olivine by their characteristic OH absorption bands. Serpentine is commonly found and is clearly distinguishable from intrinsic OH. Talc is present in one sample. Prominent OH bands at 3572 and 3525 cm?1 are attributed to humite group minerals. San Carlos, Arizona, olivines annealed in the presence of H2O develop absorption bands which are found in natural samples, however the OH absorption spectra of these annealed olivines are not identical to those of any single natural crystal. Sharp-band OH abundances in annealed samples are an order of magnitude lower than the maximum measured in natural specimens. The mechanical properties determined from these annealed olivines may not be directly applicable to mantle olivine because both the OH sites and concentrations are different.  相似文献   
994.
Modeling Organic Contaminant Partitioning in Ground-Water Systems   总被引:1,自引:0,他引:1  
  相似文献   
995.
24 SmNd isotope analyses of fine-grained Phanerozoic and modern clastic sediments from Britain and Quebec are presented. In combination with published data, they have been used to calculate “crustal residence ages” (tCR) and to assess the provenance of the British sedimentary mass. Sediments now preserved on either side of the suture formed by the closure of the Iapetus Ocean ca. 400 Ma ago were derived from isotopically distinct source regions. Sediments north of the suture are characterised by1.7 < tCR < 2.8 Ga, whereas those to the south exhibit a smaller range and an average value of 1.6 Ga. The northern and southern source regions were most probably Laurentia and Gondwana respectively. It seems likely that a third source, perhaps Baltica, provided the lower Palaeozoic Southern Uplands succession. Sediments deposited in southern Britain after the closure of Iapetus were derived mainly from the recycling of older sediments. The tectonic rearrangements which occurred during the Phanerozoic are not reflected in the SmNd isotopic structure of the southern British sedimentary mass, suggesting that the Caledonian and Hercynian orogenies, and even the Grenville orogeny, involved minimal accretion of new mantle-derived material into the British and adjacent continental crust. SmNd analyses of fine-grained clastic sediments provide a powerful sedimentological tool for elucidating palaeogeography, clastic source areas, sediment recycling and maturity, and some aspects of sediment transport.  相似文献   
996.
Extreme fractionation of minor and trace elements commonly accompanies very modest changes in major element concentrations in highly felsic igneous sequences. In such sequences, Si increases by only a few percent while, for example, Sr, Ba, Mg, and light rare earth elements decrease drastically, commonly by a factor of 10 or more. It has been argued, most notably by Hildreth (e.g. [1]), that such trends observed in tuffs were not induced by fractional crystallization (FC), but rather are a manifestation of compositional gradients in parental magma chambers which form via liquid-state thermogravitational diffusion (LSTD). The strongest arguments against FC are that (1) crystal settling is not a viable mechanism for crystal-liquid separation, and (2) extensive recrystallization is required to produce the observed trends, yet the tuffs are relatively crystal-poor. Many workers have noted trends in plutonic as well as volcanic rocks which are strikingly similar to those for which LSTD has been proposed, and some have concluded that LSTD was the fractionating mechanism.Several lines of evidence lead us to the conclusion that FC is the dominant differentiating process in high-silica magmas: (1) elemental trends are strikingly consistent with those predicted for FC; it would be a remarkable coincidence if diffusion-induced trends mimicked FC so closely; (2) large phenocryst assemblages in high-silica tuffs indicate low-variance liquid compositions that would be improbable if crystal-liquid equilibria were not controlling differentiation; (3) highly evolved plutonic rocks in many cases do not form the caps expected for LSTD, but rather occur in dikes and pods where they apparently segregated as late liquids; (4) recent experimental studies suggest that trends induced by diffusion differ drastically from observed felsic igneous trends.We do not believe that the principal arguments against FC in high-silica systems (unlikelihood of crystal settling; crystal-poor nature of tuffs) refute the reality of the chemical process, but rather emphasize the need for a better understanding of the physical mechanisms of crystal-liquid fractionation and eruption.  相似文献   
997.
Physical separation of bitumen from low-grade Utah tar sand deposits containing a relatively high viscosity bitumen phase (Sunnyside and Tar Sand Triangle deposits) has been accomplished by traditional size reduction and froth flotation techniques. At appropriate experimental conditions more than 90% of the bitumen can be recovered in a concentrate, containing more than 20 wt. % bitumen, which should be a suitable feed material for subsequent hot water or thermal processing. The efficiency of bitumen recovery depends on the extent of size reduction, as well as promoter and dispersant addition. Rejection of greater than 60% of the sand at ambient temperature and ease of water removal from the concentrate make such a process strategy both energy and cost effective. The energy required to achieve effective separation by the ambient temperature process is significantly less than the energy required for the recently developed hot water process which is being evaluated in a 100-tpd pilot plant this year.The flotation behaviour of the tar sand in this ambient temperature process has been correlated with contact angle measurements and the apparent point-of-zero-charge of the bitumen. The best flotation response at pH 7.8 to 9.0 occurs when the contact angle between the air bubble and bitumen surface is a maximum, corresponding to the apparent point-of-zero-charge of the bitumen as determined by titration.  相似文献   
998.
Mean annual estimates of the oceanic poleward energy transport are obtained using a global atmospheric general circulation model. The computations are carried out by using the atmospheric model to determine the net annual heat flux into the ocean on an 8° × 10° grid. Assuming no net annual heat storage, the annual surface heat fluxes into any zonal band must be accompanied by a corresponding meridional heat transport in the ocean. Heat is transported northward at all latitudes in the Atlantic Ocean and is transported poleward in both hemispheres in the Pacific Ocean. To account for the net northward transport throughout the Atlantic, heat is transported into the Atlantic from the Indian and Pacific basins. The results are compared with several recent direct and indirect calculations of oceanic meridional heat transports.  相似文献   
999.
It is widely recognised that a significant limitation to the ultimate precision of carbon stable isotope ratio measurements, as obtained from dual-inlet mass spectrometric measurements of CO2 isotopologue ion abundances at m/z 44, 45, and 46, is the correction for interference from 17O-bearing molecular ions. Two long-established, alternative procedures for determining the magnitude of this correction are in widespread use (although only one has IAEA approval); their differences lead to small but potentially significant discrepancies in the magnitude of the resulting correction. Furthermore, neither approach was designed to accommodate oxygen three-isotope distributions which do not conform to terrestrial mass-dependent behaviour. Stratospheric CO2, for example, contains a strongly ‘mass-independent’ oxygen isotope composition. A new strategy for determining the 17O-bearing ion correction is presented, for application where the oxygen three-isotope characteristics of the analyte CO2 are accurately known (or assigned) in terms of the slope λ of the three-isotope fractionation line and the ordinate axis intercept 103 ln(1 + k) on a 103 ln(1 + δ17O) versus 103 ln(1 + δ18O) plot. At the heart of the approach is the relationship between 17R, which is the 17O/16O ratio of the sample CO2, and other assigned or empirically determined parameters needed for the δ13C evaluation:
  相似文献   
1000.
A complete understanding of the processes of crustal growth and recycling in the earth remains elusive, in part because data on rock composition at depth is scarce. Seismic velocities can provide additional information about lithospheric composition and structure, however, the relationship between velocity and rock type is not unique. The diverse xenolith suite from the Potrillo volcanic field in the southern Rio Grande rift, together with velocity models derived from reflection and refraction data in the area, offers an opportunity to place constraints on the composition of the crust and upper mantle from the surface to depths of  60 km. In this work, we calculate seismic velocities of crustal and mantle xenoliths using modal mineralogy, mineral compositions, pressure and temperature estimates, and elasticity data. The pressure, temperature, and velocity estimates from xenoliths are then combined with sonic logs and stratigraphy estimated from drill cores and surface geology to produce a geologic and velocity profile through the crust and upper mantle. Lower crustal xenoliths include garnet ± sillimanite granulite, two-pyroxene granulite, charnokite, and anorthosite. Metagabbro and amphibolite account for only a small fraction of the lower crustal xenoliths, suggesting that a basaltic underplate at the crust–mantle boundary is not present beneath the southern Rio Grande rift. Abundant mid-crustal felsic to mafic igneous xenoliths, however, suggest that plutonic rocks are common in the middle crust and were intraplated rather than underplated during the Cenozoic. Calculated velocities for garnet granulite are between  6.9 and 8.0 km/s, depending on garnet content. Granulites are strongly foliated and lineated and should be seismically anisotropic. These results suggest that velocities > 7.0 km/s and a layered structure, which are often attributed to underplated mafic rocks, can also be characteristic of alternating garnet-rich and garnet-poor metasedimentary rocks. Because the lower crust appears to be composed largely of metasedimentary granulite, which requires deep burial of upper crustal materials, we suggest the initial construction of the continental crust beneath the Potrillo volcanic field occurred by thickening of supracrustal material in the absence of large scale magmatic accretion. Mantle xenoliths include spinel lherzolite and harzburgite, dunite, and clinopyroxenite. Calculated P-wave velocities for peridotites range from 7.75 km/s to 7.89 km/s, with an average of 7.82 km/s. This velocity is in good agreement with refraction and reflection studies that report Pn velocities of 7.6–7.8 km/s throughout most of the Rio Grande rift. These calculations suggest that the low Pn velocities compared to average uppermost mantle are the result of relatively high temperatures and low pressures due to thin crust, as well as a fertile, Fe-rich, bulk upper mantle composition. Partial melt or metasomatic hydration of the mantle lithosphere are not needed to produce the observed Pn velocities.  相似文献   
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